Chemical Incompatibilities, Selected Listing

Chemical Incompatibilities, Selected Listing

<p> Attachment 1</p><p>CHEMICAL INCOMPATIBILITIES, SELECTED LISTING</p><p>Sources: University of New Hampshire-Biological and Chemical Safety Plan; Safety in Academic Chemistry Laboratories, published by The American Chemical Society; Prudent Practices in the Laboratory, 1995; National Academic Press</p><p>The following list is to be used only as a guide. Specific incompatibilities are listed in appropriate MSDSs. </p><p>CHEMICAL INCOMPATIBLE WITH:</p><p>Acetic acid Chromic acid, nitric acid, hydroxyl compounds, ethylene glycol, perchloric acid, peroxides, permanganates</p><p>Acetone Concentrated nitric and sulfuric acid mixtures </p><p>Acetylene Chlorine, bromine, copper, fluorine, silver, mercury</p><p>Alkali and alkaline earth Water, carbon tetrachloride or other chlorinated hydrocarbons, metals carbon dioxide, magnesium, calcium, lithium, halogens, sodium, potassium</p><p>Aluminum (powdered) Chlorinated hydrocarbons, halogens, carbon dioxide, organic acids </p><p>Ammonia (anhydrous) Mercury (e.g., in manometers), chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid</p><p>Ammonium nitrate Acids, powdered metals, flammable liquids, chlorates, nitrites, sulfur, finely divided organic combustible materials </p><p>Aniline Nitric acid, hydrogen peroxide </p><p>Arsenic materials Any reducing agent</p><p>Azides Acids</p><p>Bromine Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide, benzene, finely divided metals, turpentine </p><p>Calcium carbide Water, alcohol </p><p>Calcium oxide Water</p><p>Carbon (activated) Calcium hypochlorite, all oxidizing agents</p><p>Chlorates Ammonium salts, acids, powdered metals, sulfur, finely divided organic or combustible materials</p><p>19-10 Chromic acid & chromium Acetic acid, naphthalene, camphor, glycerol, alcohol, turpentine, trioxide flammable liquids in general.</p><p>Chlorine See bromine</p><p>Chlorine dioxide Ammonia, methane, phosphine, hydrogen sulfide </p><p>Copper Acetylene, hydrogen peroxide</p><p>Cyanides Acids</p><p>Fluorine Isolate from all other chemicals</p><p>Hydrocarbons (such as Fluorine, chlorine, bromine, chromic acid, sodium peroxide butane, propane, benzene)</p><p>Hydrocyanic acid Nitric acid, alkali</p><p>Hydrofluoric acid Ammonia (aqueous or anhydrous) (anhydrous) & hydrogen fluoride</p><p>Hydrogen peroxide Copper, chromium, iron, most metals or their salts, alcohols, acetone, organic materials, aniline, nitromethane, flammable liquids, oxidizing gases</p><p>Hydrogen sulfide Fuming nitric acid, oxidizing gases</p><p>Hypochlorites Acids, activated carbon</p><p>Iodine Acetylene, ammonia (aqueous or anhydrous) hydrogen</p><p>Mercury Acetylene, fulminic acid, ammonia</p><p>Mercuric oxide Sulfur </p><p>Nitrates Acids (especially sulfuric acid) </p><p>Nitric acid (concentrated) Acetic acid, alcohols, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids and gases, copper, brass, any heavy metals</p><p>Nitrites Acids</p><p>19-11 Nitroparaffins Inorganic bases, amines</p><p>Oxalic acid Silver, mercury</p><p>Oxygen Oils, grease, hydrogen; flammable liquids, solids and gases</p><p>Perchloric acid Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease, oils</p><p>Peroxides, organic Acids (organic or mineral), avoid friction or shock, store cold</p><p>Phosphorous (white) Air, oxygen, alkalis, reducing agents</p><p>Potassium Carbon tetrachloride, carbon dioxide, water</p><p>Potassium chlorate Sulfuric and other acids</p><p>Potassium perchlorate Sulfuric and other acids, see also chlorates</p><p>Potassium permanganate Glycerol, ethylene glycol, benzaldehyde, sulfuric acid</p><p>Selenides Reducing agents</p><p>Silver Acetylene, oxalic acid, tartaric acid, ammonium compounds, fulminic acid</p><p>Sodium Carbon tetrachloride, carbon dioxide, water </p><p>Sodium nitrate Ammonium nitrate and other ammonium salts </p><p>Sodium peroxide Ethyl or methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene glycol, ethylacetate, methyl acetate, furfural</p><p>Sulfides Acids</p><p>Sulfuric acid Potassium chlorate, potassium perchlorate, potassium permanganate (similar compounds of light metals, such as sodium, lithium)</p><p>Tellurides Reducing agents</p><p>Zinc powder Sulfur</p><p>19-12</p>

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