Volume: 3 ISMEC GROUP SERIES Year: 201 3 http:// mat520.unime.it/ismecacta/ Symposium Edition: XXI V ISSN : 2239 -2459 *Acta of the International Simposia on Metal Complex *Acta of the International Simposia on Metal Complex Begoña García , Editor Facultad de Ciencias, Universidad de Burgos, Spain President of the Scientific Committee of ISMEC201 3 Guido Crisponi, Editor University of Cagliari, Italy President of the ISMEC group ISMEC GROUP SERIES Volume: 3 Year: 201 3 ISSN: 2239-2459 Symposium Edition: XXI V Sponsors /Collaborators The following institutions and companies have supported ISMEC201 3, which we acknowledge: Sponsors : Collaborators : The Acta of the International Symposia on Metal Complexes (ISSN: 2239-2459) are published annually online by the ISMEC Group. Editors : Begoña García (President of the Scientific Committee of ISMEC 2013) Departamento de Química Facultad de Ciencias Universidad de Burgos Plaza de Missael Bañuelos s/n 09001 Burgos (Spain) [email protected] Guido Crisponi (President of the ISMEC Group) Dipartimento di Scienze Chimiche Università degli Studi di Cagliari Cittadella Universitaria 09042 Monserrato – Cagliari, ITALY [email protected] Scientific Committee of ISMEC 2013: Begoña García (University of Burgos, Spain) Guido Crisponi (University of Cagliari, Italy) Antonio Bianchi (University of Florence, Italy) Etelka Farkas (University of Debrecen, Hungary) Enrique García-España (University of Valencia, Spain) Carlos C.F. Geraldes (University of Coimbra, Portugal) Juan Niclós (University of Granada, Spain) Henryk Kozlowski (University of Wroclaw, Poland) José M. Leal (University of Burgos, Spain) Fernando Pina (University of Nova Lisbon, Portugal) Maria C. Rangel (University of Oporto, Portugal) Silvio Sammartano (University of Messina, Italy) M. Amélia Santos (University of Técnica Lisbon, Portugal) Fernando Secco (University of Pisa, Italy) Manuel Valiente (University of Autónoma Barcelona, Spain) Maurizio Remelli (University of Ferrara, Italy) Copyright : Authors retain the copyrights of their acta, and their unrestricted use, distribution and reproduction in any medium are permitted, provided that the original work is properly cited. The use of general descriptive names, trade names, trademarks, and so forth in this publication, even if not specifically identified, does not imply that these names are not protected by the relevant laws and regulations. While the advice and information in this journal are believed to be true and accurate on the date of its going to press, neither the authors, the editors, nor the publisher can accept any legal responsibility for any errors or omissions that may be made. The publisher and the editors make no warranty, express or implied, with respect to the material contained herein. Acta of the International Symposia on Metal Complexes ISMEC GROUP SERIES Volume: 3 Year: 2013 Symposium Edition: XXIV http://mat520.unime.it/ismecacta/ ISSN: 2239-2459 Acta of the International Symposia on Metal Complexes – ISMEC Acta, Volume 3 ISMEC 2013, June 16 th – 20 th 2013 – Burgos (Spain) Foreword The 2013 edition of the International Symposium on Metal Complexes (ISMEC) proudly continues the tradition of the XXIII Italian-Spanish Congress on Thermodynamics of Metal Complexes, since its origins held alternatively either in Italy or in Spain. This year, the meeting follows the practice adopted in the former edition of broadening the scope of the Synposium by extending the areas of interest as well as the home countries of potential participant researchers, thus having experienced a notable increase in the overall number of contributions and to internationalize the meeting as well with researches coming from 17 different countries. The conference venue of the ISMEC 2013 edition is the “Aula de Romeros” in the “Hospital del Rey”, the main building of the University of Burgos. Starting from 1195, it was erected by the King Alfonso VIII, and the full construction took several decades. Over the centuries, it was devoted mainly to host the Pilgrims Way to Santiago de Compostela, and in the early XX century it was abandoned. Later, it was reconstructed and in 1991 it was devoted again to public service, to be used as the Faculty of Law and Rectorship of the University of Burgos. The program developed by the Organizing Committee has sought to provide the participants with a balanced combination of both scientific and social programs, embodying the enthusiastic support and warm welcome of the city with the reception to all participants by the Lord Mayor. As an innovative proposal, the ISMEC 2013 also offers a Brokerage session, a special time devised as an opportunity for those who wish to offer/receive collaboration to/from other researchers, thus giving way to new joint research programs and new emerging groups in the near future. It is our strongest desire to convert the ISMEC symposium at Burgos into a memorable gathering with plenty of fond memories, one to be remembered for years. Burgos, June 16-20, 2013 Begoña Garcia 5 Acta of the International Symposia on Metal Complexes – ISMEC Acta, Volume 3 ISMEC 2013, June 16 th – 20 th 2013 – Burgos (Spain) Scientific Committee Begoña García (University of Burgos, Spain) Guido Crisponi (University of Cagliari, Italy) Antonio Bianchi (University of Florence, Italy) Etelka Farkas (University of Debrecen, Hungary) Enrique García-España (University of Valencia, Spain) Carlos C.F. Geraldes (University of Coimbra, Portugal) Juan Niclós Gutierrez (University of Granada, Spain) Henryk Kozlowski (University of Wroclaw, Poland) José M. Leal (University of Burgos, Spain) Fernando Pina (University of Nova Lisbon, Portugal) Maria C. Rangel (University of Oporto, Portugal) Silvio Sammartano (University of Messina, Italy) M. Amélia Santos (University of Técnica Lisbon, Portugal) Fernando Secco (University of Pisa, Italy) Manuel Valiente (University of Autónoma Barcelona, Spain) Maurizio Remelli (University of Ferrara, Italy) Organizing Committee Begoña García Chair (University of Burgos, Spain) José M. Leal Co-Chair (University of Burgos, Spain) Saturnino Ibeas Secretary (University of Burgos, Spain) F. Javier Hoyuelos (University of Burgos, Spain) A. Marta Navarro (University of Burgos, Spain) Indalecio A. Peñacoba (University of Burgos, Spain) Natalia Busto (University of Burgos, Spain) Jesús Valladolid (University of Burgos, Spain) Héctor J. Lozano (University of Burgos, Spain) Contacts ISMEC2013 Organizing Committee Departamento de Química Facultad de Ciencias Universidad de Burgos Plaza de Missael Bañuelos s/n 09001 Burgos (Spain) Tel: +34 947258819 Fax: +34 947258831 Congress website : http://www3.ubu.es/ismec2013/ Acta website : http://mat520.unime.it/ismecacta 6 Acta of the International Symposia on Metal Complexes – ISMEC Acta, Volume 3 ISMEC 2013, June 16 th – 20 th 2013 – Burgos (Spain) CONFERENCE PROGRAMME Sunday, June 16 th 19:00-21:00 Registration and Welcome Reception (NH Hotel Palacio de la Merced) Monday, June 17 th 8:15 Registration (Hospital del Rey) 9:00-9:15 Opening Ceremony Chairman: José M. Leal 9:15-10:15 PL-1: The Making of Homogeneous Catalysis: Coordination Chemistry at Work. Pablo Espinet 10:15-10:30 OC-1: Polymeric Forms of the Ternary Copper(II) Complexes with the Dinucleating p-Xylylenediamino-N,N,N’,N’-tetraacetate(4-) Chelator (p- XDTA) and imidazole (Him) or pyrazole (Hpz) N-coligands. Esther Vílchez-Rodríguez , Hanan El Bakkali, Alicia Domínguez-Martín, Aurora Gema Sicilia-Zafra, Alfonso Castiñeiras, Josefa María González-Pérez, Juan Niclós-Gutiérrez 10:30-10:45 OC-2: Hemilabile amino-amides as N,N -chelating systems for main group metals. Hana Kampova, Emilie Riemlova, Jitka Klikarova, Zdenka Padelkova, Ales Ruzicka 10:45-11:15 Coffee break Chairman: Antonio Bianchi 11:15-11:45 KN-1: Arene-linked dinuclear RAPTA analogues. Benjamin S. Murray , Rosario Scopelliti, Paul J. Dyson 11:45-12:00 OC-3: Fine-tuning of the cytotoxic activity in new Ru(II) arene complexes bearing benzimidazole ligand. Marta Martínez, Gustavo Espino , Begoña García, Natalia Busto, José M. Leal, Félix A. Jalón, Blanca R. Manzano, Ana María Rodríguez 12:00-12:15 OC-4: Kinetic Study of Metal Complexes with Tetraazamacrocyclic Ligands with Phosphorus Acid Pendant Arms. Radek Šev čík, Přemysl Lubal , Jakub Van ěk, Petr Hermann, Zuzana Kotková, Jan Kotek 12:15-12:30 OC-5: Copper(II) complexes of peptide derivatives containing imidazole side chains, as models of Cu,Zn-SOD enzyme. Katalin Várnagy , Gizella Csire, Sarolta Timári 7 Acta of the International Symposia on Metal Complexes – ISMEC Acta, Volume 3 ISMEC 2013, June 16 th – 20 th 2013 – Burgos (Spain) 12:30-12:45 OC-6: A new hydroxypyrone powerful chelator. From synthesis to Al III , Fe III , Cu II and Zn II complex formation equilibria, and structural characterization. Leonardo Toso, Guido Crisponi , Maria Amelia Santos, Sergio M. Marques, Valeria M. Nurchi, Joanna I. Lachowicz, Miriam Crespo-Alonso, Delara Mansoori, Alicia Dominguez-Martin, Juan Niclos-Gutierrez, Duane Choquesillo-Lazarte, Maria Antonietta Zoroddu, Massimiliano Peana 12:45-13:00 OC-7: Bismuth coordination chemistry: The snapshot before it precipitates. Caren Billing , Ignacy Cukrowski 13:00 Lunch break Chairman: Guido Crisponi 15:00-16:00 PL-2: Fundamental Bioorganometallic Technetium and Rhenium Chemistry in Targeted Molecular Imaging and Therapy. Roger Alberto , Daniel Can, Samer Sulieman, Sebastian Imstepf, Matthias Bauwens 16:00-16:15 OC-8: Platinum complexes with 1,10-phenanthroline derivatives: synthesis, kinetics and