232nd ECS Meeting 2017 Meeting Abstracts 2017-02 National Harbor, Maryland, USA 1 – 5 October 2017 Volume 1 of 6 ISBN: 978-1-5108-4907-5 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Some papers in this book may refer to web based images from the electronic version of these proceedings that are not available in this print edition. To view images go to: http://ma.ecsdl.org/site/archive/MA2017-02.xhtml Copyright© (2017) by The Electrochemical Society All rights reserved. Printed by Curran Associates, Inc. (2018) For permission requests, please contact The Electrochemical Society at the address below. The Electrochemical Society 65 South Main Street, Building D Pennington, New Jersey 08534-2839 USA Phone: 1.609.737.1902 Fax: 1.609.737.2743 [email protected] Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2633 Email: [email protected] Web: www.proceedings.com Meeting Abstracts —MA2017-02 232nd ECS Meeting October 1, 2017 - October 5, 2017 —National Harbor, MD © 2017 The Electrochemical Society Table of Contents A01-Battery and Energy Technology Joint General Session 1Detailed Investigation of Physical Parameters of Vanadium Flow Battery Catholytes Nathan Quill, Daniela Oboroceanu, John O'Donnell, Catherine Lenihan, D. Noel Buckley, Robert P. Lynch 2Passive Deposition of Carbon Nanoparticles for Robust Kinetic Enhancement in Vanadium Redox Flow Batteries Douglas Aaron, Sinchul Yeom, Yasser Ashraf Gandomi, Tugrul Ertugrul, Kenneth Kihm, Matthew M. Mench 3Direct Observation of Crossover and Current Distribution in All-Vanadium Redox Flow Batteries Yasser Ashraf Gandomi, Tugrul Y. Ertugrul, Jason T. Clement, Douglas Aaron, Matthew M. Mench 4Delineating Contributions from Vanadium Crossover and Electrode Degradation to Capacity Decay in Vanadium Redox Flow Batteries M. C. Daugherty, Yasser Ashraf Gandomi, Alan Pezeshki, Douglas Aaron, Matthew M. Mench 5Understanding Electrolyte Remixing As a Capacity Fade Mitigation Technique for Vanadium Redox Flow Batteries Nicholas Houghton Casco, Nicholas Kourmanopoulos, Christopher R Dennison, E. Caglan Kumbur, Ertan Agar 6Investigation of Electrode Losses in All-Vanadium Redox Flow Batteries with an Interdigitated Flow Field Shohji Tsushima, Kohei Yamamoto, Takahiro Suzuki 7Lower Overpotential of Vanadium Redox Flow Battery By Partially Mixed Carbon Nanofiber in the Electrode Hirokazu Ishitobi, Satoshi Sugawara, Kosuke Oba, Nobuyoshi Nakagawa 8Novel Obstructed Flow Field Designs for Improved Perfomance in Vanadium Redox Flow Batteries Bilen Akuzum, Nick Robinson, Ertan Agar, E. Caglan Kumbur 9Non-Perflourinated Ion Conducting Membranes with Internal Crosslinking Network for Vanadium Flow Batteries (VFBs) Yuyue Zhao, Zhizhang Yuan, Xianfeng Li, Huamin Zhang 10Study of Transport in a Novel, Heteropoly Acid Hybrid Polymer Membrane Designed for Use in Flow Batteries Andrew R Motz, Mei-Chen Kuo, Ahmet Kusoglu, Michael C Tucker, Adam Z. Weber, Gregory M Haugen, Andrew M Herring 11Optimizing the Design of Redox Flow Battery Electrodes Using Impedance Measurements Advaith Murali, Bo Yang, S. R. Narayanan 12Towards Better Utilization Ratios of Active Materials in Redox Flow Batteries Wentao Duan, Bin Li, Dongping Lu, Xiaoliang Wei, Zimin Nie, Vijayakumar Murugesan, James Kizewski, Aaron Hollas, David Reed, Vincent Sprenkle, Wei Wang 13Redox Flow Batteries Based on Aqueous Soluble Organics Xiaoliang Wei, Aaron Hollas, Zheng Yang, Jinhua Huang, Wentao Duan, Bin Li, Zimin Nie, Eric Walter, Murugesan Vijayakumar, David Reed, Zhengcheng Zhang, Wei Wang, Vincent Sprenkle 14Toward Soluble, Stable Organic Electroactive Materials for Non-Aqueous Redox Flow Batteries Susan A Odom, Aman Preet Kaur, Harsha A Attanayake, Matthew D Casselman, Jarrod David Milshtein, Jeffrey A Kowalski, Corrine F Elliott, S R Parkin, Chad Risko, John Anthony, Fikile R. Brushett 15Aqueous Organic Redox Flow Batteries (AORFBs) for Sustainable and Safe Renewable Energy Storage Bo Hu, Camden DeBruler, Tianbiao Liu 16Organic Anolyte Species for Aqueous Redox Flow Batteries Aaron Hollas, Xiaoliang Wei, Bin Li, Wentao Duan, Zimin Nie, Vijayakumar Murugesan, James Kizewski, David Reed, Wei Wang, Vincent Sprenkle 17Ambient Temperature Aqueous Sulfur Batteries for Ultralow Cost Grid Storage Zheng Li, Menghsuan Pan, Liang Su, Ping-chun Tsai, Joseph M. Valle, Andres F Badel, Stephanie L. Eiler, Fikile R. Brushett, Yet-Ming Chiang 18A Low-Cost, High-Performance Polysulfide/Ferrocyanide Redox Flow Battery Using Highly Active Metal Pyrites Catalysts Wenjie Li, Yifan Dong, Song Jin 19Illuminating Heterogeneous Mass Transport in Commercial Porous Electrodes for Aqueous Flow Batteries By Fluorescence Microscopy Andrew A. Wong, Shmuel Rubinstein, Michael J. Aziz 20Characterization of the Efficiency Losses in the Minimal Architecture Zinc-Bromine Battery Kevin William Knehr, Shaurjo Biswas, Hang Huynh, Daniel A Steingart 21Unlocking the Capacity of Iodide for High-Energy-Density Polyiodide-Based Redox Flow Batteries Guo-Ming Weng, Zhejun Li, Guangtao Cong, Yucun Zhou, Yi-Chun Lu 22(Invited) Transport Phenomena in Electrochemical Energy-Conversion Technologies Adam Z. Weber 23Unit Cell Model of a Regenerative Hydrogen-Vanadium Fuel Cell Catalina Pino, Harini Hewa Dewage, Vladimir Yufit, Nigel P. Brandon 24Hydrogen-Vanadium Reversible Fuel Cell Crossover Study Regis Paul Dowd, Devon Powers, Ryszard Wycisk, Peter N. Pintauro, Trung Van Nguyen 25Batteries and Fuel Cells with Convective Mobile Electrolyte Halbert Fischel, Philip Lubin, Brian Clark 26(Invited) Highly Proton Conducting Membranes for Electrochemical Energy Conversion Applications Andrew M Herring, Andrew R Motz, Mei-Chen Kuo, Vinh Nguyen 27Pore Level Liquid Protrusion Under Mixed Wetting and Geometry Alexandru Herescu 28Linking Initial Microstructure to Microstructure Evolution and Conductivity Change in SOFC Electrodes: A Phase Field Simulation Yinkai Lei, Tian-Le Cheng, You-Hai Wen 29Miniaturized Ascorbic Acid Fuel Cells with an Ion-Exchange Films and Flexible Electrodes Made of Graphene-Coated Carbon Fiber Cloth Toshinari Doi, Kazuki Hoshi, Kazuo Muramatu, Hisato Sumi, Yasushiro Nishioka, Satomitsu Imai 30Oxygen Electrocatalysis on Cobalt-Based Layered Perovskite Oxychlorides in Alkaline Media Yuto Miyahara, Kohei Miyazaki, Tomokazu Fukutsuka, Takeshi Abe 31ORR and Oer Activity of the Carbon-Free Perovskite-Type Oxide Catalyst for Secondary Zn-Air Battery Tatsuya Takeguchi, Ryo Kobayashi, Koichi Ui 32Effects of High-Porosity Conductive Foams on the Electrochemical Performance of Electrochemical Flow Capacitors Bilen Akuzum, Lutfi Agartan, Deb Hudson, Yury Gogotsi, E. Caglan Kumbur 33All-in- One Graphene-Based Composite Fiber Supercapacitor Yangshuai Liu, Lathankan Rasenthiram, Lucas Lim, Wenwen Liu, Aiping Yu 34Synthesis of NiMoS4 and Its Application for High-Performance Supercapacitors Dongwei Du, Rong Lan, Shanwen Tao 35XPS Study of Rare Earth Redox Mediators for Solid-State Supercapacitors Chen Zhang, Yuchen Wang, Xiangyang Zhou, Azzam Mansour, Gordon Henry Waller, Curtis Martin 36One-Step Synthesis of Nanostructured Co3O4 Film on Nickel Foam As Electrode for Supercapacitor Application Yang Wang, Justin Roller, Radenka Maric 37Studies on the Electrochemical Properties of NiMn2O4 Nanoparticle for High Performance Energy Storage Supercapacitor Electrodes Apurba Ray 38Controlled Synthesis of Homogeneous MnCO3 Hollow Nanostructures for Supercapacitor Application Shakkthivel Piraman, Srinivassan Alagar, Rajesh Madhuvilakku 39Beyond the Hour and the Day: The Need and Technologies for Long-Duration Electrical Storage Joseph S. Manser, Lucas Spangher, Reid R. Heffner, Susan J. Babinec, Paul S. Albertus 40Optimal Control of Grid-Connected Li-Ion Batteries to Maximise Revenue and Minimise Degradation Jorn Maurits Reniers, Grietus Mulder, Sina Ober-Blöbaum, David Alastair Howey 41Durability and Reliability of EV Batteries Under Electric Utility Grid Operations Bidirectional Charging Impact Analysis Arnaud Devie, George Baure, Matthieu Dubarry 42(Battery Division Student Research Award Address) A Guide to Ethylene Carbonate- Free Electrolyte Making for Li-ion Cells Lin Ma, Remi Petibon, Jeff R Dahn 43(Battery Division Research Award Address) Developments of New Ionic Conductors and Their Application to All-Solid-State Batteries Ryoji Kanno 44(Battery Division Postdoctoral Associate Research Award Address, sponsored by MTI Corporation and the Jiang Family Foundation) The Solvation Structure of Active Cations in Next-Generation Battery Electrolytes Kimberly A See, Andrew A Gewirth 45Primary Batteries for Emerging Deep Space Exploration Missions Erik J. Brandon, Keith J. Billings, Bugga V. Ratnakumar, Keith B. Chin, John-Paul Jones, Simon C. Jones, Frederick C. Krause, Raymond A. Ontiveros, Jasmina Pasalic, Marshall C. Smart, William C. West 46Hybrid Thermo-Electrochemical System for Efficient and Low Cost High Pressure Hydrogen Compression Claudio Corgnale, Scott Greenway, Martin Sulic, Theodore Motyka, Bruce Hardy, Trent Molten, Daryl Ludlow, Jason Hattrick-Simpers, Travis Williams, Jochen Lauterbach, John W. Weidner 47(Battery Division Postdoctoral Associate Research Award Address, sponsored by MTI Corporation and the Jiang Family Foundation) K-Ion Battery for a Next-Generation Energy Storage System Haegyeom Kim, Jae Chul Kim, Dong-Hwa Seo,