Encyclopedia of INORG ANIC CHEMISTRY Second Edition Editor-in-Chief R. Bruce King University of Georgia, Athens, GA, USA Volume IX T-Z WILEY Contents VOLUME I Ammonolysis 236 Ammoxidation 236 Amphoterism 236 Ab Initio Calculations Analytical Chemistry of the Transition Elements 236 Acceptor Level Ancillary Ligand 248 Acetogen Anderson Localization 248 Acid Catalyzed Reaction Angular Overlap Model 248 7r-Acid Ligand Anion 249 Acidity Constants Antiaromatic Compound 249 Acidity: Pauling's Rules 2 Antibonding 250 Acids & Acidity 2 Antiferromagnetism 250 Actinides: Inorganic & Coordination Chemistry 2 Antigen 250 Actinides: Organometallic Chemistry 33 Antimony: Inorganic Chemistry 250 Activated Complex 59 Antimony: Organometallic Chemistry 258 Activation 59 Antioxidant 266 Activation Parameters 59 Antiport 266 Activation Volume 60 Antistructure 266 Active Site 60 Antitumor Activity 266 Adamson's Rules 60 Apoprotein 266 Addition Compound 60 Aqua 267 Agostic Bonding 60 Arachno Cluster 267 Alkali Metals: Inorganic Chemistry 61 Arbuzov Rearrangement 267 Alkali Metals: Organometallic Chemistry 84 Archaea 267 Alkalides 94 Arene Complexes 267 Alkaline Earth Metals: Inorganic Chemistry 94 Arsenic: Inorganic Chemistry 268 Alkaline Earth Metals: Organometallic Chemistry 116 Arsenic: Organoarsenic Chemistry 288 Alkane Carbon-Hydrogen Bond Activation 147 Arsine & As-donor Ligands 308 Alkene Complexes 153 Associative Substitution 309 Alkene Metathesis 154 Asymmetrie Synthesis 309 Alkene Polymerization 154 Asymmetrie Synthesis by Homogeneous Catalysis 309 Alkoxycarbonylation 154 Asymmetrie Unit 332 Alkyl Complexes 154 Ate Complexes 332 Alkyl Migration 154 Atom Transfer 332 Alkylidene 155 Atomic Mass 332 Alkylidyne 155 Atomic Number 332 Alkyne Complexes 155 Atomization Enthalpy of Metals 332 Alkyne Metathesis 155 Atoms & Ions 333 Allosterism 155 Aufbau Principle 333 Allotrope 156 Auger Spectroscopy 333 Alloys 156 Autoprotolysis 334 AUyl Complexes 169 Autoxidation 334 Alpha Helix 170 Alumina - 170 Back Bonding 335 Aluminum: Inorganic Chemistry 170 Bacteria 335 Aluminuni: Organometallic Chemistry 185 Bailar Twist 335 Ambidentate Ligand 210 Band Gap 336 Amide (Amido) Complexes 210 Band Theory 336 Ammonia & N-donor Ligands 210 :r-Base 336 XXII CONTENTS BCS Theory 336 VOLUME II Becquerel 337 Bent Metallocenes 337 C-Terminus 603 Berry Pseudorotation 337 Cadmium: Inorganic & Coordination Chemistry 603 Beryllium: Inorganic Chemistry 337 Cadmium: Organometallic Chemistry 620 Beryllium & Magnesium: Organometallic Cage Effect 630 Chemistry 342 Calcium-binding Proteins 630 Beta Sheet 369 Calixarenes 666 Beta Turn 369 Carbanion 666 Bidentate Ligand 370 Carbene Complexes 666 Binary Compounds 370 Carbides: Transition Metal Solid-state Chemistry 674 Binding Energy of Nuclei 370 Carbocation 690 Bioavailability 370 Carbometalation 690 Bioconjugate Chemistry 370 Carbon-Carbon & Carbon-Heteroatom Activation 690 Bioinformatics 370 Carbon: Fullerenes 696 Bioinorganic Chemistry 370 Carbon: Inorganic Chemistry 718 Biomimesis 371 Carbon: Nanotubes 730 Biomimetic Synthesis of Nanoparticles 371 Carbonyl Complexes of the Transition Metals 764 Biomineralization 391 Carbonyl Compound 781 Biosynthesis 404 Carbonylation 781 Biphasic Process 404 Carbonylation Processes by Homogeneous Catalysis 781 Bismuth: Inorganic Chemistry 404 Carborane 814 Carbyne Complexes 814 Bismuth: Organometallic Chemistry 425 Catalase 814 Bite Angle 440 Catalysis 815 Bleomycin 440 Catenation 815 5-Bond 440 Cation 815 7T-Bond 441 Cation-activated Enzymes 815 er-Bond 441 Ceramic Material 824 er-Bond Complexes 441 Ceramics 824 Bond Dissociation Energy 441 Chalcogenides: Solid-state Chemistry 825 Bond Energies 442 Chalcogens 863 Bond Length 445 Chalcophiles 863 Bond Lengths in Inorganic Solids & Liquids 446 Charge Carrier 864 a-Bond Metathesis 452 Charge Controlled Reactions 864 Bond Multiplicity 452 Charge Density Wave 864 Bond Order 452 Charge Transfer 864 Bond Valence Method 453 Chauvin Mechanism 864 Bonding Energetics of Organometallic Compounds 453 Chelate Effect 865 Borates: Solid-state Chemistry 472 Chelating Ligands 865 Borazine 481 Chelation Therapy 865 Borides: Solid-state Chemistry 481 Chemical Bonding 865 Chemical Vapor Deposition 865 Born-Haber Cycle 494 Chevrel Phases 865 Boron Hydrides 494 Chimie Douce 866 Boron: Inorganic Chemistry 499 Chiral 866 Boron: Metallacarbaboranes 524 Chiral Auxiliary 866 Boron: Metalloboranes 544 Chlorine, Bromine, Iodine, & Astatine: Inorganic Boron-Nitrogen Compounds 544 Chemistry 866 Boron: Organoboranes 560 Chlorophyll 887 Boron: Polyhedral Carboranes 598 Chloroplast 887 Borosilicate Glass 601 Chromium: Biological Relevance 888 Bridging Ligand 601 Chromium: Inorganic & Coordination Chemistry 893 Brillouin Zone 602 Chromium: Organometallic Chemistry 907 Buckminsterfullerene 602 Chromocene 925 CONTENTS XXIII Class A & Class B Behavior 925 Counter Ions 1226 Clathrate 925 Counting Electrons 1226 Clay Minerals 925 Coupling 1226 Close Packing 925 Covalent Bonds 1226 Closo Cluster 925 Covalent Radii 1227 Cluster 926 Crabtree's Catalyst 1227 Cluster Compounds: Inorganometallic Compounds Creutz-Taube Complex 1227 Containing.