Chapter 12 The Oldest Terrestrial Mineral Record: Thirty Years of Research on Hadean Zircon From Jack Hills, Western Australia Aaron J. Cavosie1, John W. Valley2 and Simon A. Wilde3 1Curtin University, Perth, WA, Australia; 2University of WisconsineMadison, Madison, WI, United States; 3Curtin University of Technology, Perth, WA, Australia Chapter Outline 1. Introduction 255 3.4.1 Lithium 266 2. Jack Hills Metasedimentary Rocks 256 3.4.2 Ti Thermometry 266 2.1 Age of Deposition 257 3.4.3 Rare Earth Elements, Yttrium and Phosphorous 266 2.2 Metamorphism 258 3.4.4 Other Trace Elements (Al, Sc, Sm/Nd, Xe) 267 2.3 Geology of Adjacent Rocks 258 3.5 Hafnium Isotopic Compositions 267 3. Studies of Jack Hills Zircon 259 3.6 Mineral Inclusion Studies 268 3.1 Images of Jack Hills Zircon 259 4. Early Earth Processes Recorded by Jack Hills Zircon 270 3.2 Age of the Hadean Zircon Population 259 4.1 Derivation of Jack Hills Zircon From Early Mafic 3.2.1 The UePb Story 259 Crust (εHf) 270 3.2.2 U Abundance, Radiation Damage, and Pb Loss 261 4.2 Existence of >4300 Ma Granitoid 270 3.2.3 The Oldest Grains in the Jack Hills 262 4.3 Significance of Surface Alteration on the Early Earth 271 3.2.4 Distribution of Hadean Grains 264 4.4 Impact Events Recorded in Jack Hills Zircon? 271 3.3 Oxygen Isotopes 264 Acknowledgments 273 3.4 Trace Elements 266 References 273 1. INTRODUCTION Little is known of the early Earth because of the absence of a rock record for the first 500 million years after accretion. Earth’s earliest history is assigned to the Hadean eon, which began at the onset of accretion at c.4560 Ma, when meteorite impacts and magma oceans maintained extreme surface temperatures at or above the temperatures where surface water vaporized to a dense steam atmosphere. The existence of buoyant crust as early as 4400 Ma is indicated by preservation of magmatic zircon. The Earth eventually cooled, quenching the high surface temperatures and allowing H2O to condense as oceans. The transition to a more familiar and clement Earth was a global process and may be viewed to represent the end of Hadean conditions (Valley, 2005, 2006). Establishing the timing of the HadeaneArchean transition is challenging based on the fragmentary rock record, yet it is critically important for both defining the early Earth geological timescale and also constraining when Earth became habitable (Valley, 2008; Cavosie, 2014). The present definition of the HadeaneArchean transition at 4000 Ma (e.g., Cohen et al., 2013) is near the limit of the oldest recognized rock record (Reimink et al., 2016), including c.4030e3800 Ma orthogneisses and metasedimentary rocks in the Northwest Territory of Canada (e.g., Bowring and Williams, 1999; Chapter 15), similar-aged supracrustal rocks in the Nuvvuagittuq Greenstone Belt (Cates and Mojzsis, 2007) and Saglek Block (Komiya et al., 2015) in northeast Canada, and c.3900e3800 Ma orthogneisses in the Isua supracrustal belt of southwest Greenland (e.g., Nutman et al., 2001; Chapter 17). Older Hadean ages have been reported for Earth’s Oldest Rocks. https://doi.org/10.1016/B978-0-444-63901-1.00012-5 255 Copyright © 2019 Elsevier B.V. All rights reserved. 256 SECTION | III The Most Ancient Remnants Shark Narryer Bay Terrane 26° 00'S Jack Hills Mt. Narryer Eastern Goldfields Maynard Superterrane Hills Youanmi Terrane 30° 00'S Western N Australia Perth South West Terrane 34° 00'S 200 km 116° 00'E 120° 00'E 124° 00'E FIGURE 12.1 Map of the Yilgarn Craton in Western Australia, showing Hadean zircon localities (after Wilde et al., 1996; Wyche et al., 2012). Filled circles are known locations of >4000 Ma detrital zircon and open circles are locations of xenocrysts with similar ages (see text for references). mafic volcanic rocks from Nuvvuagittuq (e.g., O’Neil et al., 2016; Chapter 16), however, the interpretation of these ages as dating the timing of crystallization of these rocks remains a topic of debate. The only identified materials on the Earth with unequivocal UePb ages extending into the Hadean are ancient >4000 Ma zircon grains that are dominantly found as detrital grains in Archean rocks in the ancient crustal nuclei of Western Australia and are only rarely found elsewhere. In Western Australia, variably metamorphosed metasedimentary rocks from several localities in the Yilgarn Craton have yielded zircon older than 4000 Ma. These include sites at Mount Narryer and the Jack Hills (Froude et al., 1983; Compston and Pidgeon, 1986; Cavosie et al., 2004; Wang and Wilde, 2018) and Maynard Hills and Mount Alfred (Wyche et al., 2004; Thern and Nelson, 2012; Chapter 13) (Fig. 12.1). Rare >4000 Ma grains have also been reported as xenocrysts in younger Archean granitoids close to Mount Narryer (Nelson et al., 2000). Metasedimentary rocks in the Jack Hills have received the most attention of the above localities, primarily because of both the consistently high concentration (up to 12%, Compston and Pidgeon, 1986) of Hadean zircon grains and the presence of the oldest known detrital grains. Given the unique window these grains offer on early Earth processes, this review focuses primarily on published reports that describe the population of Hadean zircon grains from the Jack Hills. 2. JACK HILLS METASEDIMENTARY ROCKS The Jack Hills, located in the Narryer Terrane of the Yilgarn Craton in Western Australia (Fig. 12.1), comprise a w90 km- long northeast-trending belt of folded and weakly metamorphosed supracrustal rocks that are composed primarily of siliciclastic and chemical metasedimentary rocks, along with minor felsic and mafic volcanic rocks and also ultramafic rocks (Fig. 12.2; Wilde and Spaggiari, 2007; Chapter 18). Bedding strikes east-northeast and has a subvertical dip. The siliciclastic portion of the belt has been interpreted as alluvial fan-delta deposits, based on repeating fining upward se- quences consisting of basal conglomerate, medium-grained sandstone, and fine-grained sandstone (Wilde and Pidgeon, 1990). Located on Eranondoo Hill in the central part of the belt is now a famous site referred to as “W74” (Fig. 12.3), the number originally assigned to a sample collected from conglomerate at this spot by the Curtin University group. The W74 site contains a well-exposed, 2-m thick quartz pebble metaconglomerate. The previously undescribed unit was originally sampled by S. Wilde, R. Pidgeon, and J. Baxter in 1984 during mapping for an Australian Research Council project and was later described by Compston and Pidgeon (1986), who reported the first UePb ages for detrital zircon grains from the Jack Hills, including one grain with a spot as old as 4276 Æ 6 Ma. Aliquots of zircon from the original W74 zircon concentrate, as well as additional samples from the same outcrop, have subsequently been the subject of many studies. The Oldest Terrestrial Mineral Record Chapter | 12 257 Mt. Taylor Muscovite granite Monzogranites, ca. 2650 Ma Banded iron formation Mt. Hale 26° S Ultramafic rocks N Siliciclastic rocks Granitoids, 3730-3300 Ma Cargarah sz fault/ shear zone 10 km z rah s arga 01JH36 C Yarameedie Hill W74 site (Eranondoo Hill) 26 15' Noonie Hill 117° E 117 15' FIGURE 12.2 Geologic map of the Jack Hills metasedimentary belt (after Cavosie et al., 2004). Two localities where Hadean zircon grains with concordant U-Pb ages >4350 Ma have been reported, W74 and 01JH36, are shown. The trace of the Cargarah shear zone (sz) is from Spaggiari (2007). FIGURE 12.3 Photo of the authors at the W74 site in the Jack Hills in July 2001. Shown are J.W. Valley (left), A.J. Cavosie (middle), and S.A. Wilde (right). Photo by D. Valley. 2.1 Age of Deposition The deposition age of metasedimentary rocks in Jack Hills is somewhat controversial, as it appears to vary with location. The maximum age of the W74 metaconglomerate was originally cited as c.3100 Ma based on the youngest detrital zircon age (Compston and Pidgeon, 1986). However, numerous studies have produced concordant zircon UePb ages that are younger, including grains with ages of 3046 Æ 9Ma(Nelson, 2000) and 3047 Æ 21 Ma (Crowley et al., 2005). Thus, it 258 SECTION | III The Most Ancient Remnants appears that the maximum age of deposition of the W74 metaconglomerate may be c.3050 Ma. An Archean deposition age is consistent with the observation that metamorphic monazite with an age of 2653 Æ 5 Ma was identified in the matrix of the conglomerate at the W74 site (Rasmussen et al., 2010). Furthermore, some of the metasedimentary rocks are intruded by granitoids that yield zircon UePb ages of c.2650 Ma (Pidgeon and Wilde, 1998; Spaggiari et al., 2007). Studies of the distribution of detrital zircon ages away from the W74 site show that not all of the Jack Hills meta- sedimentary rocks were deposited in the Archean. Detrital grains with Proterozoic ages have been reported, including a 1576 Æ 22 Ma grain from a 60-m section that contains the W74 site (Fig. 12.2) and <3000 Ma grains from a 20-m conglomerate-bearing section 1 km east of W74 (Cavosie et al., 2004). All of the rocks sampled along these two sec- tions are dominated by chemically mature clastic metasedimentary rocks (>95 wt.% SiO2) and include metaconglomerate, quartzite, and metasandstone. The presence of detrital Proterozoic zircon grains in these sections and elsewhere in the Jack Hills metasedimentary sequence has been confirmed by other studies. Dunn et al. (2005) reported c.1800 Ma detrital grains, and Grange et al. (2010) reported concordant detrital grains from a site w1 km west of W74 with ages as young as 1220 Ma.