SAFETY DATA SHEET Issuing Date 12-Mar-2008 Revision Date 24-Oct-2019 Revision Number 4 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Identifier Product Name TETRAETHYL TITANATE Other means of identification Product Code 1308200 CAS Number MIXTURE Formula MIXTURE Synonyms Ethanol, Titanium(4+) Salt- + 2-Propanol, Titanium(4+) Salt - UN-No UN1993 Recommended use of the chemical and restrictions on use Recommended Use Misc. Intermediate Uses advised against Do not use where contact with food or drinking water is possible. Avoid prolonged contact with eyes, skin, and clothing. Details of the supplier of the safety data sheet Supplier Address ACETO US, LLC 4 Tri Harbor Court Port Washington, NY 11050-4661 Phone: (516) 627-6000 Fax: (516) 627-6093 Email: [email protected] Emergency Telephone Number(s) ChemTrec: 1-800-424-9300 Outside of the United States: 1-703-527-3887 2. HAZARDS IDENTIFICATION Classification Acute toxicity - Inhalation (Vapors) Category 3 Skin Corrosion/Irritation Category 2 Serious eye damage/eye irritation Category 2A Flammable liquids Category 3 Label elements Emergency Overview Signal Word DANGER Hazard statements Toxic if inhaled Causes skin irritation Causes serious eye irritation FLAMMABLE LIQUID AND VAPOR _____________________________________________________________________________________________ Page 1 / 10 1308200 TETRAETHYL TITANATE Revision Date 24-Oct-2019 _____________________________________________________________________________________________ Appearance Physical State Odor Clear Colorless to Light yellow Liquid No information available Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present . If eye irritation persists: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None known Other Information No information available 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Ethanol, Titanium(4+) Salt- + 2-Propanol, Titanium(4+) Salt - Formula MIXTURE Chemical name CAS No. Weight-% North American Hazard Indicator Tetraethyl Titanate 3087-36-3 85 True Titanium Isopropoxide 546-68-9 15 True _____________________________________________________________________________________________ Page 2 / 10 1308200 TETRAETHYL TITANATE Revision Date 24-Oct-2019 _____________________________________________________________________________________________ 4. FIRST AID MEASURES First Aid Measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before reuse. Consult a physician. Inhalation Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Consult a physician. Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Consult a physician. Self-Protection of the First Aider Use personal protective equipment as required. Avoid contact with eyes, skin and clothing. Remove all sources of ignition. Most important symptoms and effects, both acute and delayed Signs and Symptoms No information available. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable properties Flammable liquid. Vapors may cause flash fire or explosion. Suitable Extinguishing Media Water spray. Alcohol-resistant foam. Dry chemical. Carbon dioxide (CO2). Water mist may be used to cool closed containers. Unsuitable Extinguishing Media No information available. Hazardous Combustion Products Thermal decomposition or combustion may produce hazardous gases and/or materials. Explosion Data Not available Sensitivity to mechanical impact Not available. Sensitivity to static discharge Not available. Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Flash back possible over considerable distance. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective _____________________________________________________________________________________________ Page 3 / 10 1308200 TETRAETHYL TITANATE Revision Date 24-Oct-2019 _____________________________________________________________________________________________ equipment as required. Avoid contact with eyes, skin and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Remove all sources of ignition. Take precautionary measures against static discharges. Pay attention to flashback. Environmental Precautions Local authorities should be advised if significant spillages cannot be contained. Methods and material for containment and cleaning up Methods for Clean-up Evacuate personnel to safe areas. Remove all sources of ignition. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use spark-proof tools and explosion-proof equipment. Ground and bond containers when transferring material. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for safe handling Handling Use only in an area equipped with a safety shower. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation. Do not breathe vapors/dust. Do not breathe vapours or spray mist. Avoid contact with eyes, skin and clothing. Keep away from open flames, hot surfaces and sources of ignition. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Avoid repeated exposure. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep away from open flames, hot surfaces and sources of ignition. Protect from moisture. Incompatible Materials Strong Acids. Zinc and its Alloys. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Tetraethyl Titanate - - - 3087-36-3 Titanium Isopropoxide - - - 546-68-9 Appropriate engineering controls Individual protection measures, such as personal protective equipment Eye/Face Protection Tight sealing safety goggles. Skin and body protection Use suitable eye protection and gloves. Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties _____________________________________________________________________________________________ Page 4 / 10 1308200 TETRAETHYL TITANATE Revision Date 24-Oct-2019 _____________________________________________________________________________________________ Appearance Clear Colorless to Light yellow Physical State Liquid Odor No information available Odor Threshold No information available Property Values Remarks • Method pH No Data Available Melting point / Freezing point No Data Available Literary Reference Boiling point / boiling range No information available Flash Point [Tetraethyl Titanate] 33°C No information available [Titanium Isopropoxide] 45°C Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air No information available Upper flammability limit No information available Lower flammability limit Not available Vapor Pressure No information available Vapor Density Not available Specific Gravity 1.08 - 1.10 g/cm3 @ 25°C Water Solubility No information available