Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 date of compilation: 2016-07-05 Version: 2.0 en Revision: 2019-11-27 Replaces version of: 2016-07-05 Version: (1) SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Identification of the substance Sodium persulfate Article number 4365 Registration number (REACH) 01-2119495975-15-xxxx EC number 231-892-1 CAS number 7775-27-1 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: laboratory chemical laboratory and analytical use 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone: +49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data : Department Health, Safety and Environment sheet e-mail (competent person) : [email protected] 1.4 Emergency telephone number Name Street Postal code/city Telephone Website National Poisons In- Dudley Rd B187QH Birmingham 844 892 0111 formation Service City Hospital Emergency information service +49/(0)89 19240 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Classification acc. to GHS Section Hazard class Hazard class and cat- Hazard egory state- ment 2.14 oxidising solid (Ox. Sol. 3) H272 3.1O acute toxicity (oral) (Acute Tox. 4) H302 United Kingdom (en) Page 1 / 16 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 Classification acc. to GHS Section Hazard class Hazard class and cat- Hazard egory state- ment 3.2 skin corrosion/irritation (Skin Irrit. 2) H315 3.3 serious eye damage/eye irritation (Eye Irrit. 2) H319 3.4R respiratory sensitisation (Resp. Sens. 1) H334 3.4S skin sensitisation (Skin Sens. 1) H317 3.8R specific target organ toxicity - single exposure (respiratory tract ir- (STOT SE 3) H335 ritation) 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS03, GHS07, GHS08 Hazard statements H272 May intensify fire; oxidiser H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation Precautionary statements Precautionary statements - prevention P220 Keep away from clothing and other combustible materials. P260 Do not breathe dust. Precautionary statements - response P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTRE/doctor if you feel unwell. Labelling of packages where the contents do not exceed 125 ml Signal word: Danger Symbol(s) H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. United Kingdom (en) Page 2 / 16 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. 2.3 Other hazards There is no additional information. SECTION 3: Composition/information on ingredients 3.1 Substances Name of substance Sodium persulfate Registration number (REACH) 01-2119495975-15-xxxx EC number 231-892-1 CAS number 7775-27-1 Molecular formula Na₂S₂O₈ g Molar mass 238,1 /mol SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off contaminated clothing. Following inhalation Remove person to fresh air and keep comfortable for breathing. In case of allergic symptoms, espe- cially in the breathing area, seek medical advice immediately. Following skin contact Rinse skin with water/shower. In case of skin reactions, consult a physician. In case of skin irritation, consult a physician. Following eye contact Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist. Following ingestion Rinse mouth immediately and drink plenty of water. Call a doctor. 4.2 Most important symptoms and effects, both acute and delayed Irritation, Cough, Allergic reactions, Headache, Breathing difficulties, Nausea, Vomiting 4.3 Indication of any immediate medical attention and special treatment needed none United Kingdom (en) Page 3 / 16 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings water spray, foam, dry extinguishing powder, carbon dioxide (CO₂) Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Non-combustible. Oxidising property. Hazardous combustion products In case of fire may be liberated: sulphur oxides (SOx) 5.3 Advice for firefighters Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing appar- atus. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Do not breathe dust. Avoid contact with skin and eyes. 6.2 Environmental precautions Keep away from drains, surface and ground water. 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains. Advice on how to clean up a spill Take up mechanically. Control of dust. Other information relating to spills and releases Place in appropriate containers for disposal. 6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom- patible materials: see section 10. Disposal considerations: see section 13. United Kingdom (en) Page 4 / 16 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 SECTION 7: Handling and storage 7.1 Precautions for safe handling Provide adequate ventilation. Avoid dust formation. When not in use, keep containers tightly closed. • Measures to prevent fire as well as aerosol and dust generation Removal of dust deposits. Take any precaution to avoid mixing with combustibles. Advice on general occupational hygiene Keep away from food, drink and animal feedingstuffs. Wash hands before breaks and after work. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a dry place. Incompatible substances or mixtures Observe hints for combined storage. Consideration of other advice • Ventilation requirements Use local and general ventilation. • Specific designs for storage rooms or vessels Recommended storage temperature: 15 – 25 °C. 7.3 Specific end use(s) No information available. SECTION 8: Exposure controls/personal protection 8.1 Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) Coun- Name of agent Notation Identifier TWA [mg/ STEL [mg/ Source try m³] m³] GB dust i WEL 10 EH40/2005 GB dust r WEL 4 EH40/2005 Notation i Inhalable fraction r Respirable fraction STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15- minute period (unless otherwise specified) TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified) Relevant DNELs/DMELs/PNECs and other threshold levels • human health values Endpoint Threshold Protection goal, Used in Exposure time level route of exposure DNEL 2,06 mg/m³ human, inhalatory worker (industry) chronic - systemic effects DNEL 590 mg/m³ human, inhalatory worker (industry) acute - systemic effects DNEL 2,06 mg/m³ human, inhalatory worker (industry) chronic - local effects United Kingdom (en) Page 5 / 16 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU Sodium persulfate ≥ 99% article number: 4365 Endpoint Threshold Protection goal, Used in Exposure time level route of exposure DNEL 18,2 mg/kg bw/ human, dermal worker (industry) chronic - systemic effects day DNEL 400 mg/kg bw/ human, dermal worker (industry) acute - systemic effects day • environmental values Endpoint Threshold level Environmental compartment mg PNEC 0,076 /l freshwater mg PNEC 0,011 /l marine water mg PNEC 0,763 /l water mg PNEC 3,6 /l sewage treatment plant (STP) mg PNEC 0,275 /kg freshwater sediment mg PNEC 0,04 /kg marine sediment mg PNEC 0,015 /kg soil 8.2 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection Use safety goggle with side protection. Skin protection • hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the