EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name MARLON AMI 80 1.2 Relevant identified uses of the substance or mixture and uses advised against Use raw material for washing and cleaning agents surface-active substance Uses advised against 1.3 Details of the supplier of the safety data sheet Company SASOL Germany GmbH Anckelmannsplatz 1 20537 Hamburg Germany Telephone: +49 40 63684-1000 Telefax: +49 40 63684-3700 Information (Product safety): Telephone: + 49 (0) 23 65 - 49 47 05 Telefax: + 49 (0) 23 65 - 49 92 40 E-mail address [email protected] 1.4 Emergency telephone number Emergency telephone number + 49 (0) 23 65 - 49 22 32 SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 (Oral) Harmful if swallowed. Serious eye damage, Category 1 Causes serious eye damage. Long-term (chronic) aquatic hazard, Category 3 Harmful to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms Signal word Danger Hazard statements Print Date 03.12.2019 000000008253 CONEUSDBUS E 1/15 EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 H302 Harmful if swallowed. H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear eye protection/ face protection. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P501 Dispose of contents/ container to an approved waste disposal plant. Hazardous components which must be listed on the label: Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.-, compd. with 1-aminopropane-2-ol Remarks on classification and The mixture, as such, was examined for toxicological characteristics and then labelling classified accordingly. 2.3 Other hazards None known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture in the meaning of regulation (EC) 1907/2006. COMPONENTS TO BE NAMED IN ACCORDANCE WITH REGULATION (EC) 1907/2006 AS WELL AS OTHER HAZARDOUS INGREDIENTS AND CONTAINED SUBSTANCES WITH WORK PLACE LIMIT VALUES Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.-, compd. with 1-aminopropane-2-ol content: >= 70 - < 90 % component type: Active ingredient EC-No.: 939-479-4 Index-No.: CAS-No.: 1471311-60-0 REACH No.: 01-2119971816-24-0000 Substance name (REACH / CLP): Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.-, compd. with 1- aminopropane-2-ol Classification (Regulation Acute Tox. 4 (Oral) H302 (EC) No 1272/2008): Eye Dam. 1 H318 Aquatic Chronic 3 H412 Substances for which maximum allowable workplace concentrations have been laid down propane-1,2-diol content: >= 20 - < 30 % component type: Active ingredient EC-No.: 200-338-0 Index-No.: CAS-No.: 57-55-6 REACH No.: 01-2119456809-23-XXXX For the full text of the H-Statements mentioned in this Section, see Section 16. Other data Synonyms: Alkylbenzenesulfonicacid(C10-14), MIPA-salt; CAS-No.: 85995-83-1 Print Date 03.12.2019 000000008253 CONEUSDBUS E 2/15 EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice If you feel unwell, seek medical advice (show the label where possible). Take off all contaminated clothing immediately. If inhaled Remove from exposure, lie down. If breathing is irregular or stopped, administer artificial respiration. Monitor breathing, give oxygen if necessary. Consult a physician. In case of skin contact Wash off immediately with plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Consult a physician. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms and effects, both acute and delayed Most important symptoms and Symptoms: No information available. effects, both acute and delayed Risks: No information available. 4.3 Indication of any immediate medical attention and special treatment needed Indication of any immediate Treatment: No information available. medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Water spray, Dry powder, Foam, Carbon dioxide (CO2) 5.2 Special hazards arising from the substance or mixture Specific hazards during Dangerous gases or fumes may occur in case of fire. firefighting 5.3 Advice for firefighters Special protective equipment Wear self-contained breathing apparatus for firefighting if necessary. for firefighters Further information Standard procedure for chemical fires. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment. Special precautions Forms slippery/greasy layers with water. 6.2 Environmental precautions Print Date 03.12.2019 000000008253 CONEUSDBUS E 3/15 EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 Environmental precautions Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 6.4 Reference to other sections For personal protection see section 8. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling Wear personal protective equipment. Advice on protection against No special protective measures against fire required. fire and explosion 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas No special storage conditions required. and containers Storage class (TRGS 510) 10-13: German Storage Class 10 to 13 7.3 Specific end use(s) Specific use(s) This information is not available. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters COMPONENTS WITH WORKPLACE CONTROL PARAMETERS National occupational exposure limits Control parameters / Typ Control Update Basis Substance name parameters PROPYLENE GLYCOL, TWA 10 mg/m3 2012 WEEL Guides List AEROSOL ONLY Propylene Glycol TWA 10 mg/m3 2008-01-01 USA. Workplace Environmental Exposure Levels (WEEL) EUROPEAN OCCUPATIONAL EXPOSURE LIMITS No data available DERIVED NO EFFECT LEVEL (DNEL) Substance name: Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.-, compd. with 1-aminopropane-2-ol Print Date 03.12.2019 000000008253 CONEUSDBUS E 4/15 EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 End Use Exposure routes Value Note Workers dermal, Acute/short-term exposure - Not relevant / Not systemic effects applicable Inhalation, Acute/short-term exposure - Not relevant / Not systemic effects applicable dermal, Acute/short-term exposure - local Not relevant / Not effects applicable Inhalation, Acute/short-term exposure - Not relevant / Not local effects applicable dermal, long-term exposure - systemic 0,98 mg/kg based on body weight and effects day Inhalation, long-term exposure - systemic 3,45 mg/m3 effects dermal, long-term exposure - local effects Not relevant / Not applicable Inhalation, long-term exposure - local Not relevant / Not effects applicable Consumers dermal, Acute/short-term exposure - Not relevant / Not systemic effects applicable Inhalation, Acute/short-term exposure - Not relevant / Not systemic effects applicable Oral, Acute/short-term exposure - systemic Not relevant / Not effects applicable dermal, Acute/short-term exposure - local Not relevant / Not effects applicable Inhalation, Acute/short-term exposure - Not relevant / Not local effects applicable dermal, long-term exposure - systemic 0,49 mg/kg based on body weight and effects day Inhalation, long-term exposure - systemic 0,85 mg/m3 effects Oral, long-term exposure - systemic 0,49 mg/kg based on body weight and effects day dermal, long-term exposure - local effects Not relevant / Not applicable Inhalation, long-term exposure - local Not relevant / Not effects applicable Print Date 03.12.2019 000000008253 CONEUSDBUS E 5/15 EC-SAFETY DATA SHEET MARLON AMI 80 Version: 7.02 Revision Date 16.09.2019 PREDICTED NO EFFECT CONCENTRATION (PNEC) Substance name: Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.-, compd. with 1-aminopropane-2-ol Environmental Compartment Value Note Fresh water 268 mg/l Marine water 0,0268 mg/l intermittent release 0,268 mg/l Sewage treatment plant 1,37 mg/l Fresh water sediment 8,1 mg/kg based on dry weight Marine sediment 8,1 mg/kg based on dry weight Soil 35 mg/kg based on dry weight food Not relevant / Not applicable 8.2 Exposure controls PERSONAL PROTECTIVE EQUIPMENT Respiratory protection No personal respiratory protective equipment normally required. In inadequately ventilated areas, where workplace limits are exceeded, where unpleasant odours exist or where aerosols are in use, or smoke and mist occur, use self-contained breathing apparatus or breathing apparatus with a type A filter or appropriate combined filter (e.g. where aerosols are in use,