Guide to the Chemical Literature

Guide to the Chemical Literature

<p>Chemistry 2411L Name ______Dr. Sheppard</p><p>Searching the Chemical Literature Report Sheet</p><p>Use the chemical literature to look up the answers to the following questions. Work individually or in groups of two. Answers should be typed and all chemical structures should be drawn using ChemDraw.</p><p>1. Draw structures and give the IPUAC names for the compounds:</p><p>(a) any compound with the molecular formula C15H10O6 (b) chrysanthemic acid (c) vitamin B2 (d) cadaverine (e) angelic acid (f) traumatic acid</p><p>2. Find the melting point for each of the following compounds: (a) biphenyl (b) 4-bromobenzoic acid (c) 3-nitrophenol</p><p>3. Find the boiling point for each of the following compounds: (a) octanoic acid at atmospheric pressure (b) 4-chloroacetophenone at atmospheric pressure and at reduced pressure (c) 2-methyl-2-heptanol (at any pressure, but be sure to specify what the pressure is)</p><p>4. Use the Merck Index or CRC Handbook of Chemistry and Physics to determine the following: (a) The CAS registry number for Vitamin B12. (b) The solubility of 1-hexene. (c) The density for 1-butanol (at atmospheric pressure).</p><p>5. List some of the health hazards for benzene.</p><p>6. An entry in the CRC Handbook describes the crystalline form of an organic molecule as “col. pl. f. al.”. What does this mean (i.e. what does the abbreviation stand for)?</p><p>7. Using the reference book by J. March, give two methods (including chemical equations) which can be used to prepare compounds containing each of the following functional groups: (a) carboxylic acids (b) esters</p><p>8. For the compound whose CAS is [81-81-2]: (a) Give its IUPAC name. (b) Give its common name. (c) Describe its major application. Chemistry 2411L Name ______Dr. Sheppard</p><p>9. For each of the following abbreviated names, provide the full name of the journal. Determine if CSU carries the journal. If not, list a library nearby that does. (a) Acc. Chem. Res. (b) J. Org. Chem. (c) Chem. Ber.</p><p>10. Use the resources discussed in class to answer the following: (a) List the first author on this article: J. Phys. Chem. A, 2002, 106 (13), pp 3114–3122. (b) How many journal articles containing the phrase “electrophilic addition” in the title of the article are published in the ACS journals? (c) List references for three journal articles authored by a chemist who has been awarded the Nobel Prize.</p><p>11. For your assigned compound (each group will be assigned a compound when we meet): (a) Provide a one-paragraph synopsis of the importance of the compound, including its complete chemical structure and IUPAC name. (b) List four complete citations for articles about your compound, including the article title, journal, issue, etc. Two of these citations must be from primary scientific journals. One of the articles can be from a popular journal or magazine (Newsweek, Time, Cosmopolitan, etc.). One citation should be from the web: search online and find the most interesting web site that provides information about your compound.</p>

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