PITTCON Conference and Expo 2012 Abstracts Orlando, Florida, USA 11-15 March 2012 Index ISBN: 978-1-63439-020-0 4/4 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2012) by Pittsburgh Conference All rights reserved. Printed by Curran Associates, Inc. (2014) For permission requests, please contact Pittsburgh Conference at the address below. Pittsburgh Conference 300 Penn Center Boulevard Suite 332 Pittsburgh, PA 15235-5503 USA Phone: (412) 825-3220 (800) 825-3221 Fax: (412) 825-3224 [email protected] Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2634 Email: [email protected] Web: www.proceedings.com Table of Contents Sunday Afternoon, March 11, 2012 AWARD Session 20 Plenary Lecture (Mixer immediately following in the Valencia Room) Sunday Afternoon, Room: Chapin Theater 4:45 PM (20-01) PLENARY LECTURE - Ambient Ionization and Mini Mass Spectrometers: In situ MS for Everyone R GRAHAM COOKS, Purdue University, Zheng Ouyang SYMPOSIA Session 30 Advances in Rapid Mixing Instruments for Analysis of Enzyme Activities - arranged by Michael A. Trakselis, University of Pittsburgh Sunday Afternoon, Room: 206A Michael A. Trakselis, University of Pittsburgh, Presiding 1:05 PM (30-01) Rapid Chemical Quench-Flow Methods Reveal Mechanisms of Enzymes that Unwind Duplex DNA KEVIN D. RANEY, University of Arkansas for Medical Sciences 1:40 PM (30-02) Multi-Sample, Computer Automated Stopped-Flow TIRF Microscope SANFORD H. LEUBA, University of Pittsburgh, Grant Schauer, Laurence Brewer, Matthew Fagerburg 2:15 PM (30-03) Probing Early Events in Protein Folding by Interfacing Microfluidic Microsecond Mixing with Fluorescence Lifetime and Small-Angle X-ray Scattering Detection OSMAN BILSEL, University of Massachusetts Medical School, C Robert Matthews, Can Kayatekin, Elena Kondrashkina, Liang Guo, R Paul Nobrega, Raul Barrea, Rita Graceffa, Sagar Kathuria, Tom Irving 2:50 PM (30-04) Microfluidic Approaches For Enzyme Kinetics HOWARD A. STONE, Princeton University 3:25 PM (30-05) Presteady-State Fluorescence of Enzyme Complexes: Assembly, Kinetics, and Dynamics MICHAEL A. TRAKSELIS, University of Pittsburgh SYMPOSIA Session 40 Application of Vibrational Spectroscopic Techniques to Art Conservation and Archeology - arranged by John F. Rabolt, University of Delaware Sunday Afternoon, Room: 308A John F. Rabolt, University of Delaware, Presiding 1:05 PM (40-01) An Overview and Case Studies of Infrared and Raman Spectroscopies in Conservation Science CATHERINE MATSEN, Winterthur Museum 1:40 PM (40-02) Application of a Portable, Ultrafast Planar Array Infrared (PA-IR) Spectrograph to Heritage Art Objects JOHN F. RABOLT, University of Delaware, Bruce Chase 2:15 PM (40-03) The Never Ending Story of the Ubiquitous Calcium Oxalates in Cultural Heritage: Recent Aspects of Vibrational Spectroscopy GIUSEPPE ZERBI, Politecnico di Milano, Claudia Conti 2:50 PM (40-04) New Developments in the Application of ATR-FTIR and Raman Spectroscopy to the Characterization of Organic Media in Cross-Sections ADRIANA RIZZO, The Metropolitan Museum of Art 3:25 PM (40-05) Vibrational Spectroscopy in Collections Research: Beyond Identification KAREN TRENTELMAN, Getty Conservation Institute SYMPOSIA Session 50 Applications of Nanoparticles for Bioanalysis - arranged by Duncan Graham, University of Strathclyde Sunday Afternoon, Room: 206B Duncan Graham, University of Strathclyde, Presiding 1:05 PM (50-01) Single-Molecule and Singe-Nanoparticle SERS: 15 Years Later SHUMING NIE, Emory University, Ximei Qian 1:40 PM (50-02) Tuning SERS Nanoantennas for Bioassays MICHAEL NATAN, Cabot Security Materials 2:15 PM (50-03) Single-Cell Analysis of Intracellular Content with “Nano-Flares” CHAD A. MIRKIN, Northwestern University 2:50 PM (50-04) Gold Nanoparticles, Surface Enhanced Raman Scattering, and Ultrasensitive Immunodiagnostics MARC PORTER, University of Utah 3:25 PM (50-05) New Methods of Bioanalysis Using Functionalised Nanoparticles and SERS DUNCAN GRAHAM, University of Strathclyde SYMPOSIA Session 60 Ionic Liquids in Separations and Mass Spectrometry - arranged by Daniel W. Armstrong, University of Texas at Arlington Sunday Afternoon, Room: 206C Daniel W. Armstrong, University of Texas at Arlington, Presiding 1:05 PM (60-01) Ionic Liquids in Separations and Mass Spectrometry DANIEL W. ARMSTRONG, University of Texas at Arlington 1:40 PM (60-02) A New Trend in Gas Chromatography Selectivity: Ionic Liquid Stationary Phases LUIGI MONDELLO, University of Messina, Carla Ragonese, Danilo Sciarrone, Peter Tranchida 2:15 PM (60-03) Extraction-MALDI-MS and Extraction-LC-MS Analytical Tools Based on Ionic Liquids RICO DEL SESTO, Los Alamos National Laboratory, Andrew Koppisch, Cynthia Corley, David Fox, Geraldine Purdy, John Wilkes, Katherine Lovejoy, Srinivas Iyer, Timothy Sanchez 2:50 PM (60-04) The Use of Ionic Liquids as Capillary Gas Chromatographic Stationary Phases LEONARD M. SIDISKY, Supelco/Sigma-Aldrich, Greg Baney, James Desorcie, Katherine Stenerson 3:25 PM (60-05) Ionic Liquid-Based Separation Methods for Pharmaceutical Analysis JARED L. ANDERSON, The University of Toledo, Pamela Twu, Qichao Zhao, Tien Ho SYMPOSIA Session 70 Looking Ahead to a New Era of Analytical Chemistry Education (ACS-ANYL) - arranged by Carol Korzeniewski, Texas Tech University Sunday Afternoon, Room: 308B Carol Korzeniewski, Texas Tech University, Presiding 1:05 PM (70-01) Challenges to Education in the Chemical Sciences in a Time of Change MICHAEL DOYLE, University of Maryland 1:40 PM (70-02) Funding for Analytical Instruments from the National Science Foundation BERT E. HOLMES, University of North Carolina-Asheville 2:15 PM (70-03) Safety in Academic Laboratories JYLLIAN KEMSLEY, Chemical & Engineering News 2:50 PM (70-04) Incorporating RCR in Chemistry Education ALICE YOUNG, Texas Tech University 3:25 PM (70-05) Teaching Analytical Chemistry in Canada, Eh! CHARLES A. LUCY, University of Alberta SYMPOSIA Session 80 New Advances in Electrochemical Neurotransmitter Detection - arranged by R Mark Wightman, University of North Carolina at Chapel Hill Sunday Afternoon, Room: 311B R Mark Wightman, University of North Carolina at Chapel Hill, Presiding 1:05 PM (80-01) Using FSCV to Probe Tyrosine Kinase Receptors Ability to Regulate Dopamine Dynamics TIFFANY A. MATHEWS, Wayne State University, Aaron Apawu, Francis Maina 1:40 PM (80-02) Electrochemical Detection of Octopamine and Tyramine in Drosophila B JILL VENTON, University of Virginia, Madelaine Denno, Phuong Vo, Trisha Vickrey 2:15 PM (80-03) Regulation of Striatal Dopamine Release by Insulin MARGARET E. RICE, New York University School of Medicine, Christian Lee, Jyoti Patel, Kenneth Carr, Li Bao, Melissa Stouffer, Paul Witkovsky, Robert Machold 2:50 PM (80-04) Simultaneous Voltammetric In vivo Detection of 5-HT and Histamine PARASTOO HASHEMI, Wayne State University, Kevin Wood, R Mark Wightman 3:25 PM (80-05) A Novel Voltammetric Microsensor for the Quantitative Detection of Real- Time Glucose Fluctuations in Living Brain Tissue LESLIE A. SOMBERS, North Carolina State University, Amanda Corder, Leyda Lugo-Morales, Phillip Loziuk SYMPOSIA Session 90 Novel Analytical Chemistry for Nanotoxicity Assays - arranged by Chenzhong Li, Florida International University Sunday Afternoon, Room: 207A Chenzhong Li, Florida International University, Presiding 1:05 PM (90-01) Nanomaterials Toxicity: From Materials Properties to Rapid Screening SUDIPTA SEAL, University of Central Florida 1:40 PM (90-02) Analytical Approaches for Nanotoxicity Assays YULIANG ZHAO, National Center for Nanoscience and Technology 2:15 PM (90-03) Integrated Analytical Biosensor for Nanotoxicity Assessment CHEN-ZHONG LI, Florida International University, Evangelia Hondroulis 2:50 PM (90-04) Sensors for Assessing the Toxicity of Engineered Nanomaterials OMOWUNMI (WUNMI) SADIK, SUNY at Binghamton 3:25 PM (90-05) Biophysical Interactions of Nanoparticle with Membrane Lipids VINOD LABHASETWAR, Cleveland Clinic ORGANIZED CONTRIBUTED SESSION Session 100 Biomedical Applications of NIR Fluorescence - arranged by Gabor Patonay, Georgia State University Sunday Afternoon, Room: 207B Gabor Patonay, Georgia State University, Presiding 1:00 PM (100-01) Diagnosis to Therapy: Applications of Cyanine Based NIR Optical Probes NISHA V. PADHYE, LI-COR Biosciences, Joy Kovar, Kousik Kundu, Kuiyi Xing, Michael Olive, Ying Wang 1:20 PM (100-02) GUMBOS: A New Breed of Tunable Materials ISIAH M. WARNER, Louisiana State University, Chengfei Lu, Paul Magut, Sergio de Rooy, Susmita Das, Suzana Hamdan 1:40 PM (100-03) Tumor Imaging with NIR Molecular Probes SAMUEL ACHILEFU, Washington University 2:00 PM (100-04) Design and Synthesis of New NIR Fluorescence Probes for In vivo Imaging KENJIRO HANAOKA, The University of Tokyo 2:35 PM (100-05) Biomedical Applications of Near Infrared Fluorescence from Single Walled Carbon Nanotubes MICHAEL S. STRANO, Massachusetts Institute of Technology 2:55 PM (100-06) A Boronic Acid-Functionalized Squarylium Cyanine Dye Designed for On- Capillary Labeling of Gram-Positive Bacteria in CE-LIF SHINGO SAITO, Saitama University, Christa Colyer, Hiroyuki Nakazumi, Takeshi Maeda 3:15 PM (100-07) NIR Fluorescence Imaging of Human Lymphatic Disease EVA SEVICK- MURACA, University of Texas Health Science Center, Banghe Zhu, Chinmay