Version 1.3 Revision date 02/02/2018 SAFETY DATA SHEET 1. Identification Identification Product name: CATANOX® Premium Biodiesel Additive Additional identification Chemical name: Mixture Recommended use and restriction on use Recommended use: Miscellaneous fuel additive Restrictions on use: None identified. Supplier Details Company Name: TARGRAY INDUSTRIES INC Headquarters address: 18105 TRANSCANADIENNE KIRKLAND, QC H9J 3Z4 CANADA Telephone: +1 (514) 695-8095 Emergency telephone number: ▪ FOR TRANSPORT EMERGENCY CALL CHEMTREC 1-800-424-9300 2. Hazard(s) identification Hazard Classification Physical Hazards Flammable liquids Category 4 Health Hazards Acute toxicity (Oral) Category 4 Acute toxicity (Dermal) Category 4 Acute toxicity (Inhalation - dust Category 4 and mist) Carcinogenicity Unknown Category 2 toxicity Acute toxicity, oral 0.0 % Acute toxicity, dermal 0.0 % Acute toxicity, inhalation, vapor 94.3 % Acute toxicity, inhalation, dust 9.1 % or mist Label Elements: Hazard Symbol: SDS_US - CATANOX® Premium Biodiesel Additive 1/15 Version 1.3 Revision date 02/02/2018 Signal Word: Warning Hazard Statement: Combustible liquid. Harmful if swallowed, in contact with skin or if inhaled Suspected of causing cancer. Precautionary Statements: Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of water. IF SWALLOWED: Call a POISON CENTRE/doctor/… if you feel unwell. Rinse mouth. Call a POISON CENTRE/doctor if you feel unwell. Specific measures (see this label). Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical or foam for extinction. Water can be used to cool and protect exposed material. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result None identified. in GHS classification: 3. Composition/information on ingredients Chemical name CAS number Percent by Weight 2-Ethylhexyl nitrate 27247-96-7 80 - 90% Petroleum naphtha 64742-94-5 5 - 10% 2-Ethylhexanol 104-76-7 1 - 5% ++ Naphthalene 91-20-3 0.5 - 1% SDS_US - CATANOX® Premium Biodiesel Additive 2/15 Version 1.3 Revision date 02/02/2018 ++ The listed components are subcomponents of the hazardous ingredients listed above. 4. First-aid measures IF exposed or concerned: Get medical advice/attention. General information: Ingestion: Do NOT induce vomiting. Rinse mouth. Call a POISON CENTRE/doctor if you feel unwell. Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTRE/doctor if you feel unwell. Skin Contact: Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Call a POISON CENTRE/doctor if you feel unwell. Launder contaminated clothing before reuse. Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects, acute and delayed Symptoms: Symptoms may be delayed. See section 11. Indication of immediate medical attention and special treatment needed Treatment: Treat symptomatically. 5. Fire-fighting measures General Fire Hazards: Move containers from fire area if you can do so without risk. Suitable (and unsuitable) extinguishing media Suitable extinguishing CO2, Dry chemical or Foam. Water can be used to cool and protect media: exposed material. Unsuitable extinguishing Not determined. media: Specific hazards arising from Vapors may cause a flash fire or ignite explosively. Prevent buildup of the chemical: vapors or gases to explosive concentrations. Vapors may travel considerable distance to a source of ignition and flash back. Water may cause splattering. Container may rupture on heating. See section 10 for additional information. Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: SDS_US - CATANOX® Premium Biodiesel Additive 3/15 Version 1.3 Revision date 02/02/2018 Special protective Wear full protective firegear including self-containing breathing apparatus equipment for fire-fighters: operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots. 6. Accidental release measures Personal precautions, Ventilate closed spaces before entering them. ELIMINATE all ignition protective equipment and sources (no smoking, flares, sparks or flames in immediate area). Do not emergency procedures: touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep upwind. Keep unauthorized personnel away. See Section 8 of the SDS for Personal Protective Equipment. Methods and material for In case of leakage, eliminate all ignition sources. Dike far ahead of larger containment and cleaning up: spill for later recovery and disposal. Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or confined areas. Environmental Precautions: Avoid release to the environment. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. 7. Handling and storage Precautions for safe handling: DO NOT HEAT. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Observe good industrial hygiene practices. Use only in well-ventilated areas. Use personal protective equipment as required. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Launder contaminated clothing before reuse. Avoid environmental contamination. Maximum Handling 61 °C 142 °F Temperature: Conditions for safe storage, Keep at temperature not exceeding 40°C. Keep cool. Store in a wellincluding any ventilated place. Store away from incompatible materials. See section 10 incompatibilities: for incompatible materials. Do not store near potential sources of ignition. Maximum Storage 45 °C 113 °F Temperature: 8. Exposure controls/personal protection Control Parameters: Occupational Exposure Limits Chemical name Type Exposure Limit Values Source SDS_US - CATANOX® Premium Biodiesel Additive 4/15 Version 1.3 Revision date 02/02/2018 Petroleum naphtha - TWA 200 mg/m3 US. ACGIH Threshold Limit Values (03 2014) Nonaerosol. - as total hydrocarbon vapor Petroleum naphtha REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Petroleum naphtha REL 100 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) Petroleum naphtha PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Petroleum naphtha TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) ++ Naphthalene TWA 10 ppm US. ACGIH Threshold Limit Values (02 2012) ++ Naphthalene STEL 15 ppm 75 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) ++ Naphthalene REL 10 ppm 50 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010) ++ Naphthalene PEL 10 ppm 50 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Other exposure limits Chemical name Type Exposure Limit Values Source 2-Ethylhexyl nitrate TWA 1 ppm Appropriate engineering Mechanical ventilation or local exhaust ventilation is required. Material controls: should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air. Adequate ventilation should be provided so that exposure limits are not exceeded. Individual protection measures, such as personal protective equipment General information: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory and eye protection may be needed in special circumstances, such as poorly ventilated spaces, heating, evaporation of liquids from large surfaces, spraying of mists, mechanical generation of dusts, drying of solids, etc. Eye/face protection: Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Skin Protection Hand Protection: Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves Other: Gloves, coveralls, apron, boots as necessary to minimize contact. Wear apron or protective clothing in case of contact. SDS_US - CATANOX® Premium Biodiesel Additive 5/15 Version 1.3 Revision date 02/02/2018 Respiratory Protection: