THERMODYNAMIC PROPERTIES OF INDIVIDUAL SUBSTANCES Fourth Edition Volume 2 Elements C, Si, Ge, Sn, Pb, and Their Compounds PartTwo Tables Editors L. V. Gurvich and I. V. Veyts Institute for High Temperatures USSR Academy of Sciences, Moscow C. B. Alcock University of Notre Dame, Notre Dame, Indiana Table Editor V. S. Iorish Institute for High Temperatures USSR Academy of Sciences, Moscow OHEMISPHERE PUBLISHING CORPORATION A member of the Taylor & Francis Group New York Washington Philadelphia London CONTENTS LIST OF TABLES Table No. Substance Pag 238 Carbon (graphite) C(cr, 1) 1 239 Carbon (diamond) C(cr) 2 240 Carbon C(g) 3 241 Carbon positive ion C+(g) 5 242 Carbon negative ion C_(g) 7 243 Dicarbon C2(g) 8 + 244 Dicarbon positive ion C2 (g) 10 245 Dicarbon negative ion C2~(g) 12 246 Tricarbon C3(g) 14 247 Tetracarbon C4(g) 16 248 Pentacarbon C5(g) 18 249 Carbon oxide CO(g) 20 250 Carbon oxide positive ion CO+(g) 22 251 Carbon dioxide C02(g) 24 + 252 Carbon dioxide positive ion C02 (g) 26 253 Dicarbon oxide CzO(g) 28 254 Tricarbon dioxide C302(g) 29 255 Methine CH(g) 30 256 Methine positive ion CH +(g) 32 257 Methylene CH2(g) 34 258 Methyl CH3(g) 35 259 Methane CH4(g) 36 260 Dicarbon hydride C2H(g) 37 261 Acetylene C2H2(g) 39 262 Dicarbon trihydride C2H3(g) 41 263 Ethylene C2H4(g) 42 264 Ethyl C2H5(g) 43 265 Ethane C2H6(g) 44 vi CONTENTS Table No. Substance Page 266 Formyl HCO 45 267 Carboxyl COOH(g) 46 268 Formaldehyde H2CO(g) 47 269 Formic acid HCOOH(g) 48 270 Cfa-Formic acid HCOOH[rä](g) 49 271 Trans-Formic acid HCOOH[trans](g) 50 272 Carbon oxide-trihydride CH30(g) 51 273 Carbon dihydride-hydroxide CH2OH(g) 52 274 Methanol CH3OH(g) 53 275 Ethanol C2H5OH(g) 54 276 Carbon fluoride CF(g) 55 277 Carbon difluoride CF2(g) 56 278 Carbon trifluoride CF3(g) 57 279 Carbon tetrafluoride CF4(g) 58 280 Dicarbon fluoride C2F(g) 59 281 Difluoroacetylene C2F2(g) 60 282 Dicarbon trifluoride C2F3(g) 61 283 Tetrafluoroethylene C2F4(g) 62 284 Pentafluoroethyl C2F5(g) 63 285 Hexafluoroethane C2F6(g) 64 286 Carbon oxide-fluoride FCO(g) 65 287 Carbon oxide-difluoride F2CO(g) 66 288 Fluoromethylene CHF(g) 67 289 Fluoromethyl CH2F(g) 68 290 Fluoromethane CH3F(g) 69 291 Difluoromethyl CHF2(g) 70 292 Difluoromethane CH2F2(g) 71 293 Trifluoromethane CHF3(g) 72 294 Fluoroacetylene C2HF(g) 73 295 Fluoroethylene C2H3F(g) 74 296 Difluoroethylene C2H2F2(g) 75 297 1,1-Difluoroethylene C2H2F2[1, l](g) 76 298 Os-Difluoroethylene C2H2F2 [eis] (g) 77 299 7rarc.y-Difluoroethylene C2H2F2[frara'](g) 78 300 Trifluoroethylene C2HF3(g) 79 301 Carbon oxide-hydride-fluoride HFCO(g) 80 302 Carbon chloride CCl(g) 81 303 Carbon dichloride CCl2(g) 82 304 Carbon trichloride CCl3(g) 83 305 Carbon tetrachloride CCl4(g) 84 306 Dicarbon chloride C2Cl(g) 85 307 Dichloroacetylene C2Cl2(g) 86 308 Dicarbon trichloride C2Cl3(g) 87 309 Tetrachloroethylene C2Cl4(g) 88 310 Pentachloroethyl C2Cl5(g) 89 311 Hexachloroethane C2Cl6(g) 90 312 Carbon oxide-chloride ClCO(g) 91 313 Phosgene Cl2CO(g) 92 CONTENTS vii Table No. Substance Page No. 314 Chloromethylene CHCl(g) 93 315 Chloromethyl CH2Cl(g) 94 316 Chloromethane CH3Cl(g) 95 317 Dichloromethyl CHCl2(g) 96 318 Dichloromethane CH2Cl2(g) 97 319 Trichloromethane CHCl3(g) 98 320 Chloroacetylene C2Cl(g) 99 321 Chloroethylene C2H3Cl(g) 100 322 Dichloroethylene C2H2Cl2(g) 101 323 1,1-Dichloroethylene C2H2C12[1, l](g) 102 324 Cw-Dichloroethylene C2H2C12 [eis] (g) 103 325 Trans-Dichloroethylene C2H2Cl2[mz«s] (g) 104 326 Trichloroethylene C2HCl3(g) 105 327 Carbon oxide-hydride-chloride HClCO(g) 106 328 Fluorochloromethylene CFCl(g) 107 329 Difluorochloromethyl CF2Cl(g) 108 330 Trifluorochloromethane CF3Cl(g) 109 331 Fluorodichloromethyl CFCl2(g) 110 332 Difluorodichloromethane CF2Cl2(g) 111 333 Fluorotrichloromethane CFCl3(g) 112 334 Fluorochloroacetylene C2FCl(g) 113 335 Trifluorochloroethylene C2F3Cl(g) 114 336 Difluorodichloroethylene C2F2Cl2(g) 115 337 1,1 -Difluorodichloroethylene C2F2C12[ 1,1 ] (g) 116 338 Cw-Difluorodichloroethylene C2F2Cl2[ciy] (g) 117 339 7ran,s-Difluorodichloroethylene C2F2C12 [trans] (g) 118 340 Fluorotrichloroethylene C2FCl3(g) 119 341 Carbon oxide-fluoride-chloride FClCO(g) 120 342 Fluorochloromethyl CHFCl(g) 121 343 Fluorochloromethane CH2FCl(g) 122 344 Difluorochloromethane CHF2Cl(g) 123 345 Fluorodichloromethane CHFCl2(g) 124 346 Fluorochloroethylene C2H2FCl(g) 125 347 1,1-Fluorochloroethylene C2H2FC1[1, l](g) 126 348 Q's-Fluorochloroethylene C2H2FC1 [eis] (g) 127 349 rrans-Fluorochloroethylene C2H2FCl[frans](g) 128 350 Difluorochloroethylene C2HF2Cl(g) 129 351 1,1-Difluorochloroethylene C2HF2C1[1, l](g) 130 352 G's-Difluorochloroethylene C2HF2Cl[cw] (g) 131 353 Tra^-Difluorochloroethylene C2HF2Cl[trans] (g) 132 354 Fluorodichloroethylene C2HFCl2(g) 133 355 Trans-Fluorodichloroethylene C2HFCl2[rran.s] (g) 134 356 Cw-Fluorodichloroethylene C2HFCl2[c/s] (g) 135 357 l,l-FluorodichloroethyleneC2HFCl2[l,l](g) 136 358 Carbon bromide CBr(g) 137 359 Carbon dibromide CBr2(g) 138 360 Carbon tribromide CBr3(g) 139 361 Carbon tetrabromide CBr4(g) 140 viii CONTENTS Table No. Substance Page No. 362 Bromomethane CH3Br(g) 141 363 Dibromomethane CH2Br2(g) 142 364 Tribromomethane CHBr3(g) 143 365 Trifluorobromomethane CF3Br(g) 144 366 Difluorodibromomethane CF2Br2(g) 145 367 Fluorotribromomethane CFBr3(g) 146 368 Fluorobromomethane CH2FBr(g) 147 369 Difluorobromomethane CHF2Br(g) 148 370 Fluorodibromomethane CHFBr2(g) 149 371 Trichlorobromomethane CCl2Br(g) 150 372 Dichlorodibromomethane CCl2Br2(g) 151 373 Chlorotribromomethane COBr3(g) 152 374 Chlorobromomethane CH2ClBr(g) 153 375 Dichlorobromomethane CHCl2Br(g) 154 376 Chlorodibromomethane CHQBr2(g) 155 377 Difluorochlorobromomethane CF2ClBr(g) 156 378 Fluorodichlorobromomethane CFCl2Br(g) 157 379 Fluorochlorodibromomethane CFClBr2(g) 158 380 Fluorochlorobromomethane CHFClBr(g) 159 381 Carbon iodide CI(g) 160 382 Carbon diiodide CI2(g) 161 383 Carbon triiodide CI3(g) 162 384 Carbon tetraiodide CI4(g) 163 385 Iodomethane CH3I(g) 164 386 Diiodomethane CH2I2(g) 165 387 Triiodomethane CHI3(g) 166 388 Trifluoroiodomethane CF3I(g) 167 389 Difluorodiiodomethane CF2I2(g) 168 390 Fluorotriiodomethane CFI3(g) 169 391 Fluoroiodomethane CH2FI(g) 170 392 Difluoroiodomethane CHF2I(g) 171 393 Fluorodiiodomethane CHFI2(g) 172 394 Trichloroiodomethane CCl3I(g) 173 395 Dichlorodiiodomethane CCl2I2(g) 174 396 Chlorotriiodomethane CClI3(g) 175 397 Chloroiodomethane CH2ClI(g) 176 398 Dichloroiodomethane CHCl2I(g) 177 399 Chlorodiiodomethane CHClI2(g) 178 400 Difluorochloroiodomethane CF2ClI(g) 179 401 Fluorodichloroiodomethane CFCl2I(g) 180 402 Fluorochlorodiiodomethane CFClI2(g) 181 403 Fluorochloroiodomethane CHFClI(g) 182 404 Tribromoiodomethane CBr3I(g) 183 405 Dibromodiiodomethane CBr2I2(g) 184 406 Bromotriiodomethane CBrI3(g) 185 407 Bromoiodomethane CH2BrI(g) 186 408 Dibromoiodomethane CHBr2I(g) 187 409 Bromodiiodomethane CHBrI2(g) 188 CONTENTS ix Table No. Substance Page No. 410 Difluorobromoiodomethane CF2BrI(g) 189 411 Fluorodibromoiodomethane CFBr2I(g) 190 412 Fluorobromodiiodomethane CFBrI2(g) 191 413 Dichlorobromoiodomethane CCl2BrI(g) 192 414 Chlorodibromoiodomethane CClBr2I(g) 193 415 Chlorobromodiiodomethane CClBrI2(g) 194 416 Fluorobromoiodomethane CHFBrl(g) 195 417 Chlorobromoiodomethane CHClBrl(g) 196 418 Fluorochlorobromoiodomethane CFClBrl(g) 197 419 Carbon sulfide CS(g) 198 420 Carbon disulfide CS2(g) 199 421 Carbon oxide-sulfide COS(g) 200 422 Carbon nitride CN(g) 201 423 Carbon nitride positive ion CN+(g) 203 424 Carbon nitride negative ion CN~(g) 205 425 Carbon dinitride NCN(g) 207 426 Nitrogen carbide-nitride CNN(g) 208 427 Nitrogen dicarbide CNC(g) 209 428 Carbon carbide-nitride CCN(g) 210 429 Cyanogen C2N2(g) 211 430 Carbon oxide-nitride NCO(g) 212 431 Hydrogen Cyanide HCN(g) 213 432 Nitrogen hydride-carbide HNC(g) 215 433 Dicarbon hydride-nitride HCCN(g) 216 434 Carbon nitride-fluoride FCN(g) 217 435 Carbon nitride-chloride ClCN(g) 218 436 Carbon phosphide CP(g) 219 437 Silicon Si(cr, 1) 220 438 Silicon Si(g) 221 439 Silicon positive ion Si+(g) 223 440 Disilicon Si2(g) 225 441 Trisilicon Si3(g) 226 442 Silicon oxide SiO(g) 227 443 Silicon dioxide SiOz(cr, 1) 228 444 Silicon dioxide (quartz) SiOz(cr) 229 445 Silicon dioxide (cristobalite) Si02(cr) 230 446 Silicon dioxide (tridymite) Si02(cr) 231 447 Silicon dioxide SiOz(vitr) 232 448 Silicon dioxide Si02(g) 233 449 Silicon hydride SiH(g) 234 450 Silicon dihydride SiH2(g) 235 451 Silicon trihydride SiH3(g) 236 452 Silane SiH4(g) 237 453 Silicon fluoride SiF(g) 238 454 Silicon difluoride SiF2(g) 239 455 Silicon trifluoride SiF3(g) 240 456 Silicon tetrafluoride SiF4(g) 241 457 Silicon hydride-fluoride SiHF(g) 242 X CONTENTS Table No. Substance Page No. 459 Silicon dichloride SiCl2(g) 244 460 Silicon trichloride SiCl3(g) 245 461 Silicon tetrachloride SiCl4(g) 246 462 Silicon hydride-chloride SiHCl(g) 247 463 Silicon fluoride-chloride SiFCl(g) 248 464 Silicon bromide SiBr(g) 249 465 Silicon dibromide SiBr2(g) 250 466 Silicon tribromide SiBr3(g) 251 467 Silicon tetrabromide SiBr4(g) 252 468 Silicon iodide Sil(g) 253 469 Silicon diiodide Sil2(g) 254 470 Silicon triiodide Sil3(g) 255 471 Silicon tetraiodide Sil4(g) 256 472 Silicon sulfide SiS(cr, 1) 257 473 Silicon sulfide SiS(g) 258 474 Silicon disulfide SiS2(cr, 1) 259 475 Silicon disulfide SiS2(g) 260 476 Silicon nitride SiN(g) 261 477 Trisilicon tetranitride Si3N4(cr) 262 478 Silicon carbide SiC(cr, 1) 263 479 Silicon carbide (cub.) SiC(cr) 264 480 Silicon carbide SiC(g) 265 481 Silicon dicarbide SiC2(g) 266 482 Disilicon carbide Si2C(g) 267 483 Germanium Ge(cr, 1) 268