SDS - POLYVINYL CHLORIDE (PVC) SAFETY DATA SHEET 1- IDENTIFICATION OF PRODUCT AND SUPPLIER Product identifier: Polyvinyl Chloride (PVC) Resin: S58, S63, S65, S66, S71, E67, E68, E70, E74,E76 Other means of identification: PVC; polyvinyl chloride; Resin Homopolymer Recommended use of the chemical and restrictions on Manufacture of plastics products use: Supplier’s details: BRASIL Address: Avenida Presidente Juscelino Kubitschek, 1.327 – 22º andar São Paulo/SP – CEP 04543-011 SALES OFFICE Tel.: +55 11 3704 4200 UNIPAR E-mail: [email protected] ARGENTINA Address: Juana Manso 555 – 7º “D” – C.A.B.A – Argentina CP:C1107CBK Phone number.: + 54 11 5283 9300 SANTO ANDRÉ – Brasil Unipar Indupa do Brasil S.A. Address: E.F.S.J Km38 Vila Elclor - Santo André – SP – Brasil CEP 09154-900 Emergency: +55 11 4439 7018 (24 hours) INDUSTRIAL UNITS BAHÍA BLANCA – Argentina UNIPAR Unipar Indupa S.A.I.C Address: Av. del Desarrollo Pte. Frondizi 2450 Ing. White – Buenos Aires CP:B8101XAD Phone number: +54 9 291 459 3000 Emergency: +54 9 291 459 3000 +54 9 291 15 412 2266 Guardia Seguridad +54 9 11 15 5514 9020 Guardia Logística E-mail: [email protected] Others emergency contacts Pro-Química Abiquim 0800 11 8270 Revisão: 00 Página 1 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) 2- HAZARD IDENTIFICATION Classification of the Not classified as a dangerous product substance or mixture: Classification system -Globally Harmonized System of Classification and Labelling of Chemicals (GHS), United adopted: Nations. -ABNT NBR 14725-2 GHS label elements, including precautionary statements Pictograms: - Not labeled as a dangerous product Signal word: - Not labeled as a dangerous product Hazard statement(s): - Not labeled as a dangerous product Precautionary - Not labeled as a dangerous product statement(s): Other hazards which do The product does not have other hazards. not result in classification: 3- COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCES Common chemical name: PVC Common name(s), synonym(s) of the polyvinyl chloride; Resin Homopolymer substance: CAS number: 9002-86-2 Concentration (%) >= 99 Impurities and stabilizing additives which are themselves classified and The product does not have impurities which contribute to hazards. which contribute to the classification of the substance: 4- FIRST-AID MEASURES Routes of exposure Inhalation: Remove victim from de dusty environment to fresh air. Let him blow his nose - In case of skin contact, wash thoroughly with water. Skin: - In case of contact with the clothes, change them. Revisão: 00 Página 2 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) - Rinse cautiously with water for 20 minutes. Eye: - Remove contact lenses, if present and easy to do. If the victim is conscious: - Consult the doctor. Ingestion: If the victim is unconscious: - Never give anything by mouth to an unconscious person. Call a POISON CENTER or doctor/physician If you feel unwell. Take this SDS. In case of eye contact Effects: Mechanical irritation due to product particles. In case of ingestion Most important Effects: No information available. symptoms/effects, acute In case of skin contact and delayed: Effects: none In case of inhalation Effects: Mechanical irritation due to product particles. Indication of immediate medical attention and None special treatment needed, if necessary: 5- FIRE-FIGHTING MEASURES Appropriate: Adapt fire-fighting measures to local conditions and the surrounding Suitable extinguishing environment. media: Not recommended: None - The product resists of combustion and does not promote the spread of flames. Specific hazards arising - Limited risk of dust explosion when mixed with air, but only under particular from the chemical: conditions (see section 9). - Hazardous decomposition products formed during fires: Hydrochloric acid gas (HCl). Self-contained breathing apparatus (SCBA) operated in positive pressure mode and complete protective clothing. Additional information Special protective actions for fire-fighters: - Avoid dust formation. - After the fire, quickly clean the surfaces exposed to the fumes, to limit damage to the equipment. Revisão: 00 Página 3 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) 6- ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures For non-emergency Don't expose yourself to the substance without using personal protective equipment personnel: recommended in section 7and 8. Sweep the product to avoid slipping For emergency responders: Do not allow dust to accumulate on machinery and equipment to prevent overheating. Environmental Avoid spilled material reaches waterways and sewers. precautions: Should not be thrown into the environment Methods and materials for Collect waste without raising dust. containment and cleaning Store in properly labeled containers. up: Treat recovered material as described in the "Disposal Considerations" section. 7- HANDLING AND STORAGE Precautions for safe handling Safe handling of the Use electrically conductive materials for piping circuits and equipment. substance or mixture: Take measures to prevent static electricity. Handle in accordance with good industrial hygiene and safety practices. General hygiene: Avoid dust generation Do not eat, drink or smoke while using. Conditions for safe storage, including any incompatibilities Store in a well-ventilated place. Store in a dry place. To maintain the quality of the product, do not store in the heat or in direct sunlight. To avoid thermal decomposition, do not overheat. Adequate conditions: Keep away from heat / spark / open flame / hot surfaces. Make sure the equipment is electrically grounded before starting transfer activities. Avoid the formation of dust. Store at a temperature not exceeding 40 ° C other specifications Contact the supplier 8- EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Occupational exposure limit: Chemical our common name Reference Value Revisão: 00 Página 4 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) 1 mg/m3 PVC - polyvinyl chloride TLV – TWA (ACGIH 2018) Form of exposure: breathable fraction Biological limit: Not established. Appropriate engineering Refer to sections 7 and 8 for protective measures. controls: - Apply technical measures to meet occupational exposure limits. Individual protection measures, such as personal protective equipment (PPE) Eye/face protection: Dust Protection Safety Glasses - For the protection of hands, use gloves compatible with the mechanical risks of the Skin protection: operation. - Wear a work uniform for skin protection. The respirator must be used during exposure to dust. - Semi mask with a P2 particle filter (European Standard EN 143) or filter face mask PFF2 (N95) or higher. - In case of decomposition (see section 10), face mask with combined type B-P2 Respiratory protection: cartridge. - Self-contained breathing apparatus in a confined space / if there is insufficient oxygen / in case of uncontrolled emissions. - Use only respiratory protection that complies with international standards. Thermal hazards: It is not necessary to use specific PPE, since the product does not present thermal hazards. Hygiene measures - Handle in accordance with industrial hygiene and safety good practices. - Do not eat, drink or smoke during use. - Avoid dust formation Environmental risk controls Waters wash water dispose in according to local and national regulations 9- PHYSICAL AND CHEMICAL PROPERTIES Physical state: Shape: powder Physical state: solid Colour: white Odour: odorless pH: Not applied Melting point/freezing Not applicable, Transition glass temperature point: Boiling point or initial boiling point and boiling Not applicable (solid) range: Revisão: 00 Página 5 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) Flash point: Not available (Lack of information). Evaporation rate: Not applicable Flammability: The product resists combustion and does not promote the spread of flames., Combustion class: BZ1 (does not ignite). Lower and upper explosion Not available (Lack of information). limit /flammability limit: Vapour pressure: Not applicable Relative vapour density: Not applicable Auto-ignition temperature: Not available (Lack of information). Density and/or relative Apparent density: 300 to 650 Kg/m³. density: Relative density: 1.38 Solubility: In water: insoluble Solubility in other solvents: Tetrahydrofuric - Soluble Ketones: Soluble Partition coefficient n- Not applicable octanol/water (log value): Decomposition Not available (Lack of information). temperature: Auto-ignition temperature: 650 ° C cloudy 450 ° C layer Decomposition > or = 120 ° C Long-term exposure (approx. 3 hours). temperature: > 250 ° C short exposure viscosity: Dynamic viscosity: Not applicable Explosion hazard Data not available Oxidizing properties Not applicable Minimum ignition energy > 2.5J Other information: St1 10- STABILITY AND REACTIVITY Reactivity: Data not available Chemical stability: Stable product under recommended storage conditions. Possibility of hazardous None reactions: Revisão: 00 Página 6 de 9 Data: 18/02/2021 SDS - POLYVINYL CHLORIDE (PVC) Keep away from heat. Conditions to avoid: Keep away from direct sunlight. Exposure to moisture. Incompatible material: Data not available Hazardous Gaseous hydrochloric acid (HCl). decomposition products: Carbon monoxide 11- TOXICOLOGICAL INFORMATION Acute toxicity: Not applicable Skin corrosion/irritation: Not applicable Serious eye Not applicable damage/irritation: Respiratory or skin Not applicable sensitization: Germ