CH 460 Dr. Muccio Worksheet 4 1. What Is the Difference Between An

CH 460 Dr. Muccio Worksheet 4 1. What Is the Difference Between An

CH 460 Dr. Muccio Worksheet 4 1. What is the difference between an aldose and a ketose? 2. What is the oxidation number of the carbon on the following 3 groups? 3. Circle the carbons in the figure below that are chiral. How many isomers does this molecule have? 4. What is the difference between an epimer and an enantiomer? 5. How is the Fisher projection of D-glucose converted to L-glucose? 6. The chemical formula of a tetrose monosaccharide is _____. a. C6H12O6 b.C4H10O4 c.C6H10O4 d.C4H8O4 e.None 7. Match the carbohydrates to their descriptions on the left. i. D-Glyceraldehyde _____ A. C-2 Epimer of Glucose ii. D-Threose _____ B. C-2 Epimer of Threose iii. D-Ribose _____ C. Pentose with D,D,D stereochem iv. D-Mannose _____ D. Triose v. D-Galactose _____ E. Hexose with DLDD stereochem vi. D-Erythrose _____ F. C-3 Epimer of Ribose vii. D-Xylose _____ G. C-4 Epimer of Glucose viii. D-Glucose _____ H. C-2 Epimer of Erythrose ix. D-Arabinose _____ I. C-2 Epimer of Ribose x. D-Fructose _____ J. Ketose of Letter D xi. D-Xylulose _____ K. Ketose of Letter F xii. D-Erythrulose _____ L. Enantiomer of Letter A xiii. Dihydroxyacetone ____ M. Ketose of Letter B xiv. D-Ribulose _____ N. Ketose of Letter E xv. L-Mannose _____ O. Ketose of Letter C CH 460 Dr. Muccio Worksheet 4 8. In the conversion of aldoses to their ketoses, the _____ carbon loses its stererochemistry. a. C-3 b.C-2 c.C-4 d.C-5 e.C-1 9. The generic form of a hemiacetal is _________? a. R-O-C-H b. R-C-O-H c. R-OR-CH-OH d. R-C-C-OH e. none 10. In Haworth projection of carbohydrates, the D and L prefix denotes the position of the ______ group on carbon ______. a. Carbonyl; 6 b. OH; 5 c. O-; 6 d. OH; 6 e. Carbonyl; 5 11. Below is the Haworth Projection of ______________. a. α-L-Glucopyranose b. α-D-Glucopyranose c. β-D- Glucopyranose d. β-L-Glucopyranose e. D-Glucose 12. Galactose forms a (furanose/pyranose) ring structure whereas fructose forms a (furanose/pyranose). 13. __________ inverts the position of the anomeric carbon. The ring structure of carbohydrates is ______ stable than the open chain form. a. a. Epimerization; more c. Mutarotation; more b. c. Epimerization; less d. Mutarotation; less 14. The ________ position on the anomeric carbon is the more stable. a. L b. D c. β d. α 15. The ______anomer of the ______ form of ribose is the more stable. It occurs in a ______:1 ratio. a. β; pyranose; 3 b. β; furanose; 4 c. α; pyranose; 3 d. α; furanose; 4 16. Can you identify the reducing and non-reducing end of the disaccharide below? Put a star on the acetal carbon and a triangle around the hemiacetal carbon. Name the sugar below. CH 460 Dr. Muccio Worksheet 4 17. Which of the following disaccharides does not have a reducing end? a. Lactose b. Glucose c. Cellobiose d. Sucrose e. Amylopectin 18. Match the di/polysaccharides to their descriptions on the left. Some will have multiple matches. i) β-Glc (14)Glc _________ A. Cellobiose ii) α-Glc (12)-β-Fru _______ B. Sucrose iii) α-Glc (14)Glc __________ C. Branched homoglycan of Glc iv) β-Fru (21)-α-Glc __________ D. Maltose v) β-Gal (14)Glc __________ E. Linear homoglycan of Glc vi) Amylopectin _______ F. Has no reducing ends vii) Cellulose________ G. Has α(1,6) branches viii)Amylose __________ H. Lactose I. Linear polymer of Glc with β(1,4) glycosidic bonds J. 100% sweet K. Humans cannot digest – not nutritional L. hydrolyzed by Cellulases that break β(1,4) bonds M. Makes up a minority of plant starch N. Makes up a majority of plant starch .

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    3 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us