Lecture XII : Feb 28, 2018 Quantum Revolution Play .. If you are thinking of writing the play “Quantum Revolution”, • You have to be a good and creative writer. More importantly, you have to be fascinated by quantum revolution, the science and the scientists... appreciate the mind boggling imagination, brilliance, genius and weirdness of those scientists who brought the quantum revolution.. You need to be committed to the task – requires immense energy and time to research and special imaginative skill to make this a work of art. • You need to be in class for ALL lectures as what goes in class discussion will set part of the stage for the play. If you want to be part of the play, it is mandatory that you should be present in class. Also, from now onwards, we will be discussing play in almost all lectures and you need to be present. Starting next week, an attendance sheet will be passed around. 1 Electron Spin or “Classically Non-Describable Two-Valuedness” “This property of elementary particles is peculiar to quantum theory. It is a mysterious beast, and yet its practical effect prevails over the whole of science. The existence of spin is most subtle and ingenious design of Nature– without it the whole universe will collapse ” MUST READ: <http://www.lorentz.leidenuniv.nl/history/spin/ goudsmit.html> It was found that electron is like a little “magnet”. The strength of its magnetic property is ~ characterized by “spin”, which we denote as S. For electrons, S = 2 . The spin of the proton, neutron is also the same. Since it is multiplied by ~, it is purely a quantum mechanical quantity. That is, classically, there is no magnetic moment associated with electron, proton... HISTORY • Story of spin began with the discovery that special lines of an atom split into multiple lines when the atom is subjected to magnetic field. This is known as Zeeman effect. Wolfgang Pauli in 1924 was the first to propose a doubling of electron states due to a two-valued non-classical “hidden rotation”. 2 • In 1925, George Uhlenbeck and Samuel Goudsmit at Leiden University suggested the simple physical interpretation of a particle spinning around its own axis, in the spirit of the old quantum theory of Bohr and Sommerfeld. • Ralph Kronig anticipated the Uhlenbeck-Goudsmit model in discussion with Hendrik Kramers several months earlier in Copenhagen, but did not publish it because when they discussed with Pauli, he did not support. • The ( unsatisfactory) mathematical theory was worked out in depth by Pauli in 1927. • When Paul Dirac derived his relativistic quantum mechanics in 1928, electron spin was an essential part of it. In other words, relativistic theory implies are particles like electrons have to have spin, even though electrons may not be moving close to speed of light . BOSONS and FERMIONS <https://www.youtube.com/watch?v=_1S6KfMzOH8> All particles of nature have spin that is either: 1 3 5 (a) Half-integer multiples of ~ , that is, 2 ~; 2 ~; 2 ~... Such particles are called Fermions. 3 (b) or Integers, like 0; ~; 2~; 3~::::, such particles are called Bosons. Examples are photons ( spin 1), π-mesons (spin zero), gravitons ( spin -2 ). 1 1 (c) There are NO particles in nature that have spin 3 ~, 8 ~ etc... Pauli Exclusion Principle and Atoms with more than one electron The year 1925 was an important one for quantum physics, beginning with Wolfgang Paulis January announcement of the exclusion principle. This well-known principle, which states that no two identical fermion particles can be in the same quantum state, provided for the first time a theoretical basis for the structure of the periodic table of the elements. Each quantum state ( specified by the quantum number such as n ) of an atom can accommodate only two electrons. Known as the Pauli exclusion principle, it explains the buildup of elements, the Periodic Table. Difference between classical and Quantum Particles • Indistinguishability • Only two kinds of particles: fermions and bosons • Exclusion principle • Key difference between integer and half integer spin particles: After 2π rotations, wave functions do not return to their starting value. We need 4π rotations to recover initial state. What is ~ ??? • ~ determines the minimum uncertainty in classical observables... • Spin of all elementary particles is either an integral or half integral multiple of ~. I. IMPORTANT REMARKS • Pauli Exclusion Principle... Pauli’s New Force 4 Pauli’s exclusion principle that two electrons cannot be in the state state ultimately prohibits two electrons too close together. The “effective force” generated by Pauli exclusion principle is called the “exchange force”.Note it is not a new kind of force – it is not really a force – (there are only four types of fundamental forces in nature). It is an EFFECTIVE force that is, it can be viewed as a kind of force. • NOTE: Pauli exclusion principle applies only to Identical Fermions– • When we swap two electrons, there is NO way to detect the swap – experimentally or even in principle. • Pauli exclusion principle explains why we cannot walk through a solid wall, even though it is 99 percent empty. The electrons of our hand cannot penetrate the “wall” atoms because they are ruled by Pauli exclusion principle. • We understand why matter is made up of only fermions. If bosons were the building blocks of matter, it will be unstable. • Yes, quantum physics is the key to understand all physical phenomena ( almost all... ), only 5 in principle. The devil is in the details.... Even though we know all the forces, we cannot always solve Schrodinger¨ equation.... Spin and Stability of the World Pauli exclusion principle is the reason why electrons do not cluster into the lowest orbits. Therefore, it is the key to the stability of an atom and hence the universe. Shocking things – How Can it Possibly Be so Weird ????? READING: Chapter 7 from Quantum Physics for Poets. Home Work Assignment II ( Due on March 19, 2018) Write about two pages a quantum phenomenon that you find most weird and puzzling. State clearly your reasons ... 6.