<p>Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001</p><p>A [2]-catenane whose rings incorporate two differently metallated</p><p> porphyrins.</p><p>Myriam Linke, Norifumi Fujita, Jean-Claude Chambron,* Valérie Heitz, Jean-Pierre</p><p>Sauvage*</p><p>Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Université Louis Pasteur,</p><p>Institut Le Bel, 4, rue Blaise Pascal, 67000 Strasbourg, France</p><p>Supplementary Information</p><p>1 Figure SI 1 : 1D H-NMR spectrum of [Cu1](PF6)2 at 400 MHz.</p><p>1 Figure SI 2 : H-NMR ROESY map of [Cu1](PF6)2, (0-10 ppm)x(0-10 ppm), 400 MHz (1/2).</p><p>1 Figure SI 3 : H-NMR ROESY map of [Cu1](PF6)2, (6-9.5 ppm)x(6-9.5 ppm), 400 MHz (2/2).</p><p>1 Figure SI 4 : 1D H-NMR spectrum of [1]PF6 at 400 MHz.</p><p>1 Figure SI 5 : H-NMR ROESY map of [1]PF6, (0-10 ppm)x(0-10 ppm), 400 MHz (1/4).</p><p>1 Figure SI 6 : H-NMR ROESY map of [1]PF6, (7-9.5 ppm)x(7-9.5 ppm), 400 MHz (2/4).</p><p>1 Figure SI 7 : H-NMR ROESY map of [1]PF6, (7-9.5 ppm)x(0-10 ppm), 400 MHz (3/4).</p><p>1 Figure SI 8 : H-NMR ROESY map of [1]PF6, (4.5-9 ppm)x(4.5-9 ppm), 400 MHz (4/4).</p><p>1 Figure SI 9 : H-NMR COSY map of [1]PF6, (7-9.5 ppm)x(7-9.5 ppm), 400 MHz. Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001 Supplementary Material (ESI) for New Journal of Chemistry This journal is ©The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2001</p>