Pt. 414, App. A 40 CFR Ch. I (7–1–12 Edition) APPENDIX A TO PART 414—NON- n-Butyl alcohol/Hydrogenation of n- COMPLEXED METAL-BEARING WASTE Butyraldehyde, Oxo process STREAMS AND CYANIDE-BEARING 1,4-Butanediol/Hydrogenation of 1,4- butynediol WASTE STREAMS Butryolactone/Dehydrogenation of 1,4- Chromium butanediol Caprolactam/From cyclohexane via Methylhydroabietate/Esterification of cyclohexanone and its oxime hydroabietic acid (rosin) with methanol Lilian (hydroxydihydrocitronellal)/Hydra- Acrylic acid/Oxidation of propylene via acro- tion and oxidation of citronellol lein 1,2-Dichloroethane/Oxyhydrochlorination of N-butyl alcohol/Hydrogenation of n- ethylene Butyraldehyde, Oxo process Dialkyldithiocarbamates, metal salts/ Cyclohexanone/From phenol via Dialkylamines + carbon disulfide cyclohexanol by hydrogenation-dehydro- 2-Ethylhexanol/from n-Butyraldehyde by genation Aldo condensation and hydrogenation Fatty amines/Hydrogenation of fatty nitriles Fatty amines/Hydrogenation of fatty nitriles (batch) (batch) Helioptropin/Oxidation of isosafrole, chro- Geraniol/B-Myrcene + Hydrogen chloride, mium catalyst esterification of geranyl chloride, hydrol- Isobutanol/Hydrogenation of ysis of geranyl acetate isobutyraldehyde, Oxo process Furfuryl alcohol/Hydrogenation of furfural Cyclohexyl Mercaptan/Cyclohexanol + Hy- Geranial (Citral)/Oxidation of geraniol (cop- drogen sulfide per catalyst) Ethyl Mercaptan/Ethanol + Hydrogen sulfide Glyoxal/Oxidation of ethylene glycol Methanol/H.P. Synthesis from natural gas Isobutanol/Hydrogenation of via synthetic gas isobutyraldehyde, Oxo process Oxo Alcohols, C7–C11/Carbonation & hydro- Isopropanol/Catalytic hydrogenation of ace- genation of C6–C10 Olefins tone Polyoxypropylene diamine/Polypropylene 2-Mercaptobenzothiazoles, copper salt/2- glycol + Ammonia Mercaptobenzothiazole + copper salt n-Propyl alcohol/Hydrogenation of Methanol/High pressure synthesis from nat- propionaldehyde, Oxo process ural gas via synthetic gas SAN resin/Suspension polymerization Methanol/Low pressure synthesis from nat- Styrene/Dehydrogenation of ethylbenzene ural gas via synthetic gas Styrene/Dehydration of methyl benzyl alco- Methyl ethyl ketone/Dehydrogenation of sec- hol (coproduct of propylene oxide) Butanol 1-Tetralol, 1-Tetralone mix/Oxidation of Oxo alcohols, C7–C11/Carbonation & hydro- tetralin (1,2,3,4-Tetrahydronaphthalene) genation of C6–C10 olefins 3,3,3-Trifluoropropene/Catalyzed hydrogen Phenol/Liquid phase oxidation of benzoic fluoride exchange with chlorinated pro- acid pane Polyoxyalkylene amines/Polyoxyalkylene Vinyl toluene/Dehydrogenation (thermal) of glycol + ammonia ethyltoluene Polyphenylene oxide/Solution polymeriza- tion of 2,6-xylenol by oxidative coupling Copper (cuprous salt catalyst) Methylhydroabietate/Esterification of Polyoxypropylene diamine/Polypropylene hydroabietic acid (rosin) with methanol glycol + Ammonia Acetaldehyde/Oxidation of ethylene with cu- Quinaldine (dye intermediate)/Skraup reac- pric chloride catalyst tion of aniline + crotonaldehyde Acetic acid/Catalytic oxidation of butane Silicones, silicone fluids/Hydrolysis and con- Acetone/Dehydrogenation of isopropanol densation of chlorosilanes Acrylamide/Catalytic hydration of acrylo- Silicones, silicone rubbers/Hydrolysis and nitrile condensation of chlorosilanes Acrylic acid/Oxidation of propylene via acro- Silicones, silicone specialties (grease, disper- lein sion agents, defoamers & other products) Acrylonitrile/Propylene ammoxidation Silicones: Silicone resins/Hydrolysis & con- Adipic acid/Oxidation of cyclohexanol- densation of methyl, phenyl & vinyl cyclohexanone mixture chlorosilanes Adipic acid/Oxidation of cyclohexane via Silicones: Silicone fluids/Hydrolysis of cyclohexanol-cyclohexanone mixture chlorosilanes to acyclic & cyclic Allynitrile/Allychloride + sodium cyanide organosiloxanes Aniline/Hydrogenation of nitrobenzene Styrene/Dehydration of a-Methylbenzyl alco- Benzofurans, 2,3-Dihydro-2,2-dimethyl-7- hol (coproduct of propylene oxide) benzofuranol/ from o-Nitrophenol + Meth- Tetrachloroethylene (perchloroethylene)/ allyl chloride Oxyhydrochlorination of tetrachloroethane 240 VerDate Mar<15>2010 10:53 Aug 03, 2012 Jkt 226175 PO 00000 Frm 00250 Fmt 8010 Sfmt 8002 Y:\SGML\226175.XXX 226175 emcdonald on DSK7SPTVN1PROD with CFR Environmental Protection Agency Pt. 414, App. A Tris(anilino)s-triazine/Cyanuric chloride + Cycloparaffins/Catalytic hydrogenation of aniline + cogeners aromatics in kerosene solvent Trichloroethylene/Oxyhydrochlorination of Cyclohexanol/Hydrogenation of phenol, dis- tetrachloroethane tillation Unsaturated polyester resin/Reaction of ma- Cyclohexanone/From phenol via leic anhydride + phthalic anhydride + pro- cyclohexanol by hydrogenation-dehydro- pylene glycol polyester with styrene or genation methyl methacrylate Dialkyldithiocarbamates, metal salts/ Dialkylamines + carbon disulfide Lead Ethylamine/Reductive amination of ethanol Alkyd resin/Condensation polymerization Ethylamines (mono, di, tri)/Reductive Alkyd resins/Condensation polymerization of ammination (ammonia + hydrogen) of eth- phthalic anhydride + glycerin + vegetable anol oil esters Isoeugenol, high % trans/Separation of Dialkydithiocarbamates, metal salts/ mixed cis & trans isoeugenols Dialkylamines + carbon disulfide 2-Ethylhexanol/from n-Butyraldehyde by Thiuram (dimethyldithiocarbamate) Aldol condensation and hydrogenation hexasulfide/Dimethyldithiocarbamate + Fatty acids, hydrogenated/tallow & coco sulfur acids + Hydrogen Triphenylmethane dyes (methyl violet)/Con- Fatty amines/Hydrogenation of fatty nitriles densation of Formaldehyde + N- (batch) Methylaniline + N,N-dimethylaniline, oxi- Fatty amines/Hydrogenation of tallow & dation of reaction product coco nitriles 4,4′-Bis-(N,N-dimethylaniline) carbinol, Glyoxal-urea formaldehyde textile resin/con- Michler’s hydrol/Oxidation of 4,4′-Meth- densation to N-bis(hydroxymethyl) ureas & ylene-bis(N,N-dimethylaniline) with lead N,N′-(dihydroxyethyl) ureas oxide 11-hexadecenal/Coupling rxns, low pressure Naphthenic acid salts hydrogenation Stearic acid, metal salts/Neutralization with Hexahydrophthalic anhydride/Condensation a metallic base of butadiene & maleic anhydride (Diels- Alder reaction) + hydrogenation Nickel Isobutanol/Hydrogenation of Acetates, 7,11-Hexadecadien-1-ol isobutyraldehyde, Oxo process (gossyplure)/Coupling reactions, low pres- Diisobutyl amine/Ammonolysis of isobutanol sure hydrogenation, esterification Isopropyl amines (mono, di)/Reductive Acetates, 9-dodecen-1-ol (pheromone)/Cou- ammination (Ammonia + Hydrogen) of pling reactions, low pressure hydro- isopropanol genation, esterification Linalool/Pyrolysis of 2-Pinanol Acrylic acid/oxidation of propylene via acro- Methanol/High pressure synthesis from nat- lein ural gas via synthetic gas Acrylonitrile/Propylene ammoxidation Methanol/Low pressure sythesis fron natural n-Alkanes/Hydrogenation of C6-C22 alpha gas via synthetic gas olefins (ethylene oligomers) Methanol/Butane oxidation Adiponitrile/Direct cyanation of butadiene Tris-(hydroxymethyl) methyl amine/Hydro- Alkyl amines/Amination of alcohols genation of tris(hydroxymethyl) 4-Aminoacetanilide/Hydrogenation of 4- nitromethane Nitroacetanilide N-Methyl morpholine/Morpholine + Meth- BTX/Hydrogenation of olefins (cyclohexenes) anol Terphenyls, hydrogenated/Nickel catalyst, N-Ethyl morpholine/Morpholine + Ethanol hydrogenation of terphenyl 2-Methyl-7,8-epoxy octadecane/Coupling re- Bisphenol-A, hydrogenated actions, low pressure hydrogenation, (Biscyclohexanol-A)/Hydrogenation of epoxidation Bisphenol-A Alpha-Olefins/Ethylene oligomer, & Zeigler Butadiene (1,3)/Extractive distillation of C–4 Cat. pyrolyzates Petroleum hydrocarbon resins, hydro- n-Butanol/Hydrogenation of n- genated/Hydrogenation of petroleum hy- Butyraldehyde, Oxo process drocarbon resin products 1,3-Butylene glycol/Hydrogenation of Pinane/Hydrogenation of A-Pinene acetaldol 2-Pinanol/Reduction of pinane hydroperoxide 1,4-Butanediol/Hydrogenation of 1,4- Bis-(p-Octylphenol) sulfide, Nickel salt/p- butynediol Octylphenol + sulfur chloride (S2C12), neu- Butylenes (mixed)/Distillation pf C4 tralize with Nickel base pyrolyzates Piperazine/Reductive amination of ethanol 4-Chloro-2-aminophenol/Hydrogenation of 4- amine (ammonia & hydrogenation, metal Chloro-2-nitrophenol catalyst) Lilial (hydroxydihydrocitronellal)/Hydration N,N-Dimethylpiperazine/Condensation piper- and oxidation of citronellol azine + formaldehyde, hydrogenation 241 VerDate Mar<15>2010 10:53 Aug 03, 2012 Jkt 226175 PO 00000 Frm 00251 Fmt 8010 Sfmt 8002 Y:\SGML\226175.XXX 226175 emcdonald on DSK7SPTVN1PROD with CFR Pt. 414, App. A 40 CFR Ch. I (7–1–12 Edition) Polyoxylalkylene amines/Polyoxyalkylene Glyoxal-urea formaldehyde textile resin/Con- glycol + Ammonia densation to N-bis (hydroxymethyl) ureas Polyoxypropylene diamine/Polypropylene + N,N′-(Dihydroxyethyl) ureas glycol + Ammonia Isobutanol/Hydrogenation of 2-Amino-2-methyl-1-propanol/Hydrogenation isobutyraldehyde, Oxo process of 2-Nitro 2-methyl-1-propanol Isopropanol/Catalytic hydrogenation of ace- 3-Methoxypropyl amine/Reductive amination tone of acrylamide with methanol & hydrogen Methallylidene diacetate/Condensation of 2- N-Propylamine/Reductive ammination (am- Methypropenal + acetic anhydride monia + hydrogen) of n-propanol Methanol/Low pressure sythesis from nat- Sorbitol/Hydrogenation of sugars ural gas via synthetic gas Sulfolane/Condensation butadiene + sulfur Methyl chloride/Hydrochlorination of meth- dioxide, Hydrogenation anol Thionocarbamates,