SAFETY DATA SHEET WANNATE® 8001 WANHUA CHEMICAL GROUP Co., LTD. Chemwatch Hazard Alert Code: 2 Version No: 4.8 Safety Data Sheet Safety Data Sheet - Authored according to GB/T16483(2008) and GB/T17519(2013) Issue Date: 23/10/2019 Print Date: 23/10/2019 L.GHS.CHN.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name WANNATE® 8001 Synonyms Modified Isocyanate Other means of identification Not Available Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses It is used in the production of PU foam in automotive,furniture and shoe industries, especially suitable for viscoelastic foam. Details of the supplier of the safety data sheet Registered company name WANHUA CHEMICAL GROUP Co., LTD. Address No.17 Tianshan Road, Yantai, Shandong China Telephone 0535-3031150 Fax 0535-338222-1150 Website http://www.whchem.com Email [email protected] Emergency telephone number Association / Organisation WANHUA CHEMICAL GROUP Co., LTD. Emergency telephone +86 532-83889090 numbers Other emergency telephone +86 535-8203123 numbers SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture SUMMARY OF HAZARD IN AN EMERGENCY SITUATION Liquid.Does not burn. Harmful by inhalation. Danger of cumulative effects. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Eye Irritation Category 2A, Respiratory Sensitizer Category 1, Specific target organ toxicity - repeated exposure Category 2, Acute Toxicity Classification [1] (Inhalation) Category 4, Specific target organ toxicity - single exposure Category 3 (respiratory tract irritation), Skin Corrosion/Irritation Category 2, Skin Sensitizer Category 1A, Carcinogenicity Category 2 1. Classified by Chemwatch; 2. Classification drawn from Catalog of Hazardous Chemical; 3. Classification drawn from Regulation (EU) No Legend: 1272/2008 - Annex VI Label elements Hazard pictogram(s) SIGNAL WORD DANGER Hazard statement(s) H319 Causes serious eye irritation. Continued... Version No: 4.8 Page 2 of 11 Issue Date: 23/10/2019 Print Date: 23/10/2019 WANNATE® 8001 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. (Skin) (Oral, Dermal, Inhalation) H332 Harmful if inhaled. H335 May cause respiratory irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. Precautionary statement(s) Prevention P201 Obtain special instructions before use. P260 Do not breathe mist/vapours/ spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P261 Avoid breathing mist/vapours/spray. P202 Do not handle until all safety precautions have been read and understood. P264 Wash all exposed external body areas thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P308+P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment (see advice on this label). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician/first aider. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P314 Get medical advice/attention if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. Physical and Chemical Hazard Liquid.Does not burn. Health Hazards Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. Inhaled The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation of vapours, fumes or aerosols, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress. The material is not thought to produce adverse health effects following ingestion (as classified by EC Directives using animal models). Ingestion Nevertheless, adverse systemic effects have been produced following exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum. Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models). Systemic harm, however, has been identified following exposure of animals by at least one other route and the material may still produce health damage following entry through wounds, lesions or abrasions. Good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an Skin Contact occupational setting. Open cuts, abraded or irritated skin should not be exposed to this material Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. Eye Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn). Continued... Version No: 4.8 Page 3 of 11 Issue Date: 23/10/2019 Print Date: 23/10/2019 WANNATE® 8001 Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical systems. Chronic On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or mutagenic effects; in respect of the available information, however, there presently exists inadequate data for making a satisfactory assessment. Environmental Hazards See Section 12 Other hazards SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 26447-40-5* 60-69 Diphenylmethane diisocyanate (MDI) mixed isomers 58228-05-0* 25-10 Methylenediphenyl diisocyanate mixed isomers and oligomers reaction product with polyether polyol 9016-87-9* 15-21 Polymeric diphenylmethane diisocyanate SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with eyes: Wash out immediately with water. Eye Contact If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Inhalation Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Advise for rescue team (PPE requirement for rescue personnel) Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Fire Fighting DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. Non combustible. Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn. May emit poisonous fumes. SECTION 6 ACCIDENTAL RELEASE MEASURES Continued... Version No: 4.8 Page 4 of 11 Issue Date: 23/10/2019 Print Date: 23/10/2019