CONTENTS ACKNOWLEDGMENTS ........................................................................................................ viii ACRONYMS USED IN THIS DOCUMENT .......................................................................... ix EXECUTIVE SUMMARY ...................................................................................................... 1 1 INTRODUCTION .............................................................................................................. 3 1.1 Purpose ...................................................................................................................... 3 1.2 Overview of Study .................................................................................................... 3 2 GEOTHERMAL ELECTRICITY GENERATION ........................................................... 5 2.1 Conventional Hydrothermal Flash System ............................................................... 5 2.2 Conventional Hydrothermal Binary System ............................................................. 5 2.3 Enhanced Geothermal System .................................................................................. 5 2.4 Water and Geothermal Electricity Generation .......................................................... 6 3 APPROACH AND METHODS ......................................................................................... 7 3.1 Life Cycle Analysis ................................................................................................... 7 3.2 Scenarios ................................................................................................................... 7 3.3 Well Field Development ........................................................................................... 8 3.3.1 Well Construction ......................................................................................... 9 3.3.2 Hydraulic Stimulation of the Resource ......................................................... 10 3.4 Pipeline and Plant Construction ................................................................................ 11 3.4.1 Pipeline Supports ........................................................................................... 11 3.4.2 Power Plant: Construction ............................................................................. 12 3.5 Operations ................................................................................................................. 13 3.5.1 Makeup Water ............................................................................................... 14 3.5.2 Cooling Water ............................................................................................... 14 3.6 Water Quality ............................................................................................................ 16 4 ANALYSIS AND RESULTS OF THE LIFE CYCLE ...................................................... 19 4.1 Construction and Stimulation .................................................................................... 19 4.2 Plant Operations and the Life Cycle ......................................................................... 21 4.3 Comparison with other Power Plant Types ............................................................... 25 5 ANALYSIS AND INTERPRETATION OF WATER QUALITY .................................... 29 5.1 Geothermal Brine Characteristics ............................................................................. 29 iii CONTENTS (CONT.) 5.2 Water pollution potential ........................................................................................... 31 5.3 Noncondensable Gases .............................................................................................. 36 5.4 Scale Formation and Corrosion ................................................................................. 40 5.5 Mineral Extraction ..................................................................................................... 43 6 FINDINGS AND CONCLUSIONS ................................................................................... 47 7 REFERENCES ................................................................................................................... 49 APPENDIX A – ARGONNE GEOTHERMAL GEOCHEMICAL DATABASE .................. 55 APPENDIX B – DETAILED LIFE CYCLE INVENTORY DATA ....................................... 57 APPENDIX C – ADDITIONAL GEOCHEMICAL COMPOSITION DATA ........................ 61 APPENDIX D – ADDITIONAL GAS COMPOSITION DATA ............................................ 67 FIGURES 3-1 System Boundary for Well Field ....................................................................................... 9 3-2 Percent of U.S. Geothermal Power Production Capacity in 2007 by Technology ........... 15 3-3 Percent of Total U.S. Geothermal Power Generating Units by Technology .................... 15 4-1 Volume of Water Consumed for Construction of Geothermal Power Plants according to Scenarios and assuming Average Depth for Wells ........................................................... 20 4-2 Water Consumption in Millions of Gallons per Megawatt as a Function of Well Depth for the Construction Stage of the EGS Scenarios ................................................................... 21 4-3 Water Volume in Millions of Gallons per Megawatt Consumed for the EGS Scenarios According to Depth ........................................................................................................... 22 4-4 Contribution to Total Water Requirements by Process ..................................................... 22 4-5 Life Cycle Volume of Water in Millions of Gallons for Geothermal Power Plant Scenarios ....................................................................................................... 23 4-6 Contribution of Water Within the Power Plant Life Cycle to Total Water Use ............... 23 4-7 Water Consumption for Electric Power Generation Through the Life Cycle in Gallons Per Kilowatt Hour of Lifetime Energy Output .................................................... 28 5-1 Distribution of pH Measurements for U.S. Geothermal Sources with Temperature Greater than 90°C ........................................................................................ 30 iv FIGURES (CONT.) 5-2 Distribution of TDS Measurements for U.S. Geothermal Sources with Temperature Greater than 90°C ........................................................................................ 30 5-3 Geofluid Composition Box Plots, Major Constituents ...................................................... 32 5-4 Geofluid Composition Box Plots, Minor Constituents ..................................................... 33 5-5 Examples of Specific Geofluid Composition .................................................................... 34 5-6 Histogram of Carbon Dioxide Concentrations in NCG Stream ........................................ 37 5-7 Histogram of Nitrogen Concentrations in NCG Stream ................................................... 38 5-8 Histogram of Combined Nitrogen and Carbon Dioxide Concentrations in NCG Stream .................................................................................................................. 38 5-9 Examples of Noncondensible Gas Composition ............................................................... 39 C-1 Geofluid Composition, Sample from Mesa 6-2 Well in CA at 187°C .............................. 63 C-2 Geofluid Composition, Sample from Mesa 31-1 Well in CA at 157°C ............................ 63 C-3 Geofluid Composition, Sample from Well 73b-7 in NV at 174°C ................................... 64 C-4 Geofluid Composition, Sample from Well 37-33 in NV at 165°C ................................... 64 C-5 Geofluid Composition, Sample from the 101 Separator in NV at 160°C ......................... 65 C-6 Geofluid Composition, Sample from Magma Power Co, Unspecified well in CA at 94°C ........................................................................................ 65 C-7 Geofluid Composition, Sample from Breitenbush Hot Springs, in OR at 92°C ............... 66 C-8 Geofluid Composition, Sample from an Unnamed Spring in CA at 90°C........................ 66 D-1 NCG Composition, Sample from Steamboat Hills in NV at 154°C ................................. 67 D-2 NCG Composition, Sample from Crump Geyser in OR at 99°C ...................................... 67 D-3 NCG Composition, Sample from Leach Hot Spring in NV at 97°C ................................. 68 D-4 NCG Composition, Sample from Sapphire Geyser in WY at 95°C .................................. 68 v FIGURES (CONT.) D-5 NCG Composition, Sample from Casa Diablo in CA at 93°C .......................................... 69 D-6 NCG Composition, Sample from Amadee Hot Springs in CA at 92°C ............................ 69 D-7 NCG Composition, Sample from Shoshone Basin in WY at 92°C................................... 70 D-8 NCG Composition, Sample from Thermo Hot Springs in UT at 89°C ............................. 70 D-9 NCG Composition, Sample from Worswick Hot Springs in ID at 86°C .......................... 71 D-10 NCG Composition, Sample from Port Moller Hot Springs in AK at 71°C ..................... 71 D-11 NCG Composition, Sample from Travertine Hot Springs in CA at 69°C ....................... 72 TABLES 3-1 ParameterValues for Four Geothermal Power Plant Scenarios ......................................... 8 3-2 Water Volume Requirements by Step for Stimulation Process of One