CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): ___________________________________ Building: __________________________________________________________ Supervisor: _______________________________________________________ Department: _______________________________________________________ Telephone numbers 911 for Emergency and urgent consultation 48221 Police business line 46919 Fire Dept business line 46371 Radiological and Environmental Management Revisied on: Enter a revision date here. All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboraotry Standard 29 CFR 19190.1450. Purdue University laboratories may use this document as a starting point for creating their work area specific CHP. Minimally this cover page is to be edited for work area specificity (non-West Lafayette laboratories are to place their own emergency, fire, and police telephone numbers in the space above) AND appendix K must be completed. This instruction and information box should remain. This model CHP is version 2010A; updates are to be found at www.purdue.edu/rem This page intentionally blank. PURDUE CHEMICAL HYGIENE PLAN AWARENESS CERTIFICATION For CHP of: ______________________________ Professor, building, rooms The Occupational Safety and Health Administration (OSHA) requires that laboratory employees be made aware of the Chemical Hygiene Plan at their place of employment (29 CFR 1910.1450). The Purdue University Chemical Hygiene Plan and Hazardous Materials Safety Manual serves as the written Chemical Hygiene Plan (CHP) for laboratories using chemicals at Purdue University. The CHP is a regular, continuing effort, not a standby or short term activity. Departments, divisions, sections, or other work units engaged in laboratory work whose hazards are not sufficiently covered in this written manual must customize it by adding their own sections as appropriate (e.g. standard operating procedures, emergency procedures, identifying activities requiring prior approval). See Appendix K. After reading the "Purdue Chemical Hygiene Plan and Hazardous Material Safety Manual," complete and return a copy of this form to your supervisor or to your department’s Safety Committee Chair. By signing below you acknowledge that you are aware of the Chemical Hygiene Plan and the policies and procedures applicable to the OSHA standard (29 CFR 1910.1450). Your supervisor will provide additional information and training as appropriate. Please type or print legibly. Name: Work Phone: Student or staff ID number: Email address: Department: Job Classification (if employee): Building: Room: Supervisor, instructor, or P. I. for your work area: Signature: Date: Completed CHP Awareness Certifications are to be filed in a central administrative location within the staff member’s department. These and all safety training records should be organized in a way that allows original records to be retrieved quickly and efficiently on request by an OSHA inspector or a REM staff member, and to be retrieved for a single staff member or for an entire work group (identified by supervisor). The official versions of all REM forms and documents are the versions at the REM website. Always check there -- being at www.purdue.edu/REM -- to make sure that you have the official version of any form or other document. i This page intentionally blank. The official versions of all REM forms and documents are the versions at the REM website. Always check there -- being at www.purdue.edu/REM -- to make sure that you have the official version of any form or other document. ii PURDUE UNIVERSITY POLICY STATEMENT It is the policy of Purdue University to take every reasonable precaution to provide a work environment that is free from recognized hazards for its employees in accordance with the General Duty clause of the OSHA Act (Public Law 91-596, Section 5(a)(l)). Purdue University is also required by the OSHA Laboratory Standard to ensure that the necessary work practices, procedures and policies are implemented to protect laboratory employees from all potentially hazardous chemicals in use in their work area. Purdue University has established the Chemical Management Committee with the responsibility to promote safe and proper chemical management at all Purdue University Campuses and related facilities. The Charter of the University Chemical Management Committee is reprinted in Appendix A of this document. The official versions of all REM forms and documents are the versions at the REM website. Always check there -- being at www.purdue.edu/REM -- to make sure that you have the official version of any form or other document. iii TABLE OF CONTENTS Chemical Hygiene Plan Awareness Certification ....................................................... i Purdue University Policy Statement ......................................................................... iii PART I THE OSHA LABORATORY STANDARD AND THE PURDUE CHP THE OSHA LAB STANDARD .................................................................... 2 EMPLOYEE RIGHTS AND RESPONSIBILITIES ............................................ 2 HAZARDOUS CHEMICALS ............................................................................ 2 MATERIAL SAFETY DATA SHEETS (MSDSs) .............................................. 3 CHEMICAL INVENTORIES ............................................................................. 3 PURDUE UNIVERSITY CHEMICAL HYGIENE PLAN .............................. 4 SCOPE AND APPLICATION ........................................................................... 4 RESPONSIBILITY ........................................................................................... 4 EXPOSURE LIMITS ........................................................................................ 5 EMPLOYEE INFORMATION AND TRAINING ................................................ 5 Information ................................................................................................. 6 Training ...................................................................................................... 6 Documentation ........................................................................................... 6 Basic Lab Safety Awareness Training from REM ...................................... 6 MEDICAL CONSULTATIONS AND EXAMINATIONS .................................... 7 HAZARD IDENTIFICATION ............................................................................ 7 CHEMICALS DEVELOPED IN THE LABORATORY ...................................... 7 USE OF RESPIRATORS ................................................................................. 8 STANDARD OPERATING PROCEDURES .................................................... 8 CONTROL MEASURES .................................................................................. 8 PROTECTIVE EQUIPMENT ........................................................................... 8 SPECIAL HAZARDS ....................................................................................... 9 AVAILABILITY ................................................................................................. 9 ANNUAL REVIEW ........................................................................................... 9 SAMPLE MSDS ............................................................................................. 10 Table of contents continued next page The official versions of all REM forms and documents are the versions at the REM website. Always check there -- being at www.purdue.edu/REM -- to make sure that you have the official version of any form or other document. iv Table of Contents, continued PART II HAZARDOUS MATERIALS SAFE HANDLING INFORMATION SAFE HANDLING OF CHEMICALS ................................................................... 15 GENERAL SAFETY GUIDELINES ..................................................................... 15 ENGINEERING CONTROLS .................................................................................... 17 Ventilation Controls ............................................................................................. 17 Proper Use of Ventilation Systems ...................................................................... 17 ADMINISTRATIVE CONTROLS ............................................................................... 18 Restricted Access Areas ..................................................................................... 18 PERSONAL PROTECTIVE EQUIPMENT ................................................................. 19 General Considerations ....................................................................................... 19 Hazards Assessments ......................................................................................... 19 Protection Against Inhalation Hazards ................................................................ 20 Protection of Skin and Body ................................................................................ 20 CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT ........................... 21 CHEMICAL STORAGE ............................................................................................. 22 MODEL WRITTEN SOPs: SPECIAL PRECAUTIONS ....................................... 23 PHYSICAL HAZARDS ..............................................................................................