Z. Kristallogr. NCS 2018; 233(4): 603–604 Feng Yi-Min, Guo Hong-Mei, Liu Qing-Yun and Tai Xi-Shi* The crystal structure of poly[µ2-aqua-(µ2-2- naphthylamine-1-sulfonato-κ3O,O′:O′′)sodium(I)], C10H10N1O4S1Na Table 1: Data collection and handling. Crystal: Yellow block Size: 0.21 × 0.20 × 0.18 mm Wavelength: Mo Kα radiation (0.71073 Å) µ: 0.32 mm−1 Diffractometer, scan mode: Bruker SMART, φ and ω-scans θmax, completeness: 25°, >99% N(hkl)measured, N(hkl)unique, Rint: 8472, 2023, 0.045 Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 1903 N(param)refined: 154 Programs: Bruker programs [1], SHELX [2, 3], DIAMOND [4] https://doi.org/10.1515/ncrs-2017-0362 Received February 2, 2018; accepted May 3, 2018; available online May 18, 2018 Table 2: Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2). Abstract C10H10N1O4S1Na, monoclinic, P21/c, a = 16.737(3) Å, Atom x y z Uiso*/Ueq = = = b 6.6610(13) Å, c 10.427(2) Å, β 97.69(3)°, O1 0.37575(7) 0.24350(17) 0.25407(11) 0.0310(3) 3 2 V = 1152.0(4) Å , Z = 4, Rgt(F) = 0.0419, wRref(F ) = 0.1104, O1W 0.59036(8) 0.45177(18) 0.05298(12) 0.0362(3) T = 293(2) K. H1WB 0.6248 0.3834 0.0194 0.054* H1WA 0.6076 0.5225 0.1171 0.054* CCDC no.: 1577211 O2 0.40234(7) 0.43095(19) 0.45424(11) 0.0341(3) O3 0.44021(7) 0.56489(18) 0.25648(12) 0.0347(3) The crystal structure is shown in the figure. Tables 1 and 2 N1 0.32688(11) 0.8056(2) 0.13482(16) 0.0448(4) contain details on crystal structure and measurement condi- H1A 0.3747 0.7567 0.1389 0.054* tions and a list of the atoms including atomic coordinates and H1B 0.3135 0.9086 0.0870 0.054* displacement parameters. S1 0.38247(2) 0.44110(6) 0.31509(3) 0.02387(18) Na1 0.47302(4) 0.28467(11) 0.09829(6) 0.0316(2) Source of materials C1 0.28589(10) 0.5533(2) 0.28515(16) 0.0258(4) C2 0.27173(11) 0.7190(3) 0.20493(16) 0.0343(4) 0.222 g 2-Naphthylamine-1-sulfonic acid (1.0 mmol) and C3 0.19264(13) 0.8026(3) 0.1872(2) 0.0518(6) 0.04 g NaOH (1.0 mmol) were dissolved in 5 mL H2O at H3A 0.1824 0.9160 0.1356 0.062* C4 0.13208(13) 0.7208(4) 0.2437(2) 0.0571(6) H4A 0.0815 0.7808 0.2307 0.069* *Corresponding author: Tai Xi-Shi, College of Chemistry and C5 0.14326(11) 0.5472(3) 0.3218(2) 0.0431(5) Chemical Engineering, Weifang University, Weifang, Shandong C6 0.07905(13) 0.4573(4) 0.3775(3) 0.0597(7) 261061, P.R. China, e-mail: [email protected] H6A 0.0282 0.5160 0.3632 0.072* Feng Yi-Min: College of Chemistry and Chemical Engineering, C7 0.08926(14) 0.2911(4) 0.4498(3) 0.0653(7) Weifang University, Weifang, Shandong 261061, P.R. China H7A 0.0460 0.2342 0.4840 0.078* Guo Hong-Mei: College of Chemistry and Chemical Engineering, C8 0.16576(13) 0.2043(4) 0.4732(2) 0.0537(6) Shandong Vocational Animal Science and Veterinary College, H8A 0.1734 0.0892 0.5238 0.064* Weifang, Shandong 261061, P.R. China C9 0.23003(11) 0.2869(3) 0.42210(19) 0.0395(4) Liu Qing-Yun: College of Chemistry and Environmental Engineering, H9A 0.2804 0.2267 0.4396 0.047* Shandong University of Science and Technology, Qingdao, C10 0.22142(10) 0.4606(3) 0.34390(16) 0.0303(4) Shandong 266590, P.R. China Open Access. © 2018 Feng Yi-Min et al., published by De Gruyter. This work is licensed under the Creative Commons Attribution- NonCommercial-NoDerivatives 4.0 License. 604 | Yi-Min et al.: C10H10N1O4S1Na room temperature, then 10 mL CH3CH2OH containing 0.121 g 3. Sheldrick, G. M.: Crystal structure refinement with SHELXTL. 2-acetylpyridine (1.0 mmol) was dropped with stirring. The Acta Crystallogr. C71 (2015) 3–8. mixture was stirred for 5 h at 60 °C. After cooling, the yellow 4. Brandenburg K.: DIAMOND. Visual Crystal Structure Infor- mation System. Ver. 3.2. Crystal Impact, Bonn, Germany products were obtained by filtering. The crystals of the title (2012). structure were obtained by slow evaporating the methanol 5. Chen, X.-M.; Liu, Z.-J.; Deng, T.-L.: Crystal structure of 2 solution at room temperature within 25 days. Elemental anal- poly[diaqua-(u2-4,4′-bipyridine-k N:N′)manganese(II)] ysis calc. for C10H10N1O4S1Na: C, 45.59, H, 3.80, N, 5.32(%); bis(4-chlorobenzenesulfonate)-4,4′-bipyridine-water Found: C, 45.39, H, 4.16, N, 5.02(%). (1/1/2) C42H40Cl2MnN6O10S2. Z. Kristallogr. NCS 232 (2017) 513–515. Experimental details 6. Busse, M.; Andrews, P.-C.; Junk, P.-C.: Synthesis and struc- ture of silver amino-arenesulfonates. Eur. J. Inorg. Chem. 2012 Hydrogen atoms were positioned based on geometric consid- (2012) 1061–1071. erations. 7. 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