595 North Harrison Road Bellefonte, PA 16823-0048 USA Telephone 800-247-6628 ● 814-359-3441 Fax 800-447-3044 ● 814-359-3044 email: [email protected] sigma-aldrich.com/supelco Bulletin 925E SPME Applications Guide The SPME Applications Guide is a bibliographic resource of published technical articles about solid phase microextraction. With the continued growth of SPME, and its expansion into environmental, food, forensic, and other fields, we recognize the need for an organized bibliography. This guide should serve a useful purpose in your SPME research and analyses. This guide is for general information only. We have made every attempt to make the information as complete and accurate as possible. Where entries are missing, information was not available at the time of printing. NOTE: Because of copyright restrictions, Supelco cannot provide copies of the articles listed. If you desire copies, please refer to the publications cited. Using This Guide This guide is organized in an easy-to-use format. The references are Table of Contents grouped into application areas (see the Table of Contents) with the Application Area over 600 new references placed at the end of each area in bold. The Analyte/Matrix column identifies the class of analytes and the Books .................................................................... 2 sample matrix. The Literature Reference column provides the title of Foods .................................................................... 2 the article, journal reference, and authors. The next column de- scribes the SPME fiber and conditions used in the sample extraction. Polymers and Coatings .......................................... 48 The last column indicates the instrument used in the analysis. Natural Products .................................................... 51 Pharmaceuticals .................................................... 65 Key to Abbreviations Biological Matrices ................................................. 67 Abbrev. Description Toxicology ............................................................. 78 AED atomic emission detection Forensics ............................................................... 94 DVB divinylbenzene Environmental ....................................................... 99 ECD electron capture detection FID flame ionization detection Water .......................................................... 102 FPD flame photometric detection Pesticides ..................................................... 138 FTD flame thermonic detection Soil .............................................................. 149 GC gas chromatography HPLC high pressure liquid chromatography Air ............................................................... 157 ICP inductive coupled plasma Theory and Technique ......................................... 163 MS mass spectrometry Supelco SPME Literature ...................................... 181 MSD mass selective detection NPD nitrogen/phosphorus detection SPME Products .................................................... 182 PAD photodiode-array detection PDMS polydimethylsiloxane PICI positive ion chemical ionization SIM selective ion monitoring TCD thermionic-selective detection TED thermal energy detection VIS visible spectrophotometry sigma-aldrich.com/supelco SUPELCO 1 Bulletin 925E SPME Application Guide 6th Edition (New references added to the 6th edition are in bold) SPME Fiber / Analyte / Extraction Matrix Literature Reference Conditions Instrument Books Techniques for Analyzing Food Aroma, Supelco Cat. # 26589-u Marcel Decker ISBN: 0-8247-9788-4, Marsili, R. Solid Phase Microextraction: A Practical Guide Supelco Cat. # 26610-u Edited by SueAnn Scheppers Wercinski Marcel Decker 15BN: 0-8247-7058-7 Solid Phase Microextraction: Theory and Practice Supelco Cat. # 26591-u Edited by Janusz Pawliszyn VCH, New York, 275pp (1997) Applications of Solid Phase Microextraction Supelco Cat. # 26611-u Edited by Janusz Pawliszyn RSC Chromatography Monographs ISBN 0-85404-525-2 Royal Society of Chemistry 1999 Applied SPME, 1999, 364-371 Royal Society of Chemistry, Cambridge, UK Coden: 67TUA8 Talon, R, Montel, M. Foods 601 Aroma compounds Developments in extraction techniques and their Review article GC in food application to analysis of volatiles in foods Trends-Anal-Chem, May 2000, 19(5), 322-329 Sides, S., Robards, K., Helliwell, S. 602 Contaminants Application of SPME in Food Analysis Review article GC, LC, MS in Food J. Chromatogr. A (2000), 880(1+2), 35-62 Kataok, H., Lord, H., Pawliszyn, J. 784 Catechins, cafeine Automated in-tube solid phase microextraction coupled polypyrrole capillary LC-ES-MS in tes with HPLC-ES-MS for the determination of catechins and caffeine in tea Analyst (Cambridge, U. K.) (2000) 125(12), 2216-2222 Wu, J. C.; Xie, W.; Pawliszyn, J. 834 Caffeine Caffeine determination in beverages by SPME and GC-MS in beverages Ind. Bevande (2000) 29(170) 595-597, 605 Guidotti, Maurizio; Panzironi, Laura 8 Caffeine and flavors Solventless Determination of Caffeine in uncoated fiber GC-MS in coffee/tea/cola Beverages Using SPME with Fused Silica Fibers 5 min J. Chromatogr. 603: 185-191 (1992) Hawthorne, S., Miller, D., Arthur, C., Pawliszyn, J. 32 Flavors in Solid Phase Microextraction for Flavor Analysis 100µm PDMS GC/GC-MS coffee/fruit juice/ J. Agric. Food Chem, 42: 1925-1930 (1994) 10 min vegetable oil Peppard, T., Yang, X. 603 Volatiles Analysis of volatile contaminants in vegetable oils by 75µm Carboxen/PDMS GC-MS in vegetable oil headspace SPME with Carboxen-based fibers. 30-45 min @ 100°C J. Chromatogr. 873 (2000): 79-94 headspace Page, B., Lacroix, G. 39 Halogenated volatiles Application of SPME to the Headspace GC Analysis of GC in food Halogenated Volatiles in Selected Foods J. Chromatogr. 648 (1): 199-211 (1993) Page, B., Lacroix, G. Ambient temperature, unless otherwise indicated. 2 (New references added to the 6th edition are in bold) SPME Fiber / Analyte / Extraction Matrix Literature Reference Conditions Instrument 41 Fatty acids C2-C10 Determination of Fatty Acids Using SPME 85µm polyacrylate GC/GC-MS in water Anal. Chem: 67(23): 4396-4403 (1995) Low pH, salt Pan, L., Adams, M., Pawliszyn, J. derivative: 1-pyrene- diazomethane 42 Flavors in Measuring Flavors Using SPME 100µm PDMS GC-MS corn oil Food Quality January/February 1995, pp40-41 40°C, 45 min Mindrup, R. 925 Flavors, off-flavors Sample preparation for the analysis of flavors and Review article in food off-flavors in foods J. Chromatogr A, 2000, 873(1), 3-11 Wilkes, J., Conte, E., Kim, Y., Holcomb, M., Sutherland, J. Miller, D. 883 Flavors in Recent application of SPME for monitoring flavor 75µm Carboxen/PDMS GC-MS food components in foods 65µm DVB/PDMS Food Testing & Analysis Feb./March 2000, 17-20 Mindrup, R. 181 Flavors in SPME Associated with Microwave Assisted 100µm PDMS SIM GC-MS coffee, potato chips Extraction of Food Products pH 2, salt J. High Res. Chromatogr. 20 (4): 213-216 (1997) headspace Wang, Y., Bonella, M., Khaled, M., McNair, H. 10 min 60 Sulfur volatiles in Headspace SPME Analysis of Volatile Organic Sulfur truffle aroma Compounds in Black and White Truffle Aroma J. Agric. Food Chem, 43 (8): 2138-2143 (1995) Pelusio, F., Nilsson, T., Tino, R., Larsen, B., Montnarell, L. 830 Sulfur compounds Changes of aroma in shell eggs from egg shell Czech J. Food Sci (2000) 18, 231-233 Adamiec, J.; Dolezal, M.; Mikova, K.; Davidek, J 831 Sulfur compounds Limitations to the use of SPME for quantitation of mixtures of volatile organic sulfur compounds Anal. Chem (2001) 73(7) 1646-1649 Murray, R. A. 604 Aroma compounds Determination of major aroma impact compounds in 75µm Carboxen/PDMS GC-MS in fermented fermented cucumbers by SPME-GC-MS- 20min @50°C cucumbers Olfactometry detection NaCl added J. Chromatogr. Sci. (2000), 38(7), 307-314 Marsili, R., Miller, N. 61 Flavors in SPME of Flavor Compounds -- A Comparison of Two Fiber 100µm PDMS, GC-FID cinnamon bark Coatings and Discussion of the Rules of Thumb for Adsorption 85µm polyacrylate LC-GC 13 (11): 882-886 (1995) 120°C Yang, X., Peppard, T. headspace 62 Flavors in SPME and Chiral Gas Chromatography Separations 100µm PDMS GC-FID apple essence, LC-GC 13 (9): 734-740 (1995) 30°C or 40°C seeds, candy Mani, V., Woolley, C. headspace 772 Volatiles in Analysis of volatile constituents of mustard paste by GC/MS 100µm PDMS GC-MS mustard paste w/SPME and simultaneous distillation and extraction 30min @ 70°C Fenxi Huaxue (2000) 28(12) 1489-1492 Liu, B. in Chinese Ambient temperature, unless otherwise indicated. 3 (New references added to the 6th edition are in bold) SPME Fiber / Analyte / Extraction Matrix Literature Reference Conditions Instrument 854 Volatiles in Analysis of the volatile components in vanilla extracts and 85µm polyacrylate GC-MS vanilla extracts flavourings by SPME and gas chromatography 40min @20°C J Ag Food Chem (2000) 48(12), 5802-5807 Sostaric, T.; Boyce, M. C.; Spickett, E. E. 829 Volatiles of Analysis of headspace compounds of distillers grains using 75µm Carboxen/PDMS GC-MS distillers grains SPME in conjunction with GC/MS and TGA. 60min J Cereal Sci. (2001) 33(2), 223-229 headspace Staff, C., Biswas, S. 878 Essential oils in SPME of hop volatiles Potential use for determination and 100µm PDMS GC-MS hops verification of hop varieties 30min @ 70°C J. Chromatogr A 918 (2001) 159-167 headspace Kovacevic, M., Kac, M. 63 Essential oils in Determination of Essential Oils in Hops by Headspace SPME 100µm PDMS GC-FID hops J. Agric. Food. Chem, 44: 1768-1772 (1996) 50°C, 4 hr Field, J.,