safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 date of compilation: 2016-08-25 Version: 2.0 en Revision: 2016-08-25 Replaces version of: 2016-08-25 Version: (1.0) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Identification of the substance Methylcyclohexane D 14 Article number 9913 Registration number (REACH) This information is not available. EC number 233-325-3 CAS number 10120-28-2 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: laboratory chemical 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone: +49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data : Department Health, Safety and Environment sheet e-mail (competent person) : [email protected] 1.4 Emergency telephone number Emergency information service Poison Centre Munich: +49/(0)89 19240 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Classification acc. to GHS Section Hazard class Hazard class and cat- Hazard egory state- ment 2.6 flammable liquid (Flam. Liq. 2) H225 3.2 skin corrosion/irritation (Skin Irrit. 2) H315 3.8D specific target organ toxicity - single exposure (narcotic effects, (STOT SE 3) H336 drowsiness) 3.10 aspiration hazard (Asp. Tox. 1) H304 4.1A hazardous to the aquatic environment - acute hazard (Aquatic Acute 1) H400 4.1C hazardous to the aquatic environment - chronic hazard (Aquatic Chronic 2) H411 United Kingdom (en) Page 1 / 14 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 Remarks For full text of Hazard- and EU Hazard-statements: see SECTION 16. The most important adverse physicochemical, human health and environmental effects Narcotic effects. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms Hazard statements H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements Precautionary statements - prevention P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective clothing/eye protection. Precautionary statements - response P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician. P303+P361+P353 IF ON SKIN (or hair): take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Labelling of packages where the contents do not exceed 125 ml Signal word: Danger Symbol(s) H304 May be fatal if swallowed and enters airways. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician. 2.3 Other hazards There is no additional information. United Kingdom (en) Page 2 / 14 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 SECTION 3: Composition/information on ingredients 3.1 Substances Name of substance Methylcyclohexane D 14 EC number 233-325-3 CAS number 10120-28-2 Molecular formula C7D14 g Molar mass 112,3 /mol SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off contaminated clothing. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact Rinse skin with water/shower. Take off contaminated clothing. In case of skin irritation, consult a physician. Following eye contact Rinse cautiously with water for several minutes. In all cases of doubt, or when symptoms persist, seek medical advice. Following ingestion Aspiration hazard. Observe aspiration hazard if vomiting occurs. Call a physician immediately. 4.2 Most important symptoms and effects, both acute and delayed Aspiration hazard, Irritation, Dizziness, Drowsiness, Narcosis 4.3 Indication of any immediate medical attention and special treatment needed none SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings water spray, foam, dry extinguishing powder, carbon dioxide (CO2) Unsuitable extinguishing media water jet United Kingdom (en) Page 3 / 14 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 5.2 Special hazards arising from the substance or mixture Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours can form explosive mixtures with air. Hazardous combustion products In case of fire may be liberated: carbon monoxide (CO), carbon dioxide (CO2) 5.3 Advice for firefighters Do not allow firefighting water to enter drains or water courses. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Wearing of suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. Avoidance of ignition sources. 6.2 Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. Explosive properties. 6.3 Methods and material for containment and cleaning up Advices on how to contain a spill Covering of drains. Advices on how to clean up a spill Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Provision of sufficient ventilation. • Measures to prevent fire as well as aerosol and dust generation Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. United Kingdom (en) Page 4 / 14 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed. Incompatible substances or mixtures Observe hints for combined storage. Consideration of other advice Ground/bond container and receiving equipment. • Ventilation requirements Use local and general ventilation. • Specific designs for storage rooms or vessels Recommended storage temperature: 15 - 25 °C. 7.3 Specific end use(s) No information available. SECTION 8: Exposure controls/personal protection 8.1 Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) No data available. Relevant DNELs/DMELs/PNECs and other threshold levels • human health values Endpoint Threshold Protection goal, Used in Exposure time level route of exposure DNEL 64,3 mg/m³ human, inhalatory worker (industry) chronic - systemic effects DNEL 1.355 mg/m³ human, inhalatory worker (industry) acute - systemic effects DNEL 1,7 mg/kg human, dermal worker (industry) chronic - systemic effects bw/day • environmental values Endpoint Threshold level Environmental compartment Exposure time PNEC 1,34 µg/l freshwater short-term (single instance) PNEC 0,134 µg/l marine water short-term (single instance) PNEC 273 µg/l sewage treatment plant (STP) short-term (single instance) PNEC 36,2 µg/kg freshwater sediment short-term (single instance) PNEC 3,62 µg/kg marine sediment short-term (single instance) PNEC 9,7 µg/kg soil short-term (single instance) United Kingdom (en) Page 5 / 14 safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Methylcyclohexane D 14 99,5 Atom%D article number: 9913 8.2 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection Use safety goggle with side protection. Skin protection • hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. • type of material NBR (Nitrile rubber) • material thickness 0,4 mm. • breakthrough times of the glove material >480 minutes (permeation: level 6) • other protection measures Take recovery periods