JWST683-IND JWST683-Hill Printer: Yet to Come March 3, 2016 12:26 8.5in×11in INDEX Note: See pages xvii–xviii for list of acronyms. Academic Labs Rule, 1-42 Backdraft, 5-252 accidents, 1-17 bacteria, 2-94, 4-210 acetic acid, 3-131, 5-243 base, strong, 5-260 glacial, 1-60, 8-504 beta particles, 5-331 acetone, 2-72 Bhopal, India, 6-365, 7-490 acid anhydrides, 5-263 bicycloheptadiene dibromides, 6-355 acid, strong, 5-260 bio-hazard symbol, 4-211 acquired immunodeficiency syndrome, 4-210 biological exposure indices, 6-394 activated charcoal, 6-392 biological safety cabinet, 7-471 surface area, 5-350 classes, 7-472 activation energy barrier, 5-237 schematic, 7-473 active metals, 2-96, 2-100 biomonitoring, 6-393 acute radiation, effects of, 2-100 biosafety aerosols, 3-124 decontamination, 7-475 air exchange rate, 7-437 levels, 7-470 air sampling, 6-391 Biosafety in Microbiological and Biomedical Laboratories, 1-43, airborne concentrations, dimensions, 6-373 4-210, 7-470 ALARA, 7-458 bis(chloromethyl)ether, 4-201 allergen, 4-187 bleach, 7-475 allyl alcohol, 6-374 bloodborne pathogens, 4-211 alpha particles, 5-330 Bodner, George, 1-55 American Conference of Governmental Industrial Hygienists, boiling liquid expanding vapor explosion, 5-254, 5-338 6-382 Borgias, 8-535 American National Standards Institute, 3-144 Bretherick’s Handbook of Reactive Chemical Hazards, 5-290, ammoniacal silver solutions, 8-511 5-346 Anastas, Paul, 1-47 bromine, 4-169 angiosarcoma, 4-185 Bruntland Report, 1-51 ANSI Z87.1, 7-406 burns, 2-92 antagonistic effect, 4-176 from UV light, 5-321 antigen, 4-187 butylated hydroxytoluene, 5-281 Antiterrorism and Effective Death Penalty Act, 1-43 t-butyllithium, 7-429 aqua regia, 5-242, 6-397 buying chemicals, 8-523 Arrhenius equation, 5-296, 5-345 as low as reasonably achievable, 5-330, 7-458COPYRIGHTEDcalcium MATERIAL gluconate, 5-244 asphyxiant cancer, 4-201 chemical, 4-189 carbon dioxide, 5-267 simple, 3-139, 4-187 carbon disulfide, 6-377 atom economy, 1-25 carbon monoxide, 4-189, 5-251 Aum Shinrikyo, 8-535 carbon nanotube, 4-217 authority having jurisdiction, 8-507 carboxyhemoglobin, 4-189 autoignition temperature, 5-233 carcinogen, 4-202 automated external defibrillator, 2-91 occurrence, 4-203 azide, 6-397 carcinogens, select, 4-204 Laboratory Safety for Chemistry Students, Second Edition. Robert H. Hill, Jr. and David C. Finster. © 2016 John Wiley & Sons, Inc. Published 2016 by John Wiley & Sons, Inc. I-549 JWST683-IND JWST683-Hill Printer: Yet to Come March 3, 2016 12:26 8.5in×11in INDEX CAS number, 3-132 features, 7-439 catalytic converter, 5-351 measuring airflow, 7-440 ceiling level, 6-383 perchloric acid, 7-440 cells chemical hygiene officer, 1-35, 1-41, 3-164 germ, 4-204 chemical hygiene plan, 1-41 somatic, 4-204 components, 3-164 Centers for Disease Control and Prevention, 1-43 chemical storage, 8-526 centrifuges, 7-452 chemical storage cabinet, 8-504 chelation therapy, 7-456 chemical wastes, F, K, P, and U lists, 8-513 Chemical Abstracts Service, 3-132, 3-142 chemicals with explosive properties, 5-289 chemical compatible groupings, 8-530 chemicals, testing, 3-143 Chemical Connections chemophobic, 4-186 acids, strong versus weak, 5-242 Chernobyl, 5-330 activated charcoal, 6-392 chloracne, 4-193 airborne concentrations, dimensions, 6-373 Chloraseptic, 5-246 Arrhenius equation, reaction rate, 5-343 chlorine dioxide, 7-476 atom economy, 1-25 chlorobenzaldehyde phenylhydrazone, 4-169 automotive catalytic converters, 5-349 chloromethyl methyl ether, 6-377 bond energies, heats of reaction, 5-250 chromatography, 7-451 CO2 extinguisher, principles, 2-98 chromic acid, 7-405 cryogen, spilled, O2 concentrations, 5-337 chromium(VI), 1-15 decontamination, microbiological agents, 7-475 Clausius–Clapeyron equation, 3-125, 5-254 enzymes, 5-530 Clean Air Act, 1-14 explosions, nitric acid, 8-512 Clean Water Act, 1-14 explosives, 5-290 clothing in the lab, 7-412 extinguishing fires, 2-73 Code of Federal Regulations, 1-39 fire extinguishers, chemicals used in, 2-99 combustible, 5-233, 5-234 firefighters love water, 2-77 conditionally exempt small quantity, 8-513 flammability halogenated solvents, 2-97 conductor, 5-306 free radical autoxidation, 5-279 contact dermatitis, 4-186 gas density, 4-187 contact lens, 7-409 gas expansion factor, 5-288 corrosives, 5-223, 5-241 glass, laboratory types, 5-299 pictogram, 5-224 gloves, polymers used for, 7-433 cryogen, 5-337 Grignard reagents, safety, 5-345 cryogenic, 5-267 heat of solution, NaOH, KOH, 5-226 cyanides, 8-501 Lewis acid-base theory, predict interactions, 4-189 cyclotrimethylenetrinitramine, 8-534 meaning, concentrated, dilute, 5-225 oxygen balance, 5-294 de minimus, 6-363 parts per million (ppm), 6-384 deflagration, 5-253 permeability testing, gloves, 7-432 deionized water, 3-157 peroxide, inhibiting, 5-282 Delaney Clause, 6-363 radiation shielding, 7-459 Department of Health and Human Services, 1-43 radioactive decay, 5-327 Department of Homeland Security, 1-44 refrigerator, explosive concentrations, 7-453 Department of Labor, 1-39 smell, odor thresholds, 7-419 detonation, 5-287 solubility, storage, elimination, 4-196 Dewar flask, 5-339 steam, from liquid water, 5-252 diacetyl, 4-185 stoichiometry, 5-233 diaminopropane, 7-484 structure-activity relationships, 4-173 diatomic halogens, 5-245 sublimation hazards, 7-437 dibromochloropropane, 4-176 threshold limit value (TLV), calculation, 6-383 dihydrogen oxide, 3-157 trifluoroacetic acid, properties, treatments, 5-245 dimethyl sulfate, 3-149, 4-201 vapor pressure, predicting liquid, 3-124 dimethylmercury, 6-394, 7-411 Chemical Facility Anti–terrorism Standards, 1-44 dioxin, 4-175 chemical hood, 7-420 disinfectant, 4-213 airflow, 7-421 distillation, 7-451 ductless, 7-442 DOE Explosives Safety Manual, 5-296 I-550 JWST683-IND JWST683-Hill Printer: Yet to Come March 3, 2016 12:26 8.5in×11in INDEX dose–response curve, 4-170, 4-180, 4-197 influenced by structure, 5-239 dry air, 3-123 limits, 5-233 dust explosion, 5-291 flammable, 5-232, 5-234 dusts, 3-124, 3-126 flash point, 5-233 flashover, 5-251 Ebola, 4-209, 7-470 fluorescent stain, 2-84 education, safety, 1-8 1-fluoro-2,4-dinitrobenzene, 3-142 effects of oxygen deficiency, 5-252 fomite, 4-209 Einstein, Albert, 5-278, 7-484 formaldehyde, 1-33, 6-390, 7-476 electric shock, 2-90, 2-93 40 CFR Part 260, 1-42 electrical hazard, 5-306 Fukushima Daiichi, 5-330 electrophoresis, 5-305 fulminating silver, 8-509 emergency fumes, 3-124 medical, 2-91 fuming, 3-125 responding to, 2-117 Emergency Planning and Community Right-to-Know Act, 1-44 Gambler, The, 6-369 Environmental Protection Agency, 1-41 gamma rays, 5-332 epidemiology, 4-194 gas cylinders, 5-268 ethanedithiol, 8-499 gas leak, 2-88, 2-112 ethanol, 6-362 Geiger-Muller counter, 7-457 ether, 3-132, 5-249, 5-278 Geller, Scott, 1-5, 1-29 ethic general duty clause, 3-163 safety, 1-36 German proverb, 2-90 student safety, 1-10 Globally Harmonized System of Classification and Labelling of ethics, 1-9 Chemicals, 3-133, 3-144, 6-370 ethylene glycol, 4-173, 5-344 health hazards, 6-370 ethylene oxide, 7-475 glovebox, 7-441 exit signs, 2-68 gloves, 7-413 exposure, 1-4 disposable, 7-414 extinguisher insulated, 5-342 carbon dioxide, 2-76, 2-97 latex, 4-213, 7-411 Class D powder, 2-76 nitrile, 4-213 dry chemical, 2-76 online resources, 7-434 Halon, 2-99 permeability, 7-432 pressurized water, 2-76 removing, 7-415 extractions, 7-452 reusing, 3-121 eyewash station, 2-85 green chemistry, 1-13 Green Chemistry Institute, 1-14 face shield, 7-426 Green Chemistry: Theory and Practice,1-47 Fahlberg, Constantine, 3-123 Grignard reagent, 5-344, 5-347 Federal Insecticide, Fungicide, and Rodenticide Act, 6-364 ground fault circuit interrupter, 5-305, 5-307 fetal alcohol syndrome, 4-190 fire Halon, 2-97 Class A, 2-73, 2-96 haptens, 4-187 Class B, 2-73, 2-96 Hawthorne, Nathaniel, 4-185 Class C, 2-74, 2-99 hazard, 1-3, 6-356 Class D, 2-74, 2-100 hazard categories, using OEL data, 6-385 classes of, 2-73, 2-96 hazard classes, GHS, 3-138 dangers from, 5-251 Hazard Communication, 1-41 extinguisher, 2-76 Hazard Communication Standard, 3-136, 3-143 flash, 5-253 hazard statement, 3-133 in laboratory hoods, 2-100 Hazardous Materials Identification System, 3-140 metal, 5-263 Hazardous Substances Data Bank, 6-387 fire alarm, 2-68 Hazardous Waste Operations and Emergency Response, 1-41, fire tetrahedron, 2-75, 5-236 2-108 fire triangle, 2-74, 5-235, 5-250 Hazards Identification and Evaluation Task Force, 6-400 five whys, 1-19 heat guns, 7-450 flammability heating mantles, 7-449 I-551 JWST683-IND JWST683-Hill Printer: Yet to Come March 3, 2016 12:26 8.5in×11in INDEX hemoglobin, 4-189 explosion, liquid nitrogen, 5-267 Henry’s law, 5-228 explosion, lithium aluminum hydride, 1-39 hepatitis B, 4-212 explosion, nitric acid, 6-362 hepatotoxic, 4-191 explosion, organic, 5-257 hexamethylene triperoxide diamine, 8-534 explosion, reaction, 5-249 hexane, 2-96 explosion, refrigerator, 7-446 high efficiency particulate air, 7-471 explosion, rotary evaporator, 5-278 Hiroshima, 5-330 explosion, runaway, 5-342 house vacuum system, 5-298 explosion, scale-up, 7-490 housekeeping, 5-313, 5-318 explosion, sealed vial, 6-397 human immunodeficiency virus, 4-210 explosion, sodium azide, 3-149 HVAC system, 7-438 explosion, Tollens’, 8-509 hydrofluoric acid, 3-163, 5-244 explosion, undergraduate, 2-114 hydrogen peroxide vapor, 7-476 explosives, chemist, 8-534 hydrogen sulfide, 6-369 exposure, carcinogens, 4-201 hydrogenation, 5-300 exposure, dioxin, 4-179 using palladium catalyst, 5-350 exposure, fatal,