ZINC SULFATE MONOHYDRATE Cambridge Commodities Chemwatch Hazard Alert Code: 3 Chemwatch: 4609-15 Issue Date: 15/04/2021 Version No: 5.1.23.11 Print Date: 27/09/2021 Safety data sheet according to REACH Regulation (EC) No 1907/2006, as amended by UK REACH Regulations SI 2019/758 S.REACH.GB.EN SECTION 1 Identification of the substance / mixture and of the company / undertaking 1.1. Product Identifier Product name ZINC SULFATE MONOHYDRATE Chemical Name zinc sulfate monohydrate Synonyms ZnSO4.7H2O; white vitriol; zinc vitriol; sulfuric acid, zinc salt dried; sulphuric acid, zinc salt (1:1), monohydrate ZnSO4.H2O Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains zinc sulfate monohydrate) Chemical formula H2-O4-S .Zn|H2O4S.Zn Other means of P2605 identification CAS number 7446-19-7 Index number 030-006-00-9 REACH registration 01-2119474684-27-XXXX, 01-2120770765-43-XXXX number 1.2. Relevant identified uses of the substance or mixture and uses advised against Raw material for the manufacture of lithopone and other zinc salts. Also used in synthetic fibre industry, zinc plating, pesticides, Relevant identified uses or flotation. Fungicide, water purification, fertiliser. Uses advised against Not Applicable 1.3. Details of the supplier of the safety data sheet Registered company name Cambridge Commodities Address Lancaster Way Business Park, Ely, Cambridgeshire Cambridgeshire CB6 3NX United Kingdom Telephone +44 1353 667258 Fax Not Available Website Not Available Email [email protected] 1.4. Emergency telephone number Association / Organisation Not Available Product code: Version No: 5.1.23.2 Page 1 of 20 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 4609-15 +44 (0) 1353 667258 Issue Date: 15/04/2021 [email protected] Print Date: 27/09/2021 www.c-c-l.com Emergency telephone Not Available numbers Other emergency Not Available telephone numbers SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classified according to GB-CLP Regulation, UK SI H302 - Acute Toxicity (Oral) Category 4, H318 - Serious Eye Damage/Eye Irritation Category 1, H400 - Hazardous to the Aquatic 2019/720 and UK SI Environment Acute Hazard Category 1, H410 - Hazardous to the Aquatic Environment Long-Term Hazard Category 1 2020/1567 [2] Legend: 1. Classified by Chemwatch; 2. Classification drawn from GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567 2.2. Label elements Hazard pictogram(s) Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H318 Causes serious eye damage. H410 Very toxic to aquatic life with long lasting effects. Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention P280 Wear protective gloves, protective clothing, eye protection and face protection. P264 Wash all exposed external body areas thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. Precautionary statement(s) Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/physician/first aider. P391 Collect spillage. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell. P330 Rinse mouth. Product code: Version No: 5.1.23.2 Page 2 of 20 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 4609-15 +44 (0) 1353 667258 Issue Date: 15/04/2021 [email protected] Print Date: 27/09/2021 www.c-c-l.com Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. 2.3. Other hazards May produce discomfort of the respiratory system and skin*. Possible respiratory sensitizer*. REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 Composition / information on ingredients 3.1.Substances 1.CAS No 2.EC No Classified according to GB-CLP Regulation, UK SI 2019/720 Nanoform Particle %[weight] Name 3.Index No and UK SI 2020/1567 Characteristics 4.REACH No 1.7446-19-7 Acute Toxicity (Oral) Category 4, Serious Eye Damage/Eye 2.Not Available zinc sulfate Irritation Category 1, Hazardous to the Aquatic Environment Acute 3.030-006-00-9 >96 Not Available monohydrate Hazard Category 1, Hazardous to the Aquatic Environment 4.01-2119474684-27- Long-Term Hazard Category 1; H302, H318, H400, H410 [2] XXXX|01-2120770765-43-XXXX Legend: 1. Classified by Chemwatch; 2. Classification drawn from GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties 3.2.Mixtures See 'Information on ingredients' in section 3.1 SECTION 4 First aid measures 4.1. Description of first aid measures If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally Eye Contact lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If dust is inhaled, remove from contaminated area. Inhalation Encourage patient to blow nose to ensure clear passage of breathing. If irritation or discomfort persists seek medical attention. Product code: Version No: 5.1.23.2 Page 3 of 20 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 4609-15 +44 (0) 1353 667258 Issue Date: 15/04/2021 [email protected] Print Date: 27/09/2021 www.c-c-l.com IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. For advice, contact a Poisons Information Centre or a doctor. Urgent hospital treatment is likely to be needed. In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the SDS should be provided. Further action will be the responsibility of the medical specialist. If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the Ingestion SDS. Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. NOTE: Wear a protective glove when inducing vomiting by mechanical means. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed Absorption of zinc compounds occurs in the small intestine. The metal is heavily protein bound. Elimination results primarily from faecal excretion. The usual measures for decontamination (Ipecac Syrup, lavage, charcoal or cathartics) may be administered, although patients usually have sufficient vomiting not to require them. CaNa2EDTA has been used successfully to normalise zinc levels and is the agent of choice. [Ellenhorn and Barceloux: Medical Toxicology] SECTION 5 Firefighting measures 5.1. Extinguishing media Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. 5.2. Special hazards arising from the substrate or mixture Fire Incompatibility None known. 5.3. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Fire Fighting Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Product code: Version No: 5.1.23.2 Page 4 of 20 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 4609-15 +44 (0) 1353 667258 Issue Date: 15/04/2021 [email protected] Print Date: 27/09/2021 www.c-c-l.com Equipment should be thoroughly decontaminated after use. Non combustible. Not considered a significant fire risk, however containers may burn. Decomposition may produce toxic fumes of: Fire/Explosion Hazard sulfur oxides (SOx) sulfur dioxide (SO2) metal oxides SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures See section 8 6.2. Environmental precautions See section 12 6.3. Methods and material for containment and cleaning up Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Minor Spills Control personal contact with the substance, by using protective equipment.