World Headquarters Page 1 Hach Company Date Printed 11/3/15 P.O.Box 389 MSDS No: M00905 Loveland, CO USA 80539 (970) 669-3050 SAFETY DATA SHEET _____________________________________________________________________________ 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Nitrate Ionic Strength Adjustor Powder Pillows Catalog Number: 4456369 Hach Company Emergency Telephone Numbers: P.O.Box 389 (Medical and Transportation) Loveland, CO USA 80539 (303) 623-5716 24 Hour Service (970) 669-3050 (515)232-2533 8am - 4pm CST MSDS Number: M00905 Chemical Name: Not applicable CAS Number: Not applicable Additional CAS No. (for hydrated forms): Not applicable Chemical Formula: Not applicable Chemical Family: Inorganic Salt Intended Use: Ionic strength adjustor, buffer and interference suppressor for Nitrate electrode _____________________________________________________________________________ 2. HAZARDS IDENTIFICATION GHS Classification: Hazard categories: Serious Eye Damage/Eye Irritation: Eye Dam. 1 Hazardous to the Aquatic Environment: Aquatic Acute 1 GHS Label Elements: DANGER Hazard statements: Causes serious eye damage. Very toxic to aquatic life with long lasting effects. Precautionary statements: Handle environmental release according to local, state, federal, provincial requirements. Wear eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Collect spillage. Dispose of contents/container according to state, local, federal or national regulations. HMIS: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: X - See protective equipment, Section 8. NFPA: Health: 1 Flammability: 0 Reactivity: 0 Symbol: Not applicable WHMIS Hazard Classification: Not applicable WHMIS Symbols: Not applicable _____________________________________________________________________________ 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Components according to GHS: Aluminum Sulfate World Headquarters Page 2 Hach Company Date Printed 11/3/15 P.O.Box 389 MSDS No: M00905 Loveland, CO USA 80539 (970) 669-3050 CAS Number: 10043-01-3 Chemical Formula: Al 2(SO 4)3 GHS Classification: Percent Range (Trade Secret): 70.0 - 80.0 Percent Range Units: weight / weight PEL: 2 mg/m 3 TLV: 2 mg/m 3 WHMIS Symbols: Other Toxic Effects Potassium Sulfamate CAS Number: 13823-50-2 Chemical Formula: NH 2SO 3K GHS Classification: Acute Tox Inh. 4, H332; Acute Tox Der. 4, H312; Eye Irrit. 2, H319; STOT SE 3, H335; Skin Irrit. 2 H315 Percent Range (Trade Secret): 10.0 - 20.0 Percent Range Units: weight / weight PEL: Not established TLV: Not established WHMIS Symbols: Not applicable Silver Sulfate CAS Number: 10294-26-5 Chemical Formula: Ag 2SO 4 GHS Classification: Eye Dam. 1, H318; Aquatic Chronic 1, H410 Percent Range (Trade Secret): 5.0 - 15.0 Percent Range Units: weight / weight PEL: 0.01 mg/m³ (Ag) TLV: 0.01 mg/m³ (Ag) WHMIS Symbols: Not applicable _____________________________________________________________________________ 4. FIRST AID MEASURES General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to a doctor. Advice to doctor: Treat symptomatically. Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician if irritation develops. Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Call physician if irritation develops. Remove contaminated clothing. Inhalation: Remove to fresh air. Ingestion (First Aid): Give large quantities of water. Call physician immediately. Never give anything by mouth to an unconscious person. _____________________________________________________________________________ 5. FIRE FIGHTING MEASURES Flammable Properties: Does not burn, but may melt in a fire, releasing toxic fumes. Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective gear. Extinguishing Media: Use media appropriate to surrounding fire conditions Extinguishing Media NOT To Be Used: Not applicable Fire / Explosion Hazards: This product will not burn or explode. Hazardous Combustion Products: This material will not burn. _____________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES World Headquarters Page 3 Hach Company Date Printed 11/3/15 P.O.Box 389 MSDS No: M00905 Loveland, CO USA 80539 (970) 669-3050 Spill Response Notice: Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Containment Technique: Stop spilled material from being released to the environment. Clean-up Technique: Sweep up material. Dispose of material in government approved hazardous waste facility. Decontaminate the area of the spill with a soap solution. Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the evacuation. DOT Emergency Response Guide Number: Not applicable _____________________________________________________________________________ 7. HANDLING AND STORAGE Handling: Avoid contact with eyes skin Do not breathe dust. Use with adequate ventilation. Wash thoroughly after handling. Maintain general industrial hygiene practices when using this product. Storage: Keep container tightly closed when not in use. Flammability Class: Not applicable _____________________________________________________________________________ 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Have an eyewash station nearby. Use a fume hood to avoid exposure to dust, mist or vapor. Maintain general industrial hygiene practices when using this product. Personal Protective Equipment: Eye Protection: safety glasses with top and side shields Skin Protection: disposable latex gloves Inhalation Protection: laboratory fume hood Precautionary Measures: Avoid contact with: eyes skin Do not breathe: dust Use with adequate ventilation. Wash thoroughly after handling. TLV: Not established PEL: Not established For Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.: _____________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White crystals Physical State: Solid Molecular Weight: Not applicable Odor: None Odor Threshold: Odorless pH: 3.08 Metal Corrosivity: Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria. Steel: Not Applicable Aluminum: Not Applicable Specific Gravity/ Relative Density (water = 1; air =1): 2.03 Viscosity: Not applicable Solubility: Water: Soluble Acid: Soluble Other: Not determined Partition Coefficient (n-octanol / water): Not applicable Coefficient of Water / Oil: Not applicable Melting Point: 86.5°C Decomposition Temperature: Not determined Boiling Point: Not applicable Vapor Pressure: Not applicable Vapor Density (air = 1): Not applicable World Headquarters Page 4 Hach Company Date Printed 11/3/15 P.O.Box 389 MSDS No: M00905 Loveland, CO USA 80539 (970) 669-3050 Evaporation Rate (water = 1): Not applicable Volatile Organic Compounds Content: Not determined Flammable Properties: Does not burn, but may melt in a fire, releasing toxic fumes. Flash Point: Not applicable Method: Not applicable Flammability Limits: Lower Explosion Limits: Not applicable Upper Explosion Limits: Not applicable Autoignition Temperature: Not applicable Explosive Properties: Not classified according to GHS criteria. Oxidizing Properties: Not classified according to GHS criteria. Reactivity Properties: Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS criteria. Gas under Pressure: Not classified according to GHS criteria. Not applicable _____________________________________________________________________________ 10. STABILITY AND REACTIVITY Chemical Stability: Stable when stored under proper conditions. Mechanical Impact: None reported Static Discharge: None reported. Reactivity / Incompatibility: Incompatible with: alkalies oleum oxidizers Hazardous Decomposition: Heating to decomposition releases: sulfur oxides Conditions to Avoid: Heating to decomposition. Excess moisture _____________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Toxicokinetics, Metabolism and Distribution: No information available for mixture. Toxicologically Synergistic Products: None reported Acute Toxicity: Based on classification principles, the classification criteria are not met. Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity Data ATE Dermal Rat LD50= 6803 mg/kg Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteria are not met. Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classification criteria are not met. Skin Corrosion/Irritation: Irritating to skin. Eye Damage: Corrosive to eyes. Sensitization: Based on classification principles, the classification criteria are not met. CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicity or reproductive toxicity data found. IARC Listed: No NTP