RHEOLOGY BULLETIN Publication of the Society of Rheology

RHEOLOGY BULLETIN Publication of the Society of Rheology

RHEOLOGY BULLETIN Publication of the Society of Rheology Volume 28, No. 3 Fall, 1959 THE BINGHAM MEDAL, 1959 THIRTIETH ANNIVERSARY The Bingham Medal of the Society of Rheology for MEETING — 1959 1959 will be awarded to Dr. Egon Orowan, George Plans are now being completed for the Thirtieth Westinghouse Professor of Mechanical Engineering in Anniversary Meeting of the Society, to be held at the Massachusetts Institute of Technology. The re- Lehigh University on Wednesday, Thursday and Fri- cipient was chosen by a special Bingham Award Com- day, November 4, 5 and 6. A block of rooms has been mittee, consisting of the following members: J. D. reserved for the Society at the Hotel Bethlehem in Dienes (Chairman), T. Alfrey, Jr., H. Leaderman, Bethlehem, Pa., and Society members are strongly A. S. Nowick, and F. D. Dexter. urged to make their room reservations immediately, Dr. Orowan was born in 1902 in Budapest, Hungary, if they have not already done so. Bus service will be where he also attended school. He studied at the Uni- available between the Hotel and the Lehigh campus. versity of Vienna for two years, and then transferred A very full program of papers has been scheduled to the Technical University of Berlin-Charlottenburg, by the Program Committee, under the chairmanship of where he obtained an Engineering Diploma and a Doc- J. T. Bergen, as will be seen from the detailed program tor's degree in Applied Physics. which follows. Two special symposia are included. We He then returned to Budapest, and was for a time in are also fortunate to have as a foreign guest Prof. charge of the Krypton Gas Works of the United In- Markus Reiner from Israel, one of the world's dis- candescent Lamp and Electric Company there. tinguished rheologists, who will give an informal talk In 1937, he went to England, and from 1937-39 held at Wednesday's luncheon. Special talks will also be the position of Research Associate in the Physics De- given by John D. Ferry and Melvin Mooney, on Wed- partment of the University of Birmingham. During an nesday morning and at Thursday's luncheon, respec- eleven-year period, 1939-50, he was in charge of the tively. Metal Physics Group and was also Reader in the A viscometer exhibit is planned, and there will be Physics of Metals in the Cavendish Laboratory at an opportunity to visit some of the Lehigh laboratories, Cambridge University. including the Fritz Laboratory of Civil Engineering, In September 1950, he moved permanently to the which contains one of the show pieces of the University United States to accept a Professorship at the Massa- —a Universal Testing Machine weighing 5 million chusetts Institute of Technology, following an appoint- pounds, and standing 7 stories tall. ment at M.I.T. in the spring of the same year as Visit- Social activities have also not been neglected. A ing Professor. He was appointed to the George Westing- cocktail party and smoker have been scheduled, as well house Professorship in 1951. as the banquet on Thursday evening, which will feature Professor Orowan's interests have been directed some interesting Pennsylvania Dutch specialties on the toward the general mechanical properties of materials, menu. The ladies' program is given in detail below, and and particularly the underlying physical mechanisms Prof. Raymond R. Myers of the Lehigh Chemistry of deformation and fracture phenomena. He has made Department, Chairman of the Local Arrangements important contributions to this subject from both the Committee, would be interested to know in advance experimental and theoretical aspects, and one of his the number of ladies who will be attending. Attention outstanding contributions was the introduction of the is also drawn to the Lehigh-V.M.I. football game on concept of dislocations in metals as a controlling factor Saturday. The Local Committee will attempt to get in their yield and cleavage crack propagation behavior. tickets in advance, if so requested. In 1946, he received the gold medal (Thomas Hawks- ley Award) of the Institution of Mechanical Engineers of London, for his theory of rolling of metals. He has also done important work in interpreting the phenom- Ladies' Program enon of delayed fracture ("static fatigue") in glass, Wednesday Morning, November 4 and in the field of fracture and viscoelasticity of 9:00 Registration begins polymers. 11:00 Guided Bus Tour of Lehigh University He has taken a considerable interest in geological Wednesday Afternoon, November 4 phenomena, as well, and has recently published a 12:30 Luncheon: University Center paper on the mechanism of tectonic earthquakes. In 1:45 Get-acquainted Party: University Center 1958. he was a Visiting Professor in the Geology De- 5:30 Cocktails: Hotel Bethlehem partment at the California Institute of Technology. 7:30 Artistic Program — 1 — or compounded stocks. Typical results for selected elastomers obtained under various operating condi- tions are discussed and compared to data obtained from RHEOLOGY BULLETIN other testing instruments and processing equipment. Inadequacy of single point characterization typical of R. D. Andrews, Jr., Editor widely used tests is emphasized. Results are inter- Plastics Research Laboratory preted with respect to molecular theories of flow for Room 7-006, M.l.T. viscoelastic polymers. Cambridge 39, Mass. The Influence of Viscometer Design on Non-Newtonian Measurements R. MCKENNELL, Ferranti Ltd., Moston, Manchester Thursday Morning, November 5 10, England. 10:00 "Autumn Daze"—a holiday bazaar held in Uncertainty arising from viscometric data obtained the Moravian Christian Education Building from non-Newtonian fluids is minimised by observing (across from Hotel Bethlehem). two principal conditions: the shear rate should be 11:30—2 P.M. Luncheon—cafeteria style (same uniform throughout the measured sample; and a con- location) sistent experimental procedure, including the amount Thursday Afternoon, November 5 and duration of shear, should be adopted. The effect 1:30—3:00 P.M. Old Moravian Area Guided of shear rate variation within the sample fluid is dis- Tour—A glimpse into the life, customs and cussed for some viscometers in common industrial use. architecture of early Bethlehem. An outline is given of the methods available for elim- 7:00 Dinner: Asa Packer Room, University Center inating variations in shear rate, and hence the tedium Friday Morning, November 6 of applying corrections to flow curves for different 9:30 Shopping tour in Hess's—an outstanding types of non-Newtonian behaviour. A viscometer is department store in Allentown. described which combines uniform shearing conditions 11:00 Luncheon and fashion show in the Patio. with a flexible automatic flow curve recorder giving a Friday Afternoon, November 6 wide range of rheological test programs. The recorder Return to Bethlehem enables the duration of shear to be minimised in the (Luncheons, tours and incidental expenses will be higher ranges so that shear-induced heating in the thin borne by the women participants.) layer of fluid is greatly reduced. Comparative data are presented for several rotation viscometers to show this PROGRAM OF MEETING effect. All technical sessions will be held in the University Flow Down an Inclined Plane Center. Time for presentation of papers: 30 min. RAY D. HOFFMAN and RAYMOND R. MYERS, Wednesday Morning, November 4 Lehigh University, Bethlehem, Pa. 9:00 Registration Begins: West Foyer, 3rd Floor, The flow of Newtonian and shear-thinning liquids University Center down an inclined plane was studied with the objective 10:00 Opening Remarks: Dr. J. H. Dillon, Presi- of estimating the degree of non-Newtonian behavior dent of the Society. Dr. H. A. Neville, Vice- from a simple test. An empirical relation called the President of Lehigh University flow decay curve was obtained, by means of which a 10:15 Technical Session (J. T. Bergen, Chairman) wide variety of materials was characterized by the de- crease in velocity of the advancing front with distance Rheological Measurements on Elastomers of flow. In general the decrease was an exponential with the Brabender Plastograph function of distance, and the magnitude of the ex- C. C. MCCABE, Elastomer Chemicals Department, ponent provided an index of shear thinning, independ- E. /. du Pont de Nemours and Company, Inc., Wil- ent of viscosity. The flow decay curve was compatible with a theoretical equation based on hydrodynamic mington, Del. flow principles. Rheological properties of elastomers are of primary importance during processing and must be maintained 11:45 "Impressions of Rheological Research in within certain limits for successful operation. The need Europe" for new and improved characterization tests is clearly J. D. Ferry, Department of Chemistry, apparent. The shear stress vs. shear rate relationship University of Wisconsin, Madison, Wis. appears most effective in characterizing elastomers. Wednesday Afternoon, November 4 Because wide variations of these parameters exist in 12:30 Luncheon—University Center processing equipment, it is necessary to determine Informal after-luncheon address: Prof. this relationship over a wide range if processability is Markus Reiner, Israel Institute of Technol- to be predicted. ogy, Haifa, "Reminiscences on the Society's The Brabender Plastograph affords a means of First Thirty Years" measuring rheological characteristics as a function of 1:45 Technical Session (Edward Collins, Chair- shear rate and temperature in either uncompounded man) — 3 — The Rheology of Asphaltf: Stress Optical Properties of Silicones II. Flow Characteristics of Asphalt W. PHILIPPOFF,* Franklin Institute, Philadelphia, Pa. FREDERICK H. GASKINS,* JOHN G. BRODNYAN,** The stress optical properties of silicone solutions WLADIMIR PHILIPPOFF,*** and EDMUND THELEN, have been reported in previous papers. However, the The Franklin Institute Laboratories for Research and extensive description of the experiments including a Development, Philadelphia, Pa. check of the angle x measured in flow birefringence The rheological behavior of ten asphalts has been and with the one determined by the Weissenberg rhe- investigated.

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