ISSN 1425-204X PL9700796 INSTITUTE OF NUCLEAR CWmiSTRY AN* TECHNOLOGY SI El El El El Si ZHHPEHUIZ 1995 EDITORIAL BOARD Wiktor Smuiek, Ph.D. Ewa Godlewska Sylwester Wojtas CONTENTS GENERAL INFORMATION 7 MANAGEMENT OF THE INSTITUTE 9 MANAGING STAFF OF THE INSTITUTE 9 HEADS OF THE INCT DEPARTMENTS 9 PROFESSORS AND SCIENTIFIC COUNCIL 10 PROFESSORS 10 ASSOCIATE PROFESSORS 10 ASSISTANT PROFESSORS (Ph.D.) 11 SCIENTIFIC COUNCIL (1991-1995) 13 HONORARY MEMBERS OF THE INCT SCIENTIFIC COUNCIL (1991-1995) 14 SCIENTIFIC COUNCIL (1995-1999) 14 HONORARY MEMBERS OF THE INCT SCIENTIFIC COUNCIL (1995-1999) 16 RADIATION CHEMISTRY AND PHYSICS 17 RADIATION-INDUCED SILVER AGGLOMERATION IN SMECTITE CLAYS J. Michalik, J. Sadlo, H. Yamada, D.R. Brown, L. Kevan 19 STUDY OF INTRAMOLECULAR PROTON TRANSFER TO HYDROXY SULPHURANYL RADICAL IN METHIONINE AND ITS DERIVATIVES D. Pogocki, K. Bobrowski 20 ON THE REACTION OF THE HYDRATED ELECTRON WITH METHIONINE-CONTAINING OLIGOPEPTIDES G. Strzelczak-Burliriska, K, Bobrowski, J. Holcman 23 4-CARBOXYBENZOPHENONE AND N-(9-METHYLPURIN-6-YL)PYRIDINUM CATION AS PHOTOSENSITIZERS IN THE OXIDATION OF METHIONINE-CONTAINING PEPTIDES AND SULPHUR-CONTAINING AMINO ACIDS K. Bobrowski, B. Marciniak, G.L. Hug 25 THE TRIPLET STATE ARYL CATION 3.5-DICHLORO-4-AMINO 3Arf H. B. Ambroz, TJ. Kemp, G.K. Przybytniak 28 SPURS IN CRYSTALLINE L-ALANINE Z.P. Zagdrski 29 HPLC MONITORING OF RADIOLYTIC DECOMPOSITION OF CHLOROPHENOLS IN SYNTHETIC SOLUTION AND NATURAL WATER MATRICES A. Chudziak, T. Bryl-Sandelewska, M. Trojanowicz 31 THERMAL DECOMPOSITION OF GAMMA IRRADIATED PROTEINS BY THERMAL ANALYSIS METHODS K. CieSla, E.F. Vansant, M. Swiderska-Kowalczyk 33 DENATURATION PROCESSES IN GAMMA IRRADIATED PROTEINS BY DIFFERENTIAL SCANNING CALORIMETRY K. CieSla, Y. Roos 34 EXAMINATION OF IRRADIATED FLOUR AND MEAT BY AMYLOGRAPHY AND DIFFERENTIAL SCANNING CALORIMETRY K. CieSla, M. Swiderska-Kowalczyk, W. Gluszewski 35 OXIDATION OF SO2 BY SIMULTANEOUS APPLICATION OF ELECTRON BEAM AND ELECTRICAL FIELD IN HUMID AIR H. Nichipor, E. Radouk, AG. Chmielewski, Z. Zimek 36 RELATIVE DOSIMETERS FOR HIGH-LET RADIATIONS Z. Stuglik 37 A COMPARISON OF THREE MATERIALS USED FOR ESR DOSIMETRY Z. Stuglik, J. Sadlo 38 RADIATION FACILITY AT JINR U-400 CYCLOTRON CHECKED BY FRIC'KE DOSIMETER MEASUREMENTS Z. Stuglik 39 TEMPERATURE AND DOSE RATE EFFECTS IN As IMPLANTED GaAsi-XPX J. Krynicki, S. Warchot, H. Rzewuski, R. Groetzschel 40 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, CHEMISTRY IN GENERAL 43 SOLUTION CHEMISTRY OF ELEMENT 104: SOLVENT EXTRACTION INTO TRIISOOCTYLAMINE FROM HYDROFLUORIC ACID SOLUTIONS A Bilewicz, C D. Kacher, D C. Hoffman 45 A CHEMICAL STUDIES OF THE ^Ne CLUSTER DECAY OF 232Th Ch. Neskovic, R. Delmas, M. Hussonnois, A. Bilewicz, B. BartoS 45 MATERIALS FOR IN-SITU MONITORING OF LIGHT WATER REACTOR (LWR) WATER CHMISTRY BY OPTICAL METHODS L. Fuks, S. Pikus 46 STATE-OF-THE-ART REVIEW ON FISSION PRODUCT AEROSOL POOL SCRUBBING UNDER SEVERE ACCIDENT CONDITIONS M. Swiderska-Kowalczyk, M.Escudero Berzal, M.Marcos Crespo, M.Martin Espigares, J.Lopez-Jimdnez 48 SELECTION OF ELEMENTS FOR THE STUDIES OF "EVEN-ODD" EFFECT IN CHMICAL ISOTOPE EXCHANGE REACTIONS W. Dembifiski 48 IS THERE ANY INFLUENCE OF "MAGIC" NUCLEI ON CHEMICAL BEHAVIOUR? T. Mioduski 49 SELECTIVITY OF ION EXCHANGE ON CRYSTALLINE ANTIMONIC ACID - RADIOTRACER STUDY IN HYDROCHLORIC ACID AND AMMONIA SOLUTIONS A Bilewicz, J. Narbutt 50 LANTHANIDE IONS COMPLEXATION BY URONIC ACIDS L. Fuks 51 IONIC RADII. EFFECT' OF SHELL RADIUS, CATION CHARGE AND LONE ELECTRON PAIR S. Siekierski 54 "REGULAR" AND "INVERSE" TETRAD EFFECT T. Mioduski 55 SPECIATION OF CHROMIUM IN NATURAL WATERS BY SEPARATION AND PRECONCENTRATION ON A PYROLLIDINEDITHIOCARBAMATE LOADED RESIN FOLLOWED BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY (GF AAS) J. Chwastowska, W. Zmijewska, E. Sterlirtska 56 A STUDY ON THE EFFECT OF COLUMN OVERLOADING AND ITS INFLUENCE ON THE QUALITY OF ANALYTICAL RESULTS WHEN DETERMINING SIMPLE ANIONS BY ION CHROMATOGRAPHY K. Kulisa, R. Dybczyriski, H. Polkowska-Motrenko 57 DEVISING OF THE METHOD FOR THE DETERMINATION OF SAMLL AND VERY SMALL AMOUNTS OF CADMIUM IN BIOLOGICAL MATERIALS BY RADIOCHEMICAL VERSION OF NEUTRON ACTIVATION ANALYSIS Z. Samczyriski, R. Dybczyfiski 59 MECHANISM OF THE CHLORIDE ION EFFECTS ON TOE ANALYTICAL SIGNAL OF SELENIUM MODIFIED BY PALLADIUM IN GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY L. Pszonicki, W. Skwara 61 SOL-GEL PREPARATION OF YBazCu40g PRECURSORS FROM BY COMPLEX SOL-GEL PROCESS (CSGP) A Deptula, W. Lada, T. Olczak, K.C. Goretta 61 RETENTION OF SODIUM ON HYDRATED ANTIOMONY PENTOXIDE MICROSPHERES (DIAMETER <20pm) PREPARED BY SOL-GEL PROCESS A. Deptula, W. Zmijewska, W. Lada, T. Olczak 64 SINTERING OF Zr02-Ca0, ZrOz-YzOg AND Zr02-Ce0% SPHERICAL POWDERS PREPARED BY IChTJ SOL-GEL PROCESS A Deptula, M. Carewska, T. Olczak, W. Lada 66 LOCATION OF THE PROTON IN TOE VERY STRONG 0-H...0 HYDROGEN BONDS IN 2-(N,N-DITHYLAMINO-N-OXYMETOYL)-4,6-DICHLOROPHENOL. A NEUTRON DIFFRACTION STUDY H. Ptasiewicz-Bqk, R. Tellgren, I. Olovsson, A Koll 67 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART VII: THE CRYSTAL AND MOLECULAR STRUCTURES OF CALCIUM COMPLEXES WITH 2-PARAZINECARBOXYLIC AND 2,3-PYRAZINEDICARBOXYLIC ACIDS J. Leciejewicz, H. Ptasiewicz-Bqk 68 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART VIII: THE CRYSTAL AND MOLECULAR STRUCTURES OF MAGNESIUM COMPLEXES WITH 2-FURANCARBOXYLIC AND 3-FU RAN CARBOXYLIC ACIDS B. Paluchowska, J.K. Maurin, J. Leciejewicz 69 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART IX: THE CRYSTAL AND MOLECULAR STRUCTURES OF DINUCLEAR COPPER (II) COMPLEXES WITH 3-FURANCARBOXYLIC ACID AND 2-THIOPEPHENCARBOXYLIC ACID B. Paluchowska, J.K. Maurin, J. Leciejewicz 70 MAGNETIC ORDERING IN LANTHANIDE INTERMETALLIC PHASES J. Leciejewicz, A. Szytuta 70 THE HNS SPECTROSCOPY OF AMINOACIDS III: L-ISOLEUCINE A Pawlukojd, J. Leciejewicz, I. Natkaniec 73 RADIOBIOLOGY 75 DNA REPAIR IN ADAPTED HUMAN LYMPHOCYTES M. Wojewddzka, I. Szumiel 77 INTERDEPENDENCE OF INITIAL DNA DAMAGE, ITS REPAIR AND SENSITIVITY TO TOPOISOMERASE I POISON, CAMPTOTHECIN I. Grqdzka, I. Szumiel 77 TOPQISOMERASE I IS NOT DOWN-REGULATED BY X-IRRADIATION IN L5178Y-R SUBLINE I. Grqdzka, I. Szumiel 78 ANTIOXIDANT DEFENSE IN L5178Y SUBLINES: GLUTATHIONE B Sochanowicz 79 ANTIOXIDANT DEFENSE IN L5178Y SUBLINES: CATALASE E. Bouzyk, M. Kruszewski, N. Jarocewicz 79 "PROTECTIVE ENZYMES" IN L5178Y SUBLINES AND DNA DAMAGE M. Kruszewski, T. Iwanefiko 80 THE INFLUENCE OF COPPER (II) ON RADIATION-INDUCED DAMAGES TO DNA H.B Ambroz, I. Grqdzka, TJ. Kemp, M. Kruszewski, G.K Przybytniak, T. Wrotiska 81 NUCLEAR TECHNOLOGIES AND METHODS 83 PROCESS ENGINEERING 85 MULTISTAGE PROCESS OF DEUTERIUM AND HEAVY OXYGEN ENRICHMENT BY MEMBRANE DISTILLATION A G. Chmielewski, G. Zakrzewska-Trznadel, N.R. Miljcvid, A. Van Hook 85 RADIOTRACER INVESTIGATIONS OF FLUE GAS FLOW DYNAMICS IN TWO STAGE IRRADIATION PILOT PLANT FOR NO* AND SO] REMOVAL IN POWER STATION IN KAW^CZYN AG. Chmielewski, A. Owczarczyk, J. Palige, A. Dobrowolski, E. Iller 85 INFLUENCE OF DOSE DISTRIBUTION AND FLOW PATTERN BETWEEN IRRADIATION STAGES ON REMOVAL OFNOx A G. Chmielewski, B. Tymirtski, A. Dobrowolski 86 APPLICATION OF SelRO MEMBRANES TO THE TREATMENT OF AGGRESSIVE WASTES CONTAINING THE ABSORBENT GENOSORB AG. Chmielewski, M. Harasimowicz, J. Palige 88 SELECTION OF A NEW OUTFALL POINT LOCALIZATION FOR SEWAGES DISCHARGED FROM "CELLULOSE AND PAPER FACTORY SWIECIE" (CPFS) INTO VISTULA RIVER A. Owczarczyk, R. Wierzchnicki, M. Strzelecki, B. Wiqclaw 89 DETERMINATION OF WATER LEAKAGES INTO HEAT-GENERATING PLANTS A. Owczarczyk, H. Buriiliski, B. Wi^ctaw, M. Strzelecki, R Wierzchnicki 90 MATERIAL ENGINEERING, STRUCTURAL STUDIES, DIAGNOSTICS 91 ALLOYING OF AUSTENITIC STAINLESS STEEL WITH NITROGEN USING HIGH-INTENSITY PULSED BEAMS OF NITROGEN PLASMA J. Piekoszewski, L. WaliS, Z Werner, J. Bialoskdrski, L. Nowicki, M. Kopcewicz, A. Grabias 91 SURFACE MORPHOLOGY OF NITROGEN-ALLOYED STEELS USING HIGH INTENSITY PULSED PLASMA BEAMS J. Piekoszewski, L. WaliS, J. Langner 92 EXAMINATION OF HIGH-TEMPERATURE RESISTANCE OF ISOTOPE SMOKE DETECTORS A. Nowicki, L. Rowirtska, E. Paficzyk 93 WELDING ELECTRODES DOPED WITH THORIUM DIOXIDE A. Nowicki 94 NEW MAGNETIC MATERIALS OBTAINED FROM AMINOTRIAZOLE COMPLEXES WITH TRANSITION METALS A. Lukasiewicz, L. WaliS, H. Grigoriew 95 NEW ENVIRONMENT-FRIENDLY PREPARATIONS FOR IMPREGNATING AND DYEING OF WOOD A. Lukasiewicz, L. Rowifiska, L. WaliS 96 APPLICATION OF FOLLOW-UP DETECTORS TO LEAKPROOF CONTROL OF UNDERGROUND PIPELINES J. KraS, W. Kielak, S. Myczkowski 96 DETERMINATION OF TRACE ELEMENTS IN FILLINGS OF SARCOPHAGI OF EGYPTIAN MUMMIES FROM THE ARCHEOLOGICAL MUSEUM IN KRAK6W E. Paficzyk, M. Ligqza, J. Kierzek, K. CieSIa, L. WaliS 97 STUDY OF CHINESE PORCELAINS BY X-RAY FLUORESCENCE ANALYSIS J. Kierzek, B. Malozewska-Budko 99 AUTOMATIC INDEXING TEST OF e-BN K. Godwod, H. Grigoriew, W. Starosta 101 RADIATION TECHNOLOGIES 103 TOWARDS STANDARDIZATION OF THERMOLUMINESCENCE ANALYSIS APPLIED FOR DETECTION OF IRRADIATED FOODSTUFFS K Malec-Czechowska, A M. Dancewicz, Z. Szot 103 EFFECT OF IONIZING RADIATION ON PROPERTIES OF ACRYLIC PRESSURE SENSITIVE ADHESIVES E. Wojtyfiska, W. Gluszewski, J. Bojarski, P.P. Panta 104 PARTICLE TRACK MEMBRANES IN A CORONA DISCHARGE FIELD M. Buczkowski, W. Starosta, D. Wawszczak, A. Fiderkiewicz 106 EB POLLUTANTS REMOVAL PROCESS FROM MODEL GASES WITH HIGH SO] CONCENTRATION A.G. Chmielewski, Z. Zimek,