Gwendolyn Anne Bailey Department of Chemistry Tel: (613) 562-5800 ext. 6067 University of Ottawa Email: [email protected] Ottawa, ON, Canada K1N 6N5 EDUCATION Ph.D. University of Ottawa (Ottawa, ON); 2012–present Specialization in Transition Metal Catalysis. Advisor: Prof. Deryn Fogg Thesis: Overcoming Catalyst Decomposition in Olefin Metathesis: Challenges, Insights, Opportunities B.Sc. University of British Columbia (Vancouver, BC); 2008–2012 Honours in Chemistry, with Distinction; Co-op. Advisor: Prof. Chris Orvig Thesis: A Novel Acyclic Chelator for Radiopharmaceutical Applications (Lefevre Medal & Prize in Honours Chemistry) Transfer College of the Rockies (Cranbrook, BC); 2006–2008 HONOURS AND DISTINCTIONS Scholarships 2014–17 NSERC Canada Graduate Scholarship, Doctorate (CGS-D) $35,000 p.a. 2013–17 Excellence Scholarship, University of Ottawa $7,500 p.a. 2013–14 NSERC Canada Graduate Scholarship, Master’s (CGS-M) $17,500 2013–14 Ontario Graduate Scholarship (declined) $15,000 2012–13 Admissions Scholarship, University of Ottawa $7,500 p.a. 2012 UBC Conference Travel Award $800 2011 NSERC USRA, Medicinal Inorganic Chemistry Group, UBC $6,000 2010 NSERC USRA (x2), Tekmira Pharmaceuticals Corp. $12,000 2008–12 Trussell Science and Technology Scholarship $5,000 p.a. 2008–10 Chancellor’s Entrance Scholarship, UBC $5,000 p.a. 2008 Irving K. Barber British Columbia Transfer Scholarship $5,000 2008 Irving K. Barber One World Scholarship $2,000 2008 Nancy Ryckman Scholarship, UBC $1,600 2008 Faculty Association Scholarship, College of the Rockies $2,000 2006–08 Scholastic Distinction Scholarship, College of the Rockies $3,500 p.a. 2005 Cranbrook Rotary Club Scholarship $1,000 Awards 2017 Featured as an “Outstanding Student” in the University of Ottawa Annual Research Report - 2017 Registration Award for selected lecture (1 of 3 graduate student lectures); Gordon Research $650 Conference on Inorganic Reaction Mechanisms 2017 Registration Award for selected lecture (1 of 8 graduate student lectures); Gordon Research $350 Seminar on Inorganic Reaction Mechanisms 2016 Teaching Assistant of the Year Award (CHM/BCH); Faculty of Science, uOttawa $250 2016 Teaching Assistant Award; Chemistry and Biomolecular Sciences, uOttawa $100 2016 Oral Presentation Award; 24th Canadian Symposium on Catalysis $100 2015 Oral Presentation Award (2nd prize); 48th Inorganic Discussion Weekend book 2014 Teaching Assistant of the Year Award; Faculty of Science, University of Ottawa $250 2014 Teaching Assistant Award; Department of Chemistry, University of Ottawa $100 2012 Oral Presentation (1st prize, organic division); Western Canadian Undergrad. Chemistry Conf. $100 2012 Lefevre Medal & Prize in Honours Chemistry, UBC (highest academic standing; research thesis) $300 2005 Governor General Academic Bronze Medal, Mount Baker Secondary School (highest standing) medal 2005 Apollo Ristorante Top Music Student Award, Mount Baker Secondary School $100 Total funds awarded (CAD): $246,950 Gwendolyn Anne Bailey PUBLICATIONS (F = full article; C = communication; R = review; †equal contributions) 13C. Bailey, G.A.; Fogg, D.E. Understanding Initiation and Recapture of Olefin Metathesis Catalysts: A Classification Scheme. (In preparation) 12R. Bailey, G.A.; Nascimento, D.L.; Fogg, D.E. Decomposition of Highly-Active Ruthenium Olefin Metathesis. Acc. Chem. Res. (Invited review; due Dec. 20) 11C. Bailey, G.A.; Lummiss, J. A.; Foscato, M.; Occhipinti, G.; McDonald, R.; Jensen, V.R.; Fogg, D.E. Decomposition of Metathesis Catalysts by Brønsted Base: Evidence for Metallacyclobutane Deprotonation as a Primary Deactivating Event. J. Am. Chem. Soc. 2017. (Accepted pending minor revision) 10C. Bailey, G.A.; Higman, C.S.; Day, C.S.; Fogg, D.E. Bimolecular Coupling as a Vector for Decomposition of Fast- Initiating Metathesis Catalysts. 2017. (Revised version submitted Sept. 30; J. Am. Chem. Soc.) 9C. Higman, C.S.; do Nascimento, D.L.; Ireland, B.J.; Audörsch, S.; Bailey, G.A.; McDonald, R.; Fogg, D.E. Chelate- Assisted Ring-Closing Metathesis: A Strategy for Accelerated Macrocyclization at Ambient Temperatures. J. Am. Chem. Soc. 2017. (Under revision) 8F. Santos, A.G.†; Bailey, G.A.†; dos Santos, E.N.; Fogg, D.E. Overcoming Catalyst Decomposition in Acrylate Metathesis: Polyphenol Resins as Enabling Agents for PCy3-Stabilized Metathesis Catalysts. ACS Catal. 2017, 7, 3181–3189. (ACS Editor’s Choice; also selected for ACS virtual issue on “Hot Materials in a Cool Country”) 7F. Bailey, G.A.; Fogg, D.E. Confronting Neutrality: Maximizing Success in the Analysis of Transition-Metal Catalysts by MALDI Mass Spectrometry. ACS Catal. 2016, 6, 4962–4971. 6C. Bailey, G.A.; Fogg, D.E. Acrylate Metathesis via the Second-Generation Grubbs Catalyst: Unexpected Pathways Enabled via a PCy3-Generated Enolate. J. Am. Chem. Soc. 2015, 107, 7318–7321. 5F. Rodríguez-Rodríguez, C.; Telpoukhovskaia, M.A.; Alí-Torres, J.; Rodríguez-Santiago, L.; Manso, Y.; Bailey, G.A.; Hidalgo, J.; Sodupe, M.; Orvig, C. Thioflavin-Based Molecular Probes for Application in Alzheimer’s Disease: From in Silico to in Vitro models. Metallomics 2015, 78–87. 4F. Telpoukhovskaia, M. A.; Rodríguez-Rodríguez, C.; Cawthray, J. F.; Scott, L. E.; Page, B. D. G.; Alí-Torres, J.; Sodupe, M.; Bailey, G.A.; Patrick, B.O.; Orvig, C. 3-Hydroxy-4-pyridinone Derivatives as Metal Ion and Amyloid Binding Agents. Metallomics 2014, 6, 249–262. 3F. Bates, J.M.; Lummiss, J.A..; Bailey, G.A.; Fogg, D.E. The Boomerang Mechanism in Olefin Metathesis Reactions Promoted by the Second-Generation Hoveyda Catalyst. ACS Catal. 2014, 4, 2387–2394. 2F. Bailey, G.A.†; Price, E.W.†; Zeglis, B.M.; Ferreira, C.L.; Boros, E.; Lacasse, M.J.; Patrick, B.O.; Lewis, J.S.; Adam, M.J.; Orvig, C. A Versatile Multifunctional Chelator for 67Ga, 64Cu, 111In, and 177Lu. Inorg. Chem. 2012, 51, 12575–12589. 1F. Price, E.W.; Cawthray, J.C.; Bailey, G.A.; Ferreira, C.L; Boros, E.; Adam, M.J.; Orvig, C. H4octapa: An Acyclic Chelator for 111In Radiopharmaceuticals. J. Am. Chem. Soc. 2012, 134, 8670–8683. SCHOLARLY PRESENTATIONS (O = oral; P = poster; *indicates presenter) O18. Bailey, G.A.*; Higman, C.S.; Fogg, D.E. Catalyst Decomposition in Ru-Catalyzed Olefin Metathesis: Insights Originating in a Cyclometallated Ru Dimer. Student symposium for 2017 Leibniz prize winner, Prof. Holger Braunschweig, Ottawa: May 2, 2017. (Institutional) O17. Bailey, G.A.*; Higman, C.S.; Fogg, D.E. Catalyst Decomposition in Ru-Catalyzed Olefin Metathesis. Poster talk presented at the Gordon Research Conference in Inorganic Reaction Mechanisms, Galveston, TX: Mar 5– 10, 2017. (International; Short talk selected from poster abstracts) P16. Bailey, G.A.*; Higman, C.S.; Fogg, D.E. Metallacyclobutane Deprotonation as a Primary Event in Decomposition of Olefin Metathesis Catalysts. Gordon Research Conference in Inorganic Reaction Mechanisms, Galveston, TX: Mar 5–10, 2017. (International) O15. Bailey, G.A.*; Higman, C.S.; Fogg, D.E. Understanding Catalyst Decomposition in Olefin Metathesis. Gordon Research Seminar in Inorganic Reaction Mechanisms, Galveston, TX: Mar 4–5, 2017. (International; Selected) O14. Bailey, G.A.*; Higman, C.S.; Fogg, D.E. Metathesis of Directly Functionalized Olefins: Probing Decomposition of Electron-Deficient Intermediates. Centre for Catalysis Research & Innovation lunchtime seminars, Ottawa, ON: Dec 8, 2016. (Institutional) P13. Bailey, G.A.*; Fogg, D.E. Analyzing Transition-Metal Complexes by MALDI MS: Maximizing Success. Gordon Research Conference in Inorganic Chemistry, Biddeford, ME: June 19–24, 2016. (International) Gwendolyn Anne Bailey O12. Bailey, G.A.*; Fogg, D.E. Frontiers in Metathesis: Electron-Deficient Olefins. Ottawa-Carleton Chemistry Institute Meeting, Ottawa, ON: June 3, 2016. (Institutional) O11. Bailey, G.A.*; Fogg, D.E. Frontiers in Metathesis: Electron-Deficient Olefins. 24th Canadian Symposium on Catalysis, Ottawa, ON: May 8–11, 2016. (National; Oral Presentation Award) P10. Bailey, G.A.*; Fogg, D.E. Metathesis of Electron-Deficient Olefins: Catalyst Decomposition by Phosphines. 48th Inorganic Discussion Weekend, Kingston, ON: Nov 6–8, 2015. (Regional; Oral Presentation Award) P9. Bailey, G.A.*; Fogg, D.E. Acrylate Metathesis: Origin of the Superior Performance of Phosphine-Free Ru Catalysts. 21st International Symposium on Olefin Metathesis, Graz, Austria: July 11–16, 2015. (International) P8. Bailey, G.A.*; Fogg, D.E. Deactivation of the Hoveyda Catalyst: Impact of Ethylene. 98th Canadian Chemistry Conference & Exhibition, Ottawa, ON: June 13-17, 2015. (National) P7. Bailey, G.A.*; Fogg, D.E. Acrylate-Induced Decomposition in Olefin Metathesis. 47th Inorganic Discussion Weekend, Montreal, QC: Nov 16–18, 2014. (Regional) P6. Bailey, G.A.*; Fogg, D.E. Organometallic MALDI Mass Spectrometry: Fragmentation and Survival. 19th International Symposium on Homogeneous Catalysis, Ottawa, ON: July 6–11, 2014. (International) P5. Bailey, G.A.*; Fogg, D.E. Understanding Catalyst Decomposition in Ru-Catalyzed Cross-Metathesis of Acrylates. 96th Canadian Chemistry Conference & Exhibition, Quebec City, QC: May 26–30, 2013. (National) O4. Bailey, G.A.*; Price, E.W.; Zeglis, B.M.; Ferreira, C.L.; Boros, E.; Lacasse, M.J.; Patrick, B.O.; Lewis, J.S.; Adam, M. J.; Orvig, C. A Novel Acyclic Multifunctional Chelator for 64Cu Radiopharmaceuticals. Western Canadian Undergrad. Chemistry Conf. Edmonton, AB; May 3–5, 2012. (Regional; Oral Presentation Award) O3. Bailey, G.A.*; Price, E.W.; Orvig, C. A Novel Acyclic Multifunctional Chelator for 64Cu Radiopharmaceuticals.