Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 02/04/2014 Revision date: 02/13/2018 Supersedes: 02/13/2018 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form : Substance Substance name : Potassium Permanganate CAS-No. : 7722-64-7 Product code : LC19850 Formula : KMnO4 Synonyms : permanganate of potash / potassium salt permanganic acid 1.2. Recommended use and restrictions on use Use of the substance/mixture : Oxidant Bleaching agent Reagent Disinfectant Deodorizer Algicide Dyestuff/pigment: component Medicine Laboratory chemical Food industry: additive Insecticide Germicide Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Oxidizing solids Category 2 H272 May intensify fire; oxidizer Acute toxicity (oral) H302 Harmful if swallowed Category 4 Hazardous to the aquatic H400 Very toxic to aquatic life environment - Acute Hazard Category 1 Hazardous to the aquatic H410 Very toxic to aquatic life with long lasting effects environment - Chronic Hazard Category 1 Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : GHS03 GHS07 GHS09 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H272 - May intensify fire; oxidizer H302 - Harmful if swallowed 02/13/2018 EN (English US) Page 1 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations H410 - Very toxic to aquatic life with long lasting effects Precautionary statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from clothing, combustible materials P221 - Take any precaution to avoid mixing with combustibles P264 - Wash exposed skin thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 - If swallowed, rinse mouth P391 - Collect spillage. P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards which do not result in classification Other hazards not contributing to the : None under normal conditions. classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Substance type : Mono-constituent Name Product identifier % GHS -US classification Potassium Permanganate (CAS-No.) 7722-64-7 100 Ox. Sol. 2, H272 (Main constituent) Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of hazard classes and H-statements : see section 16 3.2. Mixtures Not applicable SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half -seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watc hing the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with st erile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation : AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Risk of lung edema. Symptoms/effects after skin contact : Tingling/irritation of the skin. May stain the skin. ON CONTINUOUS EXPOSURE/CONTACT: Caustic burns/corrosion of the skin. Symptoms/effects after eye contact : Corrosion of the eye tissue. Inflammation/damage of the eye tissue. ON CONTINUOUS EXPOSURE/CONTACT: Permanent eye damage. Symptoms/effects after ingestion : Nausea. Vomiting. Diarrhoea. Irritation of the gastric/intestinal mucosa. AFTER ABSORPTION OF LARGE QUANTITIES: Possible esophageal perforation. Shock. Slowing heart action. Low arterial pressure. Possible laryngeal spasm/oedema. Respiratory difficulties. 02/13/2018 EN (English US) 2/9 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Respiratory difficulties. Impairment of the nervous system. Movement disturbances. Coordination disorders. Myasthenia. Tremor. Paralysis. Cramps/uncontrolled muscular contractions. Impaired memory. Emotional instability. 4.3. Immediate medical attention and special treatment, if necessary No additional information available SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Adapt extinguishing media to the environment. Preferably : quantities of water. Unsuitable extinguishing media : No unsuitable extinguishing media known. 5.2. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Promotes combustion. Reactions involving a fire hazard: see "Reactivity Hazard". Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard". Reactivity : Decomposes on exposure to temperature rise: oxidation which increases fire hazard. Reacts with combustible materials: risk of spontaneous ignition. Violent to explosive reaction with (some) acids: release of toxic and corrosive gases/vapours. Reacts violently with many compounds e.g.: with organic material and with (strong) reducers. With (some) metals. With (increased) risk of fire/explosion. 5.3. Special protective equipment and precautions for fire-fighters Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Gloves. Face-shield. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. Dust cloud production: dust-tight suit. Reactivity hazard: compressed air/oxygen apparatus. Reactivity hazard: gas-tight suit. See "Material-Handling" to select protective clothing. Emergency procedures : Mark the danger area. Prevent dust cloud formation. No naked flames. Keep containers closed. Wash contaminated clothes. In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation. Measures in case of dust release : In case of dust production: keep upwind. Dust production: have neighbourhood close doors and windows. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Do not breathe dust. Emergency procedures : If a major spill occurs, all personnel should be immediately evacuated and the area ventilated. Stop release. Ventilate area. 6.2. Environmental precautions Prevent soil and water pollution. Prevent spreading in sewers. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water spray. If reacting: dilute toxic gas/vapour with water spray. Take account of toxic/corrosive precipitation water. Methods for