fi OooC PL0002050 ISSN 1425-204X INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY SL ¥ u 1999 31/ 40 Please be aware that all of the Missing Pages in this document were originally blank pages EDITORS Wiktor Smuiek, Ph.D. Ewa Godlewska-Para PRINTING Sylwester Wojtas © Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 2000 All rights reserved CONTENTS GENERAL INFORMATION 9 MANAGEMENT OF THE INSTITUTE 11 MANAGING STAFF OF THE INSTITUTE 11 HEADS OF THE INCT DEPARTMENTS 11 SCIENTIFIC COUNCIL (1999-2003) 11 SCIENTIFIC STAFF 14 PROFESSORS 14 ASSOCIATE PROFESSORS 14 SENIOR SCIENTISTS (Ph.D.) 14 RADIATION CHEMISTRY AND PHYSICS, RADIATION TECHNOLOGIES 17 GENERATION OF RADICAL CATIONS FROM PHENYL, VINYL, AND ALLYL CONTAINING THIOETHERS IN ORGANIC SOLVENTS A. Korzeniowska-Sobczuk, P. Wiśniewski, K. Bobrowski, L. Richter, O. Brede 19 EPR STUDIES OF RADICALS INDUCED BY IONISING RADIATION IN FLUTAMIDE H.B. Ambroż, E. Kornacka, G. Przybytniak 20 THE ROLE OF Cu(I) AND Cu(II) IN DNA DAMAGES H.B. Ambroż, E. Kornacka, G. Przybytniak 21 TEMPERATURE COEFFICIENT OF THE RADIATION YIELD OF THE RADICAL CH3 • CH COf IN CRYSTALLINE ALANINĘ Z.P. Zagórski 22 COMPETITION BETWEEN INTRAMOLECULAR TWO-CENTERED THREE-ELECTRON BONDED (S. • .S)+ AND (S. • .N)+ FORMATION DURING PHOTOOXIDATION OF METHIONINE-CONTAINING PEPTIDES BY THE 4-CARBOXYBENZOPHENONE TRIPLET STATE IN AQUEOUS SOLUTION K. Bobrowski, G.L. Hug, H. Kozubek, B. Marciniak 23 Trp[NH ' +] -Tyr[O ' ] RADICAL TRANSFORMATION IN H-Trp-(Pro)n-Tyr-OH,n = 3-5, SERIES OF PEPTIDES K. Bobrowski, J. Poznański, J. Holcman, K.L. Wierzchowski 25 EPR OF METALS NANOPARTICLES IN MCM-41 MOLECULAR SIEVES J. Michalik, D. Brown, J.-S. Yu, M. Danilczuk, L. Kevan 27 POLY(ETHYLENE TEREPHTHALATE) COMPOSITE MATERIALS - RADIATION EFFECTS J. Sadto, J. Bojarski, G. Strzelczak, J. Michalik 30 FURTHER STUDIES ON IRRADIATION PRODUCTS AND TOXICITY CHANGES IN RADIOLYTIC DECOMPOSITION OF 2,4-DICHLOROPHENOL P. Drzewicz, P.P. Panta, W. Głuszewski, G. Naiqcz-Jawecki, S. Wahyuni, M.H.O. Sampa, S.I. Berrely, M. Trojanowicz 32 RADIATION-INDUCED POLYMERIZATION OF 2-ETHYLHEXYL ACRYLATE FOR MEDICAL APPLICATION P.P. Panta, W. Głuszewski, G. Strzelczak, E.K. Wojtyńska, Z. Zimek 35 EXPERIMENTAL SIMULATION OF SPECTRA OF PEROXIDES ON CHAINS OF POLYPROPYLENE A. Rafalski, Z.P. Zagórski 37 ELECTRON PARAMAGNETIC RESONANCE SPECTROMETRY (EPR) FOR DATING OF PALEOANTHROPOLOGICAL NURAGHI SKELETAL TISSUES W. Stachowicz, J. Sadło, G. Strzelczak, J. Michalik 38 THE CELLULOSE MEMBRANE - WATER INTERACTION STUDIED BY DIFFERENTIA!. SCANNING CALORIMETRY K. Cieśla, H. Rahier, G. Zakrzewska-Trznadel 38 DIFFERENTIAL SCANNING CALORIMETRY STUDIES OF MELTING AND GLASS TRANSITION PROCESSES IN FOOD K. Cieśla, A. Sereno, W. Głuszewski, C. Barbossa 40 EFFECT OF ANNEALING AND IRRADIATION ON THE OPTICAL PROPERTIES OF OXIDE CRYSTAL S.M. Kaczmarek, M. Berkowski, Z. Moroz, S. Warchoł 41 CHANGES IN LUMINESCENCE OF Ce: YAG CRYSTALS UNDER IONIZING RADIATION TREATMENT S.M. Kaczmarek, Z. Moroz, M. Kwaśny, J. Kisielcwski, T. Łukasiewicz, J. Wojtkowska, H. Rzewuski 42 LABORATORY FOR MEASUREMENTS OF TECHNOLOGICAL DOSES - STATE-OF-THE-ART Z. Stuglik 42 DOSIMETRIC RESPONSES OF SUNNA AND PVC FOIL DOSIMETERS IRRADIATED WITH 10 MeV ELECTRON BEAMS - TIME DEPENDENCE Z. Stuglik 43 INFLUENCE OF BUTADIENE/STYRENE COPOLYMERS ON THE STABILISATION OF POLYPROPYLENE IN ELECTRON BEAM IRRADIATION D. Żuchowska, Z.P. Zagórski, G. Przybytniak, A. Rafalski 44 RADIATION INDUCED DEFECTS IN MONOCRYSTALS AND GLASSES OF LÍ2B4O7 S.M. Kaczmarek, A. Majchrowski, J. Kisielewski, M. Kwaśny, T. Wrońska 47 ANALYTICAL METHODS FOR THE DETECTION OF IRRADIATION IN FOOD COMMODITIES ACCREDITED IN THE 1NCT LABORATORY FOR DETECTION OF IRRADIATED FOODS W. Stachowicz, K. Malec-Czechowska, A.M. Dancewicz, Z. Szot 47 DETECTION OF IRRADIATED FOODS WITH THE USE OF GAS CHROMATOGRAPHY - EXPERIMENTS WITH POULTRY CARCASSES K. Lehner, W. Stachowicz, K. Malec-Czechowska, A.M. Dancewicz, Z. Szot 48 DSC STUDIES OF GELATINIZATION AND AMYLOSE-LIPID COMPLEX DECOMPOSITION OCCURRING IN INITIAL AND GAMMA IRRADIATED WHEAT AND CORN STARCHES K. Cieśla, A.-Ch. Eliasson 49 DECONTAMINATION OF NATURAL HONEY BY IONIZING RADIATION H.B. Owczarczyk, W. Migdał, B. Kędzia, E. Hołderna-Kędzia, D. Madajczyk 51 DECONTAMINATION OF MEDICAL HERBS BY IONIZING RADIATION W. Migdał, H.B. Owczarczyk 51 APPLICATION OF RADIATION TO THE PRODUCTION OF BAITS TO CONTROL CRAWLING INSECTS IN THE URBAN AREA W. Migdał, H.B. Owczarczyk, J. Świętosławski, J. Świętosławski 52 RADIATION EFFECTS IN PVC AND PVC COMPOSITIONS B. Świerz-Motysia, Z. Zimek, J. Bojarski, G. Przybytniak, J. Sadło 54 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, CHEMISTRY IN GENERAL 57 COMPARISON OF SAMARIUM AND YTTERBIUM ISOTOPE EFFECTS IN ACETATE/AMALGAM SEPARATION SYSTEM W. Dembiński, M. Poniński, R. Fiedler 59 «-CRYSTALLINE POLYANTIMONIC ACID AS AN ADSORBENT FOR RADIOSTRONTIUM AND ACTINIDES(III), AND AS A PRIMARY BARRIER IN WASTE REPOSITORIES A. Bilewicz, J. Krejzler, J. Narbutt 60 ADSORPTION OF RADIOSTRONTIUM AND ACTINIDE(III) IONS ON A NOVEL ADSORBENT APATITE II J. Krejzler, J. Narbutt 61 ELECTRON CONFIGURATION AND RELATIVISTIC EFFECTS IN d ELECTRON ELEMENTS S. Siekierski 62 THE NEW VALUES OF IONIC RADII OF Rf4"1", Db5+ AND Sg6 + A. Bilewicz 64 STEREOCHEMICAL CHARACTER OF s2 LONE PAIR IN Bi3+ AQUA CATION B. Włodzimirska, A. Bilewicz 64 PECULIARITIES OF THE AQUEOUS RARE EARTH FLUORIDE SYSTEMS T. Mioduski 65 DETERMINATION OF SOME PRECIOUS METALS IN GEOLOGICAL AND ENVIRONMENTAL SAMPLES BY RADIOCHEMICAL NEUTRON ACTIVATION ANALYSIS USING CHELEX 100 ION EXCHANGE RESIN Z. Samczyński, B. Danko, R. Dybczyński 66 MODIFICATION OF ARSENIC, ANTIMONY AND BISMUTII BY PALLADIUM AND MAGNESIUM IN ELECTROTHERMAL. ATOMIC ABSORPTION SPECTROMETRY L.Pszonicki.J. Dudek 70 BEHAVIOUR OF SELENIUM AND TELLURIUM IN THE PRESENCE OF MODIFIERS IN ELECTROTHERMAL ATOMIC ABSORPTION SPECTROMETRY L. Pszonicki, W. Skwara 71 APPLICATION OF A CHELATING 2-MERCAPTOBENZOTHIAZOLE LOADED RESIN TO THE SEPARATION OF INORGANIC AND ALKYLMERCURY SPECIES IN NATURAL WATERS J. Chwastowska, A. Rogowska, E. Sterlińska 72 SORPTION OF HEAVY METALS ON HYDROXYAPATITES. PART 2 J. Chwastowska, M. Sadowska-Bratek, E. Sterlińska 73 DETERMINATION OF TRANSITION METALS BY ION CHROMATOGRAPHY K. Kulisa, H. Polkowska-Motrenko, R. Dybczyński 74 EFFECT OF THE SAMPLE MINERALIZATION METHOD ON THE ACCURACY OF Co DETERMINATION IN PLANT MATERIALS H. Polkowska-Motrenko, B. Danko, R. Dybczyñski 76 SOL-GEL PROCESS FOR SYNTHESIS OF Ndi osBai 95Cu3Ox SUPERCONDUCTORS FROM Nd, Ba AND Cu ACETATES/AMMONIA/ASCORBIC ACID SYSTEMS A. Deptuta, W. Lada, T. Olczak, K.C. Goretta 78 SYNTHESIS OF LiNii_yCoyO2 POWDERS BY COMPLEX SOL-GEL PROCESS (CSGP) AND THEIR ELECTROCHEMICAL CHARACTERIZATION A. Deptuta, W. Lada, F. Croce, F. Ronci, A. Di Bartolomeo, A. Brignocchi 80 FABRICATION OF L12TÍO3 SPHERICAL MICROPARTICLES BY A CLASSICAL SOL-GEL ROUTE A. Deptuta, T. Olczak, W. Lada, B. Sartowska, A.G. Chmielewski, C. Alvani, S. Casadio 82 PROTON NUCLEAR MAGNETIC RESONANSE STUDIES OF HYDRATION OF OXAALKANES IN BENZENE SOLUTION E. Gniazdowska, P. Dobrowolski, J. Narbutt 85 X-RAY MOLECULAR AND CRYSTAL STRUCTURE OF BIS(PENTANE-2,4-DIONATO)LEAD(II) J. Narbutt, B. Paluchowska, J.K. Maurin 86 SMALL AGGREGATES FORMED IN POLYURETHANE-MEMBRANE STRUCTURE DURING SWELLING IN ETHANOL H. Grigoriew, A. Wolińska-Grabczyk, A.G. Chmielewski, H. Amenitsch, S. Bernstorff 88 NEW VIEW ON STRUCTURE OF THE SYSTEM: CELLULOSE-WATER FROM TEMPERATURE TIME-RESOLVED SAXS H. Grigoriew, A.G. Chmielewski, H. Amenitsch 90 NEUTRON SPECTROSCOPY AND AB INITIO STUDY OF HYDROGEN BOND DYNAMICS IN L-SERINE A. Pawlukojć, J. Leciejewicz 91 NEUTRON DIFFRACTION STUDY OF INCOMMENSURATE MAGNETIC ORDER IN TbOs2S¡2 AND HoOs2S¡2 M. Kolenda, M. Hofmann, J. Leciejewicz, B. Penc, A. Szytuta 92 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXVIII: THE CRYSTAL STRUCTURE OF A FURAN-2-CARBOXYLATE POLYANIONIC COMPLEX 2+ n[Zn(H2O)6] [Zn8Na2(C5H3O5)i8(OH)2]^ B. Paluchowska, J.K. Maurin, J. Leciejewicz 92 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXIX: THE CRYSTAL STRUCTURE OF MONOAQUABIS(TRANS-5-METHYLPYRAZINE-2-CARBOXYLATO N,O) COPPER(II) TRIHYDRATE H. Ptasiewicz-Bąk, J. Leciejewicz 93 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXX: THE CRYSTAL STRUCTURE OF A Ca(II) COMPLEX WITH PYRIDINE-3.4-DICARBOXYLATE LIGAND W. Starosta, H. Ptasiewicz-Bąk, J. Leciejewicz 94 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXI: THE CRYSTAL STRUCTURE OF A Ca(II) COMPLEX WITH PYRIDINE-3,5-DICARBOXYLATE LIGAND W. Starosta, H. Ptasiewicz-Bąk, J. Leciejewicz 95 RADIOBIOLOGY 97 DIFFERENTIAL INACTIVATION OF DNA-DEPENDENT PROTEIN KINASE IN H2O2-TREATED L5178Y-R AND L5178Y-S CELLS B. Sochanowicz, M. Kruszewski, I. Szumiel 99 ERBSTATIN-INDUCED INCREASE IN APOPTOSIS DOES NOT RADIOSENSITIZE L5178Y CELLS I. Buraczewska, A. Gasińska, I. Grądzka, N. Jarocewicz, B. Sochanowicz, I. Szumiel 99 ERBSTATIN-INDUCED ALTERATIONS IN CELL CYCLE DISTRIBUTION IN THE X-IRRADIATED L5178Y CELLS I. Buraczewska, A. Gasińska, I. Szumiel 100 TOTAL TYROSINE PROTEIN KINASE ACTIVITY IN X-IRRADIATED L5178Y CELLS B. Sochanowicz, I. Szumiel 102 APOPTOSIS IN MAMMALIAN CELL LINES WITH DIFFERENT RADIATION SENSITIVITY: COMPARISON AFTER LOW DOSE X-IRRADIATION A. Jaworska, P. De Angelis, I. Szumiel, G. Olsen, J. Reitan 103 CELL CULTURE CONDITIONS AS A CRITICAL FACTOR IN DETERMINATION OF APOPTOSIS: FETAL CALF VERSUS