Appendix 14.1_INT Ingredients Prohibited Substances – Mechanics Version: April 2014, Page: 1 of 10 List of prohibited substances – Mechanics The substances listed below are prohibited by law or by Heidelberg internal restrictions in the relevant applications. The list will be updated continuously and has to be taken into account by the suppliers and users. All amendments are marked in red. Substance CAS NR. Limit prohibited Exception Regulation [4-[[4-anilino-1-naphthyl][4- 2580-56-5 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) (dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1- ylidene] dimethylammonium chloride (C.I. Basic Blue 26) [with ≥ 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5- 548-62-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) dien-1-ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with ≥ 0.1% of Michler's ketone (EC No. 202-027- 5) or Michler's base (EC No. 202-959-2)] [Phthalato(2-)]dioxotrilead 69011-06-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1-bromopropane (n-propyl bromide) 106-94-5 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1-Methyl-2-pyrrolidone 872-50-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl 71888-89-6 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) esters, C7-rich 1,2-Benzenedicarboxylic acid, di-C7-11-branched and 68515-42-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) linear alkyl esters 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) 112-49-2 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1,2-dichloroethane 107-06-2 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1,2-Diethoxyethane 629-14-1 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1,2-dimethoxyethane; ethylene glycol dimethyl ether 110-71-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) (EGDME) 1,2,3-Trichloropropane 96-18-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione 2451-62-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) (TGIC) 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5-triazine- 59653-74-6 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2,4,6-(1H,3H,5H)-trione (β-TGIC) 2-Ethoxyethanol 110-80-5 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2-Ethoxyethyl acetate 111-15-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2-Methoxyaniline; o-Anisidine 90-04-0 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2-Methoxyethanol 109-86-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2-Naphthylamine 91-59-8 < 0,1 Gew. % all applications EU REACH-VO. Anh. XVII 2,2'-dichloro-4,4'-methylenedianiline 101-14-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 2,4-Dinitrotoluene 121-14-2 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV | EU REACH-VO. Anh. XIV (Kandidatenliste) 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine 143860-04-2 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated [covering = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) well-defined substances and UVCB substances, polymers and homologues] 4-(1,1,3,3-Tetramethylbutyl)phenol; 4-tert-octyl phenol 140-66-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 4-Aminobiphenyl 92-67-1 < 0,1 Gew. % all applications EU REACH-VO. Anh. XVII 4-Nitrobiphenyl 92-93-3 < 0,1 Gew. % all applications EU REACH-VO. Anh. XVII © Heidelberger Druckmaschinen AG Guidline for Cooperation with Suppliers 01.2008 Appendix 14.1_INT Ingredients Prohibited Substances – Mechanics Version: April 2014, Page: 2 of 10 Substance CAS NR. Limit prohibited Exception Regulation 4-Nonylphenol, branched and linear = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof] 4-Nonylphenol, branched and linear, ethoxylated = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof] 4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with 561-41-1 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) ≥ 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] 4,4'-bis(dimethylamino)benzophenone (Michler’s ketone) 90-94-8 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) 4,4’-Diaminodiphenylmethane (MDA) 101-77-9 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV | EU REACH-VO. Anh. XIV (Kandidatenliste) 5-tert-butyl-2,4,6- trinitro-m-xylene (Musk xylene) 81-15-2 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV | EU REACH-VO. Anh. XIV (Kandidatenliste) Acenaphthene 83-32-9 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Acenaphthylene 208-96-8 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Acetic acid, lead salt, basic 51404-69-4 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) Acrylamide 79-06-1 < 0,1 Gew. % Grouting applications EU REACH-VO. Anh. XVII Acrylamide 79-06-1 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) Actinolite 77536-66-4 = 0 Gew. % all applications CH ChemRRV, Anhang | EU REACH-VO. Anh. XVII Alkanes, C10-13, chloro (Short Chain Chlorinated 85535-84-8 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) Paraffins) Aluminosilicate Refractory Ceramic Fibres are fibres = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (μm) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight Ammonium dichromate 7789-09-5 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV | EU REACH-VO. Anh. XIV (Kandidatenliste) Ammonium pentadecafluorooctanoate (APFO) 3825-26-1 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) © Heidelberger Druckmaschinen AG Guidline for Cooperation with Suppliers 01.2008 Appendix 14.1_INT Ingredients Prohibited Substances – Mechanics Version: April 2014, Page: 3 of 10 Substance CAS NR. Limit prohibited Exception Regulation Amosite 12172-73-5 = 0 Gew. % all applications CH ChemRRV, Anhang | EU REACH-VO. Anh. XVII Anthophyllite 77536-67-5 = 0 Gew. % all applications CH ChemRRV, Anhang | EU REACH-VO. Anh. XVII Anthracene 120-12-7 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Anthracene 120-12-7 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) Anthracene oil 90640-80-5 = 3 Gew. % as substances or in mixtures EU REACH-VO. Anh. XVII intended for the treatment of wood Arsenic acid 7778-39-4 = 0,1 Gew. % EU REACH-VO. Anh. XIV (Kandidatenliste) Arsenic compounds = 0 Gew. % As substances or in mixtures EU REACH-VO. Anh. XVII a) intended for use to prevent the fouling by micro-organisms, plants or animals of any totally or partly submerged appliances or equipment, b) intended for use in the treatment of industrial waters, c) used in preservation of wood Benzidine 92-87-5 < 0,1 Gew. % all applications EU REACH-VO. Anh. XVII Benzo(a)anthracene 56-55-3 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(a)pyrene 50-32-8 <= 1 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(b)fluoranthene 205-99-2 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(e)pyrene 192-97-2 <= 1 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(ghi)perylene 191-42-2 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(j)fluoranthene 205-82-3 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Benzo(k)fluoranthene 207-08-9 <= 10 mg/kg all applications D: GS-Zeichen (AtAV) Benzyl butyl phthalate (BBP) 85-68-7 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV | EU REACH-VO. Anh. XIV (Kandidatenliste) Biocidal products = 0 Gew. % all applications Biocidal products can be used if they are authorised in EU: VO 528/2012 [Biozid] accordance with Regulation (EU) No 528/2012 Biphenyl-4-ylamine 92-67-1 = 0,1 Gew. % all applications EU REACH-VO. Anh. XIV (Kandidatenliste) Bis(2-ethylhexyl)phthalate (DEHP) 117-81-7 = 0,1 Gew. % all applications EU REACH-VO.