O-Acetyl Mandelic Acid, 9 N-Acetyl Phenylalanine Ethyl Esters, 329

O-Acetyl Mandelic Acid, 9 N-Acetyl Phenylalanine Ethyl Esters, 329

Index A Antihistamines, 331 Absolute configuration, 1 α-Arabinopyranosides, 15 (S)-O-Acetyl mandelic acid, 9 Aromatics, 314 N-Acetyl phenylalanine ethyl esters, 329 α-Arylalkylamines, 79 Achiral chromatography, 301 N-Aryl-1,3,2-benzodithiazole-1-oxides, 258 Acrylamide (AM), 153 3-Arylcarbonyl-2,2-dimethyloxazolidine- Activation parameters, 231, 252 4-carboxylic acids, 13 N-Acyl valine tert-butylamide, 328 Arylnaphthalenes, 260 Adamantanones, 43 3-Aryl-2-oxo-4-oxazolidinones, 43 Adrenaline, 186 Atropisomers, 40, 78, 89, 233 Alcohols, 15, 320 Azaphosphatrane-hemicryptophane cages, 82 boronic esters formation, 193 cis-2-Alkyl-3-oxy-tetrahydropyran, 106 Allene dimethyl-2,3-pentadienedioate, 254 Amides, 78, 316 B Amines, 16 Benzene-1,3-biscarboxamide, 85 Amino acid esters, 17 Benzimidazole, 93 Amino acid methyl esters, 101 Benzo[de]isoquinoline 1,3-dione amino N-3,5-dinitrobenzoyl derivatives, 83 acids, 79 L-/D-Amino acid oxidase, 148 Benzodiazepines, 262 Amino acids, 30, 111, 162, 271, 281, 304, 309 syn-Benzotricamphor, 192 extraterrestrial, 285 3-(Benzoyl)-(1R)-camphor, 39 Amino alcohols, 12, 18, 20, 23, 29, 36, 78, 80, trans-N-Benzylhydroxypiperidinemethanols, 12 101, 111, 195, 321 (S)-1-Benzyl-6-methylpiperazine-2,5-dione, 79 cis-4-Amino-1-benzyl-3-phenylpiperidine, 19 1-N-Benzyloxycarbonylaminoalkanephosphonic L-4-Amino-phenylalanine, 155 acid, 88 Aminophosphonates, 3 Bicyclodipeptide bearing calix[4]arenes, 158 3-Aminopropyltriethoxysilane (APTES), 140 Bicyclo[3.1.0]hex-2-ene-6-carboxylic acid, 305 Anhydrides, 15 Binaphthyl CSAs, 77 0 0 Anisotropy spectroscopy, 271, 275 1,1 -Binaphthyl-2,2 -diol (BINOL), 77, 325 0 0 2-(Anthracene-2,3-dicarboximido) 1,1 -Binapthalene-2,2 -dithiol (BNSH), 157 cyclohexane carboxylic acid, 13 BINOL, 77, 323 2-(9-Anthryl)-2-tert-butoxyacetic acid, 10 BINPHAT, 81 1-(9-Anthryl)ethylamine, 16 Biopolymers, 271 0 α-(9-Anthryl)-α-methoxyacetic acid N,N -Bis(6-acylamino-2-pyridinyl) (9-AMA), 5 isophthalamide, 101 0 1-Anthryl-2,2,2-trifluoroethanol, 321 Bis[(R)-1,1 -bi-2-naphtholato]borate, 82 341 342 Index 9,10-Bis(2,3-dimethylphenyl)phenanthrenes, 1-[2-Carboxy-6-(trifluoromethyl)phenyl] 252 pyrrole-2-carboxylic acid, 77 Bis-imidazole N-oxides, 78 Carboxylic acids, 4, 75, 305, 326 N,N0-Bis(mesitylmethyl)-1,2-diphenyl- Carceplexes, 191 1,2-ethanediamine, 47 Carcerands, 191 Bis-nor-seco-cucurbit[6]uril, 189 Carvone, 159 Bis[(S)-α-phenylethyl]cyclohexane- Catechin, 89, 90 1,2-diamine, 21 Chemiresistors, 158 α,α0-(Bis-trifluoromethyl)-9,10- Chemocapacitors, 161 anthracenedimethanol, 84 Chiral cages, 177 Borate CSAs, 83 Chiral derivatizing agents (CDA), 1, 70 Boronate esters of (R)/(S)-2-(1-methoxyethyl) Chiral discrimination, 69 phenylboronic acid, 23 Chiral ionic liquids (CILs), 110 Boron-containing reagents, 22 Chiral lanthanide shift reagents (CLSRs), 70 Boronic acids, 23 Chiral ligand exchange potentiometry Bovine serum albumin (BSA), 156 (CLEP), 139 Bulk acoustic wave (BAW) sensors, 149 Chiral liquid crystals, 1 2-Butanol, 15, 39, 158, 159 Chiral recognition, 177, 301 cis-But-2-ene-1,4-diols, 77 Chiral sensors, 133 2-tert-Butoxy-2-(2-naphthyl)acetic acid, 10 Chiral shift reagent (CSR), 83 2-tert-Butoxy-2-phenylacetic acid, 10 Chiral solvating agents (CSAs), 1, 69, 70 p-tert-Butylcalix[4]arene, 97 Chiral stationary phases (CSPs), 83, 236 18-(tert-Butyldimethylsilyloxy)- Chirality, 231, 271 5-octadecayne-7-ol, 7 Chirasil-nickel(II) (polysiloxane-anchored 3-(tert-Butylhydroxymethylene)-(1R)- nickel(II)-bis camphor, 37 [3-(heptafluorobutanoyl)-(1R)- tert-Butyl-1-(2-methyl-1-naphthyl)phosphine camphorate]), 252 oxide, 258 Chiroptical properties, 177 2-Butylphenyl ethers, 42 2-Chloro-(4R,5R)-bis[(1S,2S,5R)-menth- Butylphenylphosphinothioic acid, 78 1-yloxycarbonyl)]- 1,3,2-dioxaphospholane, 21 1-Chloro-2,2-dimethylaziridine, 253, 255 C Chloromezanone, 334 Cages, supramolecular, 177 10-(3-Chlorophenyl)-6,8,9,10-tetrahydrobenzo Calixarenes, 182 [b][1,8]naphthyridin-5(7H)-one calix[4]arenes, 97, 136, 183 (Telenzepine), 258 Calix[4]crown carboxylic acid, 97 2-Chloropropionic acid, 80, 102 Calix[4]resorcinarenes, 3, 32, 98 Chloropyridin, 334 Camazepam, 334 Chlorpheniramine, 26, 331 Camphor sulfonamide, 19 Chlorthalidone, 257, 262 Camphor sulfonyl chloride, 19 Cholic acid, 207 Camphoric acid, 305 Cineole, 321 (1S)-(+)-10-Camphorsulfonate, 111 Circular dichroism, 147, 167, 271, 274 Camphorsulfonic acid (CSA), 78, 141, 147 Circularly polarized radiation, 271 Capillary electrophoresis (CE), 133 Citronellol, 160 (S)-Captopril, 138, 148 Colletotrichum acutatum,7 Carbamates, 20, 87, 98, 318 Computer simulation, 231 Carbinoxamine, 25 Conductometric (or resistive) sensors, 158 Carbocyclic[11]paracyclophanes, 253 COSAC, 271, 289 Carbon black (CB)-chiral polymer Crown ethers, 28, 108 composites, 158 Crown-6-tetracarboxylic acid, 108 2-[4-(2-Carboxy-2-methylpropyl)phenyl] Cryptophanes, 42, 109, 111, 195 propionic acid, 116 Cryptophanol-A, 198 Index 343 Cucurbit[n]urils, 188 3,5-Dinitrobenzoyl-derived 1-naphthylethyl α-Cyano-α-fluoro-p-tolylacetic acid (CFTA), 5 amide, 84 Cyclic voltammetry (CV), 143 Dioxa[11]cyclophanes, 253 Cyclodextrins, 24, 90, 116, 136, 181, 292 Dioxolanoadamantanes, 43 hosts, 181 Dipeptides, 329 QCM, 150 2,2-Diphenyl-[1, 3]-dioxolane-4,5- Cyclohexane carboxamide, 318 dicarboxylic acid, 14 trans-1,2-Cyclohexane dicarboxylic acid, 23 2-(Diphenylmethanesulfinyl)acetamide (R,R)-1,2-Cyclohexanediamine, 103 (modafinil, MDL), 115 Cyclohexenols, endo/exo-monocyclic, 9 Diporphyrin receptor, 102 Cyclopentanones, 326 Disaccharides, 167 Cyclopeptides, 158 Distillation, 301 Cyclotribenzylene (CTB), 182, 195, 202 Disuccinimidyl suberate (DSS), 141 Cyclotriveratrylene, 182 3,4-Di-tert-butyl-1,3,4-oxadiazolidine, 256 Cycloveratrylenes, 42 Dithiolano adamantanes, 43 DNA aptamers, 167 Dopamine (DOPA), 162 D Doxylamine, 25, 332 cis-Decalin, 52 Drug formulations, chiral, 115 Deoxyribooligonucleotides, 145 Drugs, 231 Derivatizing agents, chiral, 4 Dynamic capillary electrophoresis (DCE), 1,6-Dialkylpiperazine-2,5-diones, 79 231, 261 1,2-Diaminocyclohexane (DACH), 78, 87, Dynamic gas chromatography (DGC), 102, 193 231, 244, 252 4,40-Diamino-2,20-diisopropylbiphenyl, 261 Dynamic high performance liquid 4,40-Diammonio-2,20-bis(trifluoromethyl) chromatography, 231, 256 biphenyl, 261 Dynamic supercritical fluid chromatography, Dibenzoyltartaric acid, 77, 169 231, 258 Dicampholylmethane, 37 Dysprosium, 26 (2,6-Dichloro-4-methoxyphenyl) (2,4-dichlorophenyl)methanol, 20 N,N0-Diethyl-4-vinyl-benzamidine, 169 E Differential pulse voltammetry (DPV), 143 Eburnamonine, 54 Diffusion-ordered NMR spectroscopy Electrical sensors, 158 (DOSY-NMR), 109 Electrochemical impedance spectroscopy (R)-Dihydroindenol, 314 (EIS), 143 Dihydroquinines, 316 Electrochemical quartz crystal microbalance 2,20-Dihydroxybenzophenone, 19 (EQCM) sensor, 153 2,20-Dihydroxy-1,10-binaphthalene Electrochemical sensors, 136 (BINOL), 18 Electropolymerization, 153 Di-(R,R)-1-[10-(1-hydroxy-2,2,2- α-Eleostearic acid, 51 trifluoroethyl)-9-anthryl]-2,2,2- Enalapril, 262 trifluoroethyl phthalate, 85 Enantiomeric differentiation, 1, 133 Diketones, 325 Enantiomeric excess, 69, 271 Diketopiperazine, 14 Enantiomerization, 231, 235 Dimethindene, 91 Enantioselective chromatography, 231 2,6-Dimethylenebicyclo[3.1.0]-hexane, 252 Encapsulation, 96 Dimethylformamide dimethylacetal Ephedrine, 111, 188 (DMF-DMA), 292 Epichlorohydrin, 109, 158 N,N-Dimethyl-1-(1-naphthyl)ethylamine, 46 1,2-Epoxybutane, 109 Dimethyl-1-phenylethylamine, 44, 46 Ethyl-2-(9-anthryl)-2-hydroxyacetate, 15 3,5-Dinitrobenzamides, 319 α-Ethylbenzylphenyl sulfide, 314 3,5-Dinitrobenzoyl amino acids, 89 Ethyl lactate, 169 344 Index 4-Ethyl-4-methyloctane (C*MeEtPrBu), 8 High performance liquid chromatography Europium, 38 (HPLC), 83, 133, 238 Homocalixarene hosts, 183 Homochirality, life, 285 F Homocysteine, 142 Faradaic impedance spectroscopy (FIS), 146 Host-guest systems, 177 Fatty acids, 50 Human serum albumin (HSA), 141, 156 α-Ferrocenylethylphosphine, 13 Hydroxyacids, 23, 304 Field effect transistors (FET), 141 4-Hydroxy-2-carboxymethyl-2- 4-Fluoro-2-formylphenylboronic acid, 22 cyclopentenone, 326 1-(o-Fluorophenyl)ethanol, 2 Hydroxycoumarin derivatives, 334 (S)-Flurbiprofen, 138 (+)-cis-4-Hydroxy-6-deoxyscytalone, 7 N-Fmoc-N0-Boc-L-tryptophan, 80 3-Hydroxyindolin-2-ones, 319 2-Formylphenylboronic acid, 22 α-Hydroxyisovaleric acid, 80 Fullerenes, 114, 189 3-Hydroxy-2-methylpropanoic acid, 44 α-Hydroxyphosphinates, 7 2-Hydroxy-3-trimethylaminopropyl-β-CD, 138 G Gamma-globulin, 144 Gas chromatography (GC), 94, 133, 168, 289 I Gibbs free activation energy, 252 (S)-Ibuprofen, 54, 77, 114, 116 GIOTTO, 288 Imination, 191 Glassy carbon electrode (GCE), 144 Indium tin oxide (ITO) glass, 139 Glucose, 15, 150, 168 Indoles, 33 sensors, 168 Interconversion, 231 OECT, 161 Ionic liquids (IL), 109 Glucose oxidase, 149 Ion-selective electrodes (ISE), 137 Glutamic acid, 162, 167 Ion-sensitive field effect transistors (ISFET), Glycopeptides, 89 141 β-Glycopyranosides, 15 Isobenzofuran-1,3-dione, 36 Glycosides, 15 N-Isobutyryl-cysteine (NIBC), 145 Goat serum albumin (GSA), 157 Isocyanates, 17 Gravimetric/mass sensors, 149 Isophthalate, 85 Isopropyl(trifluoro)lactate, 304, 308, 326 2,3-O-Isopropylidene-L-threitol, 191 H (1S,2S)-N-[(2-Isothiocyanato)cyclohexyl] Helicenediol, 332 trifluoromethanesulfonamide, 17 Hemicarceplexes, 191 Isothiouronium, chiral, 41 Hemicarcerands, 191 Hemicryptophanes, 202, 207 3-Heptafluorobutyryl-(1R)-camphor, 37 K Heptafluoro-2,2-dimethyl-3,5-octanedione, 40 Kemp’s acid diamide, 78 Heptakis(3-O-acetyl-2,6-di- Ketones,

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