ANNUAL REPORT INSTITUTE 3F NUCLEAR CHEMISTRY AND TECHNOLOGY ANNUAL REPORT 2000 INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY EDITORS Wiktor Smulek, Ph.D. Ewa Godlew ska-Para, M.Sc. PRINTING Sylwester Wojtas ) Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 2001 All rights reserved PLEASE BE AWARE THAT ALL OF THE MISSING PAGES IN THIS DOCUMENT WERE ORIGINALLY BLANK CONTENTS GENERAL INFORMATION 9 MANAGEMENT OF THE INSTITUTE 11 MANAGING STAFF OF THE INSTITUTE 11 HEADS OF THE INCT DEPARTMENTS 11 SCIENTIFIC COUNCIL (1999-2003) 11 SCIENTIFIC STAFF 14 PROFESSORS 14 ASSOCIATE PROFESSORS 14 SENIOR SCIENTISTS (Ph.D., D.Sc.) 14 SENIOR SCIENTISTS (Ph.D.) 15 RADIATION CHEMISTRY AND PHYSICS, RADIATION TECHNOLOGIES 17 RADIATION-INDUCED CHANGES IN AMINOGLUTETHIMIDE H. Ambroz, E. Kornacka, G. Przybytniak 19 IDENTIFICATION OF RADICALS IN ELECTRON BEAM IRRADIATED IFOSFAMIDE H. Ambroz, E. Kornacka, G. Przybytniak 20 " OH RADICAL INDUCED OXIDATION OF «-METHYLALANINE TIME-RESOLVED AND SPIN-TRAPPING ESR STUDY P. Wisniowski, G.L. Hug, R.W. Fessendcn 21 GENERATION OF AROMATIC THIOETHER RADICAL CATIONS CONTAINING PHENYL, VINYL, ALLYL, AND METHYL SUBSTITUENTS IN ORGANIC SOLVENTS A. Korzeniowska-Sobczuk, P. Wisniowski, K. Bobrowski, S. Naumov, L. Richter, O. Brede 23 OXIDATION PROCESSES OFN,S,-DIACETYL-L-CYSTEINEETHYLESTER: INFLUENCE OF S-ACETYLATION P. Wisniowski, G. Strzelczak, K. Bobrowski, N. Varmenot, S. Remita, Z. Abedinzadeh 25 SPECTRAL, KINETICS, AND THEORETICAL, STUDIES OF RADICAL CATIONS DERIVED FROM THIOANISOLE AND ITS CARBOXYLIC DERIVATIVE A. Korzeniowska-Sobczuk, K. Bobrowski, G.L. Hug, I. Carmichael 26 INTERACTION OF TETRAMERIC SILVER WITH AMMONIA IN AgCs-rho ZEOLITE J. Sadio, M. Danilczuk, J. Michalik 29 A NANOSECOND PULSE RADIOLYSIS SYSTEM DEDICATED TO THE NEW LAE 10 ACCELERATOR IN THE INCT J. Mirkowski, P. WiSniowski, K. Bobrowski 31 POST-IMPLANTATION DEFECTS. INSTABILITY UNDER 1 MeV ELECTRON IRRADIATION IN GaAs S. Warchot, H. Rzewuski, J. Krynicki, R. Grotzschel . 33 RADIATION CHEMISTRY OF POLYMERS AS RECOGNIZED BY DIFFUSE REFLECTANCE SPECTROPHOTOMETRY (DRS) Z.P. Zag6rski, A. Rafalski . 35 ROLE OF SPURS IN IRRADIATED POLYMER BLENDS Z.P. Zag6rski 37 EPR SPECTROSCOPY OFy-IRRADIATED POLYCRYSTALLINE ASPARAGINE AND ASPARAGINE-CONTAINING PEPTIDES G. Strzelczak, K. Bobrowski, Ch. Houee-Levin, J. Berges 39 MULTIFREQUENCY EPR STUDY OF RADICALS PRODUCED BY RADIATION IN SHELLS AND CORALLITE G. Strzelczak, W. Stachowicz, J. Michalik, G. Vanhaelewyn, F. Callens, E. Goovaerts 41 QUALIFICATION OF THE CONCENTRATION RATIO OF RADIATION INDUCED HYDROCARBONS IN RELATION TO FATTY ACID COMPOSITION WITH THE USE OF A GAS CHROMATOGRAPH (GC) K. Lehner, W. Stachowicz 43 DETECTION OF IRRADIATION OF FROZEN FISH MEAT BY SINGLE CELL GEL ELECTROPHORESIS K. Malec-Czechowska, Z. Szot, W. Stachowicz, M. Kraszewski 44 GELATIN IS ATION AND AMYLOSE-LIPID COMPLEX TRANSITION OCCURRING IN NATIVE AND GAMMA IRRADIATED STARCHES STUDIED BY DIFFERENTIA!. SCANNING CALORIMETRY K. Cieśla, A.-Ch. Eliasson, W. Głuszewski 46 THERMOLUMINESCENCE OF SOILS FROM KUJAWY-POM ERAN IAN REGION A.M. Dancewicz, K. Malec-Czechowska 47 RADIOLYTIC DEGRADATION OF HERBICIDE Z4-DICHLOROPHENOXY ACETIC ACID (2,4-D) P. Drzewicz, M. Trojanowicz, P. Panta, W. Głuszewski, M. Gryz, G. Nałęcz-Jawecki, J. Sawicki, C. Duarte, M.H.O. Sampa, H. Oikawa, M. Szewczyńska, A. AJ-Kaid, A.A. Al-Mowed 49 RADIATION MODIFICATION OF LDPE (BRALEN TYPE) I. Legocka, Z. Zimek, K. Mirkowski, M. Zielonka 51 RADIATION STERILIZATION OF ALLOGRAFTS I. Kałuska, Z. Zimek 54 EB DOSE CALIBRATION FOR THE LINEAR ELECTRON ACCELERATOR IN THE INCT EXPERIMENTAL PLANT FOR FOOD IRRADIATION H.B. Owczarczyk, W. Migdał, W. Stachowicz, G. Strzelczak 56 CHEMICAL DOSIMETRY. LMTD STAND FOR PRECISE -/-IRRADIATION OF DOSIMETERS AND OTHER SMALL OBJECTS Z. Stuglik 57 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, GENERAL CHEMISTRY 59 INFLUENCE OF RELATIVISTIC EFFECTS ON HYDROLYSIS OF Ra2+ B. Wiodzimirska, A. Bilewicz 61 DETERMINATION OF TRACE AMOUNTS OF CADMIUM IN GEOLOGICAL AND ENVIRONMENTAL MATERIALS BY NAA WITH PRECONCENTRATION ON AMPHOTERIC ION EXCHANGE RESIN Z. Samczyński, R. Dybczyński, B. Danko 62 PROBLEMS OF THE ATTRIBUTION OF WORKS OF ART: EXAMPLES OF 18th CENTURY CENTRAL EUROPEAN DECORATIVE GLASS J. Kunicki-Goldfinger, J. Kierzek, A.J. Kasprzak, B. Małożewska-Bućko 63 DYNAMIC ADSORPTION OF RADIOEUROPIUM FROM SIMULATED LIQUID RADIOACTIVE WASTES ON «-CRYSTALLINE POLYANTIMONIC ACID J. Satyanarayana, A. Bilewicz, J. Narbutt 64 DIFFUSE REFLECTION SPECTROSCOPY: STUDIES OF OXIDE LAYERS FORMED ON THE STAINLESS STEELS IN HIGH TEMPERATURE WATER L. Fuks, C. Degueldre 65 .AN ATTEMPT TO FRACTIONATE URANIUM ISOTOPES IN THE ACETATE-AMALGAM SEPARATION SYSTEM W. Dembiński, M. Poniński, R. Fiedler 67 AQUEOUS SOLUBILITIES OF RARE EARTH TRIHALIDES (Cl, Br, I) AT 298 K T. Mioduski 67 STUDIES ON DETERMINATION OF SOME TRANSITION METALS IN BIOLOGICAL MATERIALS BY ION CHROMATOGRAPHY K. Kulisa, H. Polkowska-Motrenko, R. Dybczyński 68 SIMPLE PC SOFTWARE FOR ROUTINE ANALYSIS OF GAMMA-RAY SPECTRA Z. Szopa, R. Dybczyński 70 DIRECT PRETREATMENT OF ANALYTICAL SAMPLES IN A GRAPHITE FURNACE TUBE IN ATOMIC ABSORPTION SPECTROMETRY L. Pszonicki, W. Skwara, J. Dudek 71 DETERMINATION OF TRACE CONCENTRATION OF PLATINUM IN ENVIRONMENTAL SAMPLES BY GRAPHITE FURNACE ATOMIC: ABSORPTION SPECTROMETRY AFTER PRECONCENTRATION ON A SORBENT .1. Chwastowska, W. Skwara, E. Sterlińska, J. Dudek, L. Pszonicki 72 RADIONUCLIDE CONCENTRATION MEASUREMENTS IN SOLUTION AND SOIL J. Kierzek, J. Parus, B. Malożewska-Bućko 73 SURFACE MODIFICATION OF PARTICLE TRACK-ETCHED MEMBRANES D. Wawszczak, W. Malicki, M. Buczkowski 75 RADIATION RESISTANCE OF PARTICLE TRACK-ETCHED MEMBRANES M. Buczkowski, B. Sartowska, D. Wawszczak, W. Starosta 76 SYNCHROTRON SAXS STUDY OF PERMEATING MEMBRANE DEPENDING ON ITS DEPTH H. Grigoriew, S. Bernstorff, A. Wolinska-Grabczyd, A.G. Chmielewski 78 SYNTHESIS OF LiCoO2 AND LiMgo 05C00 95O2 THIN FILMS ON POROUS Ni/NiO CATHODES FOR MCFC BY COMPLEX SOL-GEL PROCESS (CSGP) W. tada, A. Deptuta, B. Sartowska, T. Olczak, A.G. Chmielewski. M. Carewska, S. Scaccia, E. Simonetti, L. Giorgi, A. Moreno 79 LiCoO2 NANOCOMPOSITE DOPED SiO2, TiO2, AI2O3 FOR RECHARGEABLE LITHIUM BATTERIES A. Deptula, F. Croce, W. tada, D. Deptuta, T. Olczak, D.L. Chua 81 THE CRYSTAL STRUCTURE OF TETRA-n-BUTYLAMMONIUM TETRAIODOINDATE(III) K. Rudawska, H. Ptasiewicz-BaX S. Siekierski 83 ASYMMETRIC HYDROGEN BONDS IN CENTROSYMMETRIC ENVIRONMENT: NEUTRON STUDY OF THE VERY SHORT HYDROGEN BOND IN POTASSIUM HYDROGEN DICHLOROMALEATE I. Olovsson, H. Ptasiewicz-B^k, T. Gustafsson, I. Majerz 84 ANTIFERROMAGNETIC ORDER IN RlrSi (R=Tb-Er) COMPOUNDS A. SzytuJa, M. Hofmann, J. Leciejewicz, B. Penc, A. Zygmunt 85 NEUTRON SCATTERING SPECTROSCOPY AND AB INITIO STUDY OF L-THREONINE A. Pawlukojc, J. Leciejewicz, J. Tomkinson, S.F. Parker 85 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXII: THE CRYSTAL AND MOLECULAR STRUCTURE OF A CALCIUM(II) COMPLEX WITH PYRIDINE-2,6-DICARBOXYLATE AND WATER LIGANDS W. Starosta, H. Ptasiewicz-Bgk, J. Leciejewicz 87 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXIII: THE CRYSTAL AND MOLECULAR STRUCTURES OF TWO POLYMORPHIC FORMS OF A CALCIUM(II) COMPLEX WITH PYRIDINE-2,6-DICARBOXYLATE, WATER AND NITRATE LIGANDS W. Starosta, H. Ptasiewicz-Bgk, J. Leciejewicz 88 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XXXIV: THE CRYSTAL AND MOLECULAR STRUCTURES OF LEAD(II) COMPLEXES WITH FURAN-2-CARBOXYLATE AND FURAN-3-CARBOXYLATE LIGANDS B. Paluchowska, J.K. Maurin, J. Leciejewicz 90 RADIOBIOLOGY 93 EXPRESSION OF TP53 EFFECTOR PROTEINS AND STRESS KINASES IN L5178Y SUBLINES I. Grijdzka, I. Szumiel, D. Kowalczyk, P. Janik 95 CAFFEINE-INHIBITABLE CONTROL OF THE RADIATION-INDUCED G2 ARREST IN L5178Y-S CELLS DEFICIENT IN NON-HOMOLOGOUS END-JOINING I. Szumiel, I. Grqdzka, M. Kapiszewska 96 EXAMINATION OF MICRONUCLEI FREOUENCY AS AN IONIZING RADIATION SENSITIVITY MARKER IN A PANEL OF LYMPHOID CELL LINES A. Jaworska, P. De Angelis, I. Szumiel, J. Reitan 97 EXAMINATION OF THE ROLE OF DOUBLE STRAND BREAK REPAIR IN THE ADAPTIVE RESPONSE OF HUMAN LYMPHOCYTES: NEUTRAL COMET ASSAY M. Wojewodzka, I. Gnjdzka, I. Buraczewska 98 EXAMINATION OF THE ROLE OF DOUBLE STRAND BREAK. REPAIR IN THE ADAPTIVE RESPONSE OF HUMAN LYMPHOCYTES: PULSE FIELD ELECTROPHORESIS I. Gradzka, M. Wojew6dzka, I. Buraczewska 99 CYTOTOXIC EFFECTS OF CIS-PLATINUM AND PALLADIUM(II) CHLORIDES COMPLEXED WITH A NOVEL STABLE LIGAND STUDIED IN MOUSE LYMPHOMA CELL LINES DIFFERING IN DNA REAPIR SYSTEMS M. Kruszewski, E. Bouzyk, T. Otdak, K. Samochocka, L. Fuks, W. Lewandowski, W. Priebe 101 DNA DAMAGE INFLICTED IN MOUSE LYMPHOMA CELL LINES BY CIS-PLATINUM AND PALLADIUM(II) CHLORIDES COMPLEXED WITH A NOVEL STABLE LIGAND (wpl-1) M. Kruszewski, E. Bouzyk, K. Samochocka, L. Fuks, W. Lewandowski, W. Priebe 102 DIFFERENTIAL ANTI-PROLIFERATIVE PROPERTIES OF NOVEL HYDROXYDICARBOXYLATOPLATINUM(II) COMPLEXES WITH HIGH OR LOW REACTIVITY WITH THIOLS I. Buraczewska, E. Bouzyk, J. Kuduk-Jaworska, K. Waszkiewicz, I. Szumiel 103 G2 PHASE ARREST CAUSED BY HYDROXYDICARBOXYLATOPLATINUMCII) COMPLEXES WITH LOW REACTIVITY WITH THIOLS I. Buraczewska, J. Kuduk-Jaworska, K. Waszkiewicz, A. Gasińska, I. Szumiel 104 CYTOPLASMIC ACTIVITY OF TYROSINE PROTEIN KINASE, c-Abl, IN L5178Y MURINE LYMPHOMA CELL SUBLINES - A LINK TO DIFFERENTIAL APOPTOSIS PRONENESS? B. Sochanowicz. I. Szumiel 104 VALIDATION OF THE MICRONUCLEUS-CENTROMERE ASSAY