SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of the substance YSI 2363 Potassium Ferrocyanide Identification number 14459-95-1 (CAS number) Registration number - Synonyms None. Product code YSI 2363 Issue date 20-March-2015 Version number 01 Revision date - Supersedes date - 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Analysis Standard/Reagent Uses advised against None known. 1.3. Details of the supplier of the safety data sheet Supplier Company name YSI, a Xylem brand Address 1700/1725 Brannum Lane Yellow Springs, Ohio 45387 United States Division Telephone (937) 767-7241 e-mail [email protected] Contact person Not available. 1.4. Emergency telephone CHEMTREC (US/Canada) (800) 424-9300 number CHEMTREC (International) 011 703-527-3887 (Collect calls accepted) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended Classification R52/53 The full text for all R-phrases is displayed in section 16. Classification according to Regulation (EC) No 1272/2008 as amended Environmental hazards Hazardous to the aquatic environment, Category 3 H412 - Harmful to aquatic life with long-term aquatic hazard long lasting effects. Hazard summary Physical hazards Not classified for physical hazards. Health hazards Not classified for health hazards. However, occupational exposure to the mixture or substance(s) may cause adverse health effects. Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Specific hazards For additional information on inhalation hazards, see Section 11 of this safety data sheet. Main symptoms Direct contact with eyes may cause temporary irritation. Dust may irritate respiratory system. 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Hazard pictograms None. Signal word None. YSI 2363 Potassium Ferrocyanide SDS EU 920948 Version #: 01 Revision date: - Issue date: 20-March-2015 1 / 7 Hazard statements H412 Harmful to aquatic life with long lasting effects. Precautionary statements Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Supplemental label information Not applicable. 2.3. Other hazards Not a PBT or vPvB substance or mixture. SECTION 3: Composition/information on ingredients 3.1. Substances General information Chemical name % CAS-No. / EC REACH Registration No. INDEX No. Notes No. POTASSIUM FERROCYANIDE 90 - 100 14459-95-1 - - TRIHYDRATE 237-722-2 Classification: DSD: R52/53 CLP: Aquatic Chronic 3;H412 List of abbreviations and symbols that may be used above CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. vPvB: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 4.1. Description of first aid measures Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. 4.2. Most important symptoms Direct contact with eyes may cause temporary irritation. Dust may irritate respiratory system. and effects, both acute and delayed 4.3. Indication of any Treat symptomatically. immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards No unusual fire or explosion hazards noted. 5.1. Extinguishing media Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media 5.2. Special hazards arising During fire, gases hazardous to health may be formed. from the substance or mixture 5.3. Advice for firefighters Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire. equipment for firefighters Special fire fighting Use water spray to cool unopened containers. procedures Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. YSI 2363 Potassium Ferrocyanide SDS EU 920948 Version #: 01 Revision date: - Issue date: 20-March-2015 2 / 7 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. personnel For emergency responders Keep unnecessary personnel away. 6.2. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and material for If sweeping of a contaminated area is necessary use a dust suppressant agent which does not containment and cleaning up react with the product. Collect dust using a vacuum cleaner equipped with HEPA filter. Minimise dust generation and accumulation. Following product recovery, flush area with water. Sweep up or vacuum up spillage and collect in suitable container for disposal. 6.4. Reference to other For personal protection, see section 8. For waste disposal, see section 13 of the SDS. sections SECTION 7: Handling and storage 7.1. Precautions for safe Minimise dust generation and accumulation. Provide appropriate exhaust ventilation at places handling where dust is formed. Avoid breathing dust. Avoid contact with skin and eyes. Avoid prolonged exposure. In case of insufficient ventilation, wear suitable respiratory equipment. Practice good housekeeping. 7.2. Conditions for safe Store in original tightly closed container. Store in a well-ventilated place. Store away from storage, including any incompatible materials (see section 10 of the SDS). incompatibilities 7.3. Specific end use(s) Analysis Standard/Reagent SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Czech Republic. OELs. Government Decree 361 Material Type Value YSI 2363 Potassium TWA 10 mg/m3 Ferrocyanide Components Type Value POTASSIUM TWA 10 mg/m3 FERROCYANIDE TRIHYDRATE (CAS 14459-95-1) Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Material Type Value YSI 2363 Potassium TWA 4 mg/m3 Ferrocyanide Components Type Value POTASSIUM TWA 4 mg/m3 FERROCYANIDE TRIHYDRATE (CAS 14459-95-1) Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring Follow standard monitoring procedures. procedures Derived no-effect level (DNEL) Not available. Predicted no effect Not available. concentrations (PNECs) 8.2. Exposure controls Appropriate engineering Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes controls that may be generated during handling or thermal processing. Individual protection measures, such as personal protective equipment General information Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Use tight fitting goggles if dust is generated. Skin protection - Hand protection For prolonged or repeated skin contact use suitable protective gloves. YSI 2363 Potassium Ferrocyanide SDS EU 920948 Version #: 01 Revision date: - Issue date: 20-March-2015 3 / 7 - Other Wear suitable protective clothing. Respiratory protection Respirator must be worn if exposed to dust. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental exposure Environmental manager must be informed of all major releases. controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Solid. Form Powder. Colour White Odour None. Odour threshold No data available. pH 6,5 - 7,5 Melting point/freezing point 70 °C (158 °F) Initial boiling point and boiling No data available. range Flash point Not applicable. Evaporation rate No data available. Flammability (solid, gas) No data available. Upper/lower flammability or explosive limits Flammability limit - lower No data available. (%) Flammability limit - upper No data available. (%) Explosive limit - lower (%) No data available. Explosive limit – upper No data available. (%) Vapour pressure Not applicable. Vapour density Not applicable. Relative density 1,85 Solubility(ies) Infinitely soluble in water. Partition coefficient No data available. (n-octanol/water) Auto-ignition temperature No data available. Decomposition temperature No data available. Viscosity Not applicable. Explosive properties No data available. Oxidizing properties No data available. 9.2. Other information Density No data available. Molecular formula C6FeN6,3H2O,4K