WATER This dossier on water presents the most critical studies pertinent to the risk assessment of water in its use in coal seam gas extraction activities. This dossier does not represent an exhaustive or critical review of all available data. The majority of information presented in this dossier was obtained from the ECHA database that provides information on chemicals that have been registered under the EU REACH (ECHA). Where possible, study quality was evaluated using the Klimisch scoring system (Klimisch et al., 1997). Screening Assessment Conclusion – Water is classified as a tier 1 chemical and requires a hazard assessment only. 1 BACKGROUND Water is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, even though it provides no calories or organic nutrients. Its chemical formula is H2O, meaning that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. Water is present as the dominant constituent of aqueous solutions and slurries used in hydraulic fracturing operations. Water is essential for all life and is not considered to be an ecotoxicological hazard (DoEE, 2017). 2 CHEMICAL NAME AND IDENTIFICATION Chemical Name (IUPAC): Oxidane, water CAS RN: 7732-18-5 Molecular formula: H2O Molecular weight: 18.015 g/mol Synonyms: hydroxic acid, hydroxylic acid, and hydrogen hydroxide 3 PHYSICO-CHEMICAL PROPERTIES Key physical and chemical properties for the substance are shown in Table 1. Table 1 Overview of the Physico-chemical Properties of Water Property Value Klimisch score Reference Physical state at 20oC and 101.3 kPa clear liquid - PubChem Melting Point 0 @ 101.3 kPa - PubChem Boiling Point 100℃ @ 101.3 kPa - PubChem Partition Coefficient (log Pow) Not℃ Applicable - PubChem Revision date: June 2021 1 Property Value Klimisch score Reference Density 997 kg/m3 @ 20 - PubChem Water Solubility Not Applicable ℃ - PubChem 4 DOMESTIC AND INTERNATIONAL REGULATORY INFORMATION A review of international and national environmental regulatory information was undertaken (Table 2). This chemical is listed on the Australian Inventory of Chemical Substances – AICS (Inventory). No conditions for its use were identified. No specific environmental regulatory controls or concerns were identified within Australia and internationally for water. Based on an assessment of hazards, NICNAS identified the substance as a chemical of low concern to human health and the environment (NICNAS, 2017 and DoEE, 2017a). Chemicals of low concern are considered to have a low likelihood of causing adverse human health effects should an exposure occur and are unlikely to have adverse environmental effects if they are released to the environment from coal seam gas operations. Table 2 Existing International Controls Convention, Protocol or other international control Listed Yes or No? Montreal Protocol No Synthetic Greenhouse Gases (SGG) No Rotterdam Convention No Stockholm Convention No REACH (Substances of Very High Concern) No United States Endocrine Disrupter Screening Program No European Commission Endocrine Disruptors Strategy No 5 ENVIRONMENTAL FATE SUMMARY Water is absolutely essential to all life. The protoplasm of most living cells contains about 80% water. Most of the earth's surface is covered with water. The most striking feature of the earth is the extensive hydrosphere, lacking from neighboring planets. 97.22% of earth's water is captured in oceans, with approximately 2% of water locked up in polar icecaps and glaciers. Water found in land, including surface and groundwater, makes up <1% of the earth's water resources. Groundwater represents more than 97% of the usable freshwater resources and is a major source of replenishment for surface water. Water resources are renewable but finite and scarce. Only freshwater flowing through the solar-powered hydrological cycle is renewable (PubChem). Water which evaporates from the surface of oceans, fresh watercourses, and vegetation is carried in the air to be precipitated as rainfall or snow. The molecules of water vapor in air are pure water; falling raindrops formed by their condensation are saturated with nitrogen, oxygen and other atmospheric gases (PubChem). Revision date: June 2021 2 6 ENVIRONMENTAL EFFECTS SUMMARY Water is essential for all life and is not considered to be an ecotoxicological hazard (DoEE, 2017b). 7 CATEGORISATION AND OTHER CHARACTERISTICS OF CONCERN A. PBT Categorisation The methodology for the Persistent, Bioaccumulative and Toxic (PBT) substances assessment is based on the Australian and EU REACH Criteria methodology (DEWHA, 2009; ECHA, 2008). The biodegradation endpoint is not relevant for water. As such, water does not meet the screening criteria for persistence. Bioconcentration studies are not relevant for water. Therefore, water does not meet the screening criteria for bioaccumulation. Water may exert adverse effects depending on the ionic nature of dissolved inorganic substances in the aqueous matrix. However, as a separate chemical entity, water does not meet the screening criteria for toxicity. The overall conclusion is that water is not a PBT substance. B. Other Characteristics of Concern No other characteristics of concern were identified for water. Revision date: June 2021 3 8 SCREENING ASSESSMENT Chemical Databases of Concern Bioaccumulative Persistence Assessment Step Toxicity Assessment Step Assessment Step Assessment Step Overall PBT Risk Assessment Actions Chemical Name CAS No. Listed as a COC Identified as Assessment 1 P criteria Other P T criteria Acute Chronic Required3 on relevant Polymer of Low B criteria fulfilled? fulfilled? Concerns fulfilled? Toxicity 2 Toxicity2 databases? Concern Oxidane (Water) 7732-18-5 Not a PBT No No NA No NA No NA NA 1 Footnotes: 1 - PBT Assessment based on PBT Framework. 2 - Acute and chronic aquatic toxicity evaluated consistent with assessment criteria (see Framework). 3 – Tier 1 – Hazard Assessment only. Notes: NA = not applicable PBT = Persistent, Bioaccumulative and Toxic B = bioaccumulative P = persistent T = toxic Revision date: June 2021 4 9 REFERENCES, ABBREVIATIONS AND ACRONYMS A. References Department of the Environment, Water, Heritage and the Arts [DEWHA] (2009). Environmental risk assessment guidance manual for industrial chemicals, Department of the Environment, Water, Heritage and the Arts, Commonwealth of Australia. Department of the Environment and Energy (DoEE). 2017a. Environmental risks associated with surface handling of chemicals used in coal seam gas extraction in Australia, Project report prepared by the Chemicals and Biotechnology Assessments Section (CBAS), in the Chemicals and Waste Branch of the Department of the Environment and Energy as part of the National Assessment of Chemicals Associated with Coal Seam Gas Extraction in Australia, Commonwealth of Australia, Canberra. DoEE. 2017b. Environmental risks associated with surface handling of chemicals used in coal seam gas extraction in Australia, Project report Appendices A, B, C, D, F, and G prepared by the Chemicals and Biotechnology Assessments Section (CBAS) in the Department of the Environment and Energy as part of the National Assessment of Chemicals Associated with Coal Seam Gas Extraction in Australia, Commonwealth of Australia, Canberra. ECHA. ECHA REACH database: http://echa.euroa.eu/information-on-chemicals/registered- substances. European Chemicals Agency (ECHA). (2008). Guidance on Information Requirements and Chemical Safety Assessment, Chapter R11: PBT Assessment, European Chemicals Agency, Helsinki, Finland. Klimisch, H.J., Andreae, M., and Tillmann, U. (1997). A systematic approach for evaluating the quality of experimental and toxicological and ecotoxicological data. Regul. Toxicol, Pharmacol. 25:1- 5. NICNAS. 2017. Chemicals of low concern for human health based on an initial assessment of hazards, Project report prepared by the National Industrial Chemicals Notification and Assessment Scheme (NICNAS) as part of the National Assessment of Chemicals Associated with Coal Seam Gas Extraction in Australia, Commonwealth of Australia, Canberra. PubChem. National Institutes of Health. National Library of Medicine National Center for Biotechnology Information. https://pubchem.ncbi.nlm.nih.gov/ B. Abbreviations and Acronyms °C degrees Celsius AICS Australian Inventory of Chemical Substances COC constituent of concern DEWHA Department of the Environment, Water, Heritage and the Arts EC effective concentration ECHA European Chemicals Agency Revision date: June 2021 5 EU European Union IUPAC International Union of Pure and Applied Chemistry kPa kilopascal LC lethal concentration mg/L milligrams per litre OECD Organisation for Economic Co-operation and Development PBT Persistent Bioaccumulative Toxic REACH Registration, Evaluation, Authorisation and Restriction of Chemicals SGG Synthetic Greenhouse Gases ThOD Theoretical oxygen demand Revision date: June 2021 6 .