Copper Gluconate Cambridge Commodities Chemwatch Hazard Alert Code: 3 Part Number: P0343 Issue Date: 04/06/2021 Version No: 3.16.23.11 Print Date: 24/09/2021 Safety data sheet according to REACH Regulation (EC) No 1907/2006, as amended by UK REACH Regulations SI 2019/758 S.REACH.GB.EN SECTION 1 Identification of the substance / mixture and of the company / undertaking 1.1. Product Identifier Product name Copper Gluconate Chemical Name copper(II) gluconate Synonyms Not Available Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains copper(II) gluconate) Chemical formula Not Applicable Other means of P0343 identification 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use according to manufacturer's directions. Uses advised against Not Applicable 1.3. Details of the supplier of the safety data sheet Registered company name Cambridge Commodities Address Lancaster Way Business Park, Ely, Cambridgeshire Cambridgeshire CB6 3NX United Kingdom Telephone +44 1353 667258 Fax Not Available Website Not Available Email [email protected] 1.4. Emergency telephone number Association / Organisation Not Available Emergency telephone Not Available numbers Other emergency Not Available telephone numbers Product code: P0343 Version No: 3.16.23.2 Page 1 of 21 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 9-642049 +44 (0) 1353 667258 Issue Date: 04/06/2021 [email protected] Print Date: 24/09/2021 www.c-c-l.com SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classified according to H411 - Hazardous to the Aquatic Environment Long-Term Hazard Category 2, H373 - Specific Target Organ Toxicity - Repeated GB-CLP Regulation, UK SI Exposure Category 2, H400 - Hazardous to the Aquatic Environment Acute Hazard Category 1, H302 - Acute Toxicity (Oral) 2019/720 and UK SI Category 4, H317 - Sensitisation (Skin) Category 1 2020/1567 [1] Legend: 1. Classified by Chemwatch; 2. Classification drawn from GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567 2.2. Label elements Hazard pictogram(s) Signal word Warning Hazard statement(s) H411 Toxic to aquatic life with long lasting effects. H373 May cause damage to organs through prolonged or repeated exposure. (Vascular system) (Oral) H400 Very toxic to aquatic life. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention P260 Do not breathe dust/fume. P280 Wear protective gloves and protective clothing. P264 Wash all exposed external body areas thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P302+P352 IF ON SKIN: Wash with plenty of water. P314 Get medical advice/attention if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. Product code: P0343 Version No: 3.16.23.2 Page 2 of 21 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 9-642049 +44 (0) 1353 667258 Issue Date: 04/06/2021 [email protected] Print Date: 24/09/2021 www.c-c-l.com P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell. P330 Rinse mouth. Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. 2.3. Other hazards Inhalation may produce health damage*. May produce discomfort of the eyes and skin*. REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 Composition / information on ingredients 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1.CAS No 2.EC No Classified according to GB-CLP Regulation, UK SI Nanoform Particle %[weight] Name 3.Index No 2019/720 and UK SI 2020/1567 Characteristics 4.REACH No 1.527-09-3 2.208-408-2 copper(II) 100 Not Applicable Not Available 3.Not Available gluconate 4.Not Available Legend: 1. Classified by Chemwatch; 2. Classification drawn from GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties SECTION 4 First aid measures 4.1. Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally Eye Contact lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Product code: P0343 Version No: 3.16.23.2 Page 3 of 21 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 9-642049 +44 (0) 1353 667258 Issue Date: 04/06/2021 [email protected] Print Date: 24/09/2021 www.c-c-l.com IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. For advice, contact a Poisons Information Centre or a doctor. Urgent hospital treatment is likely to be needed. In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the SDS should be provided. Further action will be the responsibility of the medical specialist. If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the Ingestion SDS. Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. NOTE: Wear a protective glove when inducing vomiting by mechanical means. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed for copper intoxication: Unless extensive vomiting has occurred empty the stomach by lavage with water, milk, sodium bicarbonate solution or a 0.1% solution of potassium ferrocyanide (the resulting copper ferrocyanide is insoluble). Administer egg white and other demulcents. Maintain electrolyte and fluid balances. Morphine or meperidine (Demerol) may be necessary for control of pain. If symptoms persist or intensify (especially circulatory collapse or cerebral disturbances, try BAL intramuscularly or penicillamine in accordance with the supplier's recommendations. Treat shock vigorously with blood transfusions and perhaps vasopressor amines. If intravascular haemolysis becomes evident protect the kidneys by maintaining a diuresis with mannitol and perhaps by alkalinising the urine with sodium bicarbonate. It is unlikely that methylene blue would be effective against the occassional methaemoglobinemia and it might exacerbate the subsequent haemolytic episode. Institute measures for impending renal and hepatic failure. [GOSSELIN, SMITH & HODGE: Commercial Toxicology of Commercial Products] A role for activated charcoals for emesis is, as yet, unproven. In severe poisoning CaNa2EDTA has been proposed. [ELLENHORN & BARCELOUX: Medical Toxicology] SECTION 5 Firefighting measures 5.1. Extinguishing media Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. 5.2. Special hazards arising from the substrate or mixture Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may Fire Incompatibility Product code: P0343 Version No: 3.16.23.2 Page 4 of 21 S.REACH.GB.EN Lancaster Way Business Park Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) Ely, Cambridgeshire, CB6 3NX, UK. Chemwatch: 9-642049 +44 (0) 1353 667258 Issue Date: 04/06/2021 [email protected] Print Date: 24/09/2021 www.c-c-l.com result 5.3. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area. Fire Fighting DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible (circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause fires and / or dust explosions. Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions).