Unusual Η1-Coordinated Alkyne and Alkene Complexes Abstract

Unusual Η1-Coordinated Alkyne and Alkene Complexes Abstract

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email protected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`1 PMaJD)HK! E-G(G! G'FG! 0G($%! F4'! a-0GG(-$! QO! H:#%:-8=%&0'! ! A4'! %'#8'F:('G! S':'! #HF(8(L'D! ($! D(?4B#:#8'F4-$'! G#B0F(#$)! -$D! F4'! G#BI'$F! '&&'?FG! S':'! 'I-B0-F'D! 0G($%! F4'! >+.! J>#B0F(#$! +#D'B! E-G'D! #$! .'$G(F;K! 8'F4#D=%&&'! ! A4':8-B! ?#::'?F(#$G! -$D! '$F:#H;! ?#$F:(E0F(#$G! F#! F4'! a(EEG!&:''!'$':%;!S':'!F-C'$!&:#8!&:'b0'$?;!?#8H0F-F(#$G!S(F4!F4'!G-8'!c5OV91.d`1PMaJD)HK! B'I'B!#&!F4'#:;!($!D(?4B#:#8'F4-$'!G#B0F(#$=! ! ZBB!F:-$G(F(#$!GF-F'G!S':'!?#$&(:8'D!F#!',4(E(F!#$B;! #$'!(8-%($-:;!I(E:-F(#$-B!&:'b0'$?;!I(-!/'GG(-$!-$-B;G'G=!!e'!4-I'!F4#:#0%4B;!',-8($'D!F4'! ?#$&#:8-F(#$-B!GH-?'!#&!'-?4!($F':8'D(-F'!-$D!F:-$G(F(#$!GF-F')!-$D!F4'!B#S'GF!'$':%;!?#$&#:8':G! -:'!($?B0D'D!($!F4'!D(G?0GG(#$G=! ! f-F0:-B!E#$D!#:E(F-B!Jf5_K!-$-B;G'G!S':'!H':&#:8'D!0G($%! f5_!`=Q!H:#%:-8=%&('! ! ! $! ! ! @$! #:D':! F#! ?#$&(:8! F4'! .<A! H:'D(?F(#$G)! G($%B'! H#($F! '$':%('G! S(F4! F4'! B-:%':! `1 PMMaJND)NHK!E-G(G!G'F!S':'!'I-B0-F'D!S(F4!C';!GF:0?F0:'G=! ! e'!-BG#!'8HB#;'D!$'S':!D'$G(F;! &0$?F(#$-BG! J+fMR)! 5P"761.P)! +Q`1N9K! F#! GF0D;! F4'! :'-?F(#$! H-F4S-;G=! ! >($?'! -BB! F4'! 8'F4#DG!H:'D(?F!?#$G(GF'$F!:'G0BFG)!S'!#$B;!D(G?0GG!F4'!c5OV91.d`1PMaJD)HK!:'G0BFG!($!F4'!F',F)! S4(B'!F4'!#F4':!:'G0BFG!-:'!:'H#:F'D!($!>0HH#:F($%!@$&#:8-F(#$!J>@K=! ! ;/$#&.$'%",',-$7#$$-*"' ! ! ! <(%0:'!M=!a(EEG!&:''!'$':%;!H:#&(B'G!J($!C?-Bd8#BK!&#:!F4'!M)M1D(E#:-F(#$!H-F4S-;!#&!>?4'8'!M=! ! g!G(%$(&('G!F4'!H'$F-G0EGF(F0F'D!H4'$;B!:($%=! ! ! ! A4'! M)M1D(E#:-F(#$! H-F4S-;! (G! (BB0GF:-F'D! ($! <(%0:'! M=! ! A4':'($)! F4'! M1H'$F;$'! ?-$! ?##:D($-F'!S(F4!F4'!5JMK!-F#8!($!D(E#:-$'!!$F4:#0%4$F4'!F:-$G(F(#$!GF-F'!%&!'(!=! ! A4'!0$0G0-B! %! ! ! Q&1?##:D($-F('D!GF:0?F0:'$(!!S(F4!-$!'$':%;!#&!MX=O!C?-Bd8#B!-E#I'!!!(G!&#0$D=!/#S'I':)!F4'! ?#88#$!Q(1?##:D($-F('D!GF:0?F0:'!S-G!$#F!B#?-F'D)!E'?-0G'!(F!?#BB-HG'G!F#!F4'!Q&1?##:D($-F('D! GF:0?F0:'=! ! A4'!%'#8'F:;!#&!(!!(G!:'H#:F'D!($!<(%0:'!N=! ! A4'!UJNK15JMK!G'H-:-F(#$!JN=VR`!hK!(G! G(%$(&(?-$FB;!B#$%':!F4-$!F4'!UJMK15JMK!E#$D!JM=V``!hK)!-$D!F4'!&#:8':!(G!F##!B#$%!F#!D'G?:(E'!-G! -!?#$I'$F(#$-B!E#$D=! ! A4'!-$%B'G!/JMK1UJMK1UJNK)!5JMK1UJMK1UJNK)!5JMK1UJMK1/JMK!-:'!MNQi)! MPMi)! MQXi)! :'GH'?F(I'B;)!($D(?-F($%!F4'! -HH:#,(8-F'! GH(! 4;E:(D(L-F(#$!#&! F4'! UJMK!-F#8=! ! @$! ?#$F:-GF)!-F#8!UJNK!:'8-($G!-HH:#,(8-F'B;!GH!4;E:(D(L'D!D0'!F#!F4'!$'-:!B($'-:!-::-$%'8'$F!#&! UJMK1UJNK1UJPK!JMVX!K=! ! A4':'&#:')!(F!8-;!E'!?#$?B0D'D!F4-F!M1H'$F;$'!-D#HFG!-$!0$0G0-B!Q&! F':8($-B!?##:D($-F(#$!8#D'!S(F4!:'GH'?F!F#!F4'!D(E#:-$'=! ! <(%0:'!N=!A4'!GF:0?F0:'G!($!F4'!M)N1D(E#:-F(#$!H-F4S-;=! ! A4'!($F':$0?B'-:!G'H-:-F(#$G!-:'!($!h=! ! A4'!%:#0HG!#$!F4'!5!-F#8G!-:'!D:-S$!($!S(:'&:-8'!&#:!G(8HB(?(F;=!!/#S'I':)!-BB!-F#8G!S':'! ($?B0D'D!($!F4'!%'#8'F:;!#HF(8(L-F(#$=! ! &! ! ! A4'!'B'?F:#$(?!GF:0?F0:'!&#:!F4'!?#8HB',!(!!S(F4!-$!Q&1M1H'$F;$'!&:-%8'$F!4-G!E''$!GF0D('D! I(-!f5_!-$-B;G(G=! ! A4'!M1H'$F;$'!8#('F;!(G!E#$D'D!F#!D(E#:-$'!I(-!#$'!U!-F#8!#&!F4'!UjU! E#$D)!E;!D#$-F($%!FS#!k!'B'?F:#$G!#&!UjU!($F#!F4'!'8HF;!F!#:E(F-B!#&!F4'!5JMK!-F#8!F#!&#:8!-! UJMK15JMK!E#$D)!B'-I($%!F4'!UJNK!-F#8!'B'?F:#$1D'&(?('$F=! ! A4'!f5_!-$-B;G(G!G4#S'D!-!lB#$'! I-?-$?;m!J"nK!&#:!F4'!UJNK!-F#8)!S4(?4!?#::'GH#$DG!F#!-$!'8HF;!I-B'$?'1H!#:E(F-B!JF1(*!(G!0G'D! E'B#SK=! ! Z??#:D($%B;)! F4'! $-F0:-B! -F#8(?! ?4-:%'G! &#:! UJMK! -$D! UJNK! -:'! 1Q=\R! -$D! oQ=\N)! :'GH'?F(I'B;=! ! A4'!f5_!G'?#$D1#:D':!H':F0:E-F(#$!GF-E(B(L($%!'$':%('G!BJNK!&#:!F4'!W1&23&"F1(*)! W1&24&"F1(*)!W1)24)"F1(*)!W1)24*"F1(*!'B'?F:#$!F:-$G&':!-:'!'GF(8-F'D!-G!RO)!PP)!M\)!-$D!NP! C?-Bd8#B)!:'GH'?F(I'B;=! ! A4'G'!8-;!H:#I(D'!-!8'-G0:'!&#:!F4'!4;H':?#$[0%-F(#$!'&&'?FG=! ! @$! <(%0:'!P!F4'!'B'?F:#$!D'$G(F;!#&!U1/!-$D!U15!E#$DG!$'-:!F4'!UJNK!-F#8!D'B#?-B(L'!F#!F4'!'8HF;! F1(*!#:E(F-B=! ! A4'!4;H':?#$[0%-F(#$!($F':-?F(#$G!B'-D!F#!-!G4#:F':!UJNK1UJPK!E#$D!JM=\PN!hK!($! (!)!?#8H-:'D!F#!F4-F!($!&:''!M1H'$F;$'!JM=\`\!hK=! ! @$!-DD(F(#$)!F4'!F:-$G&':G!#&!W1)24)"W1&21(*! JP=O! C?-Bd8#BK! -$D! W1)24("W1&21(*! J\=Q! C?-Bd8#BK! 4-I'! -BG#! 8-D'! 8($#:! ?#$F:(E0F(#$! F#! F4'! 4;H':?#$[0%-F(#$!'&&'?FG=! ! A4'!f5_!-$-B;G(G!G4#SG!$#!G(%$(&(?-$F!D#$-F(#$!&:#8!F4'!UJMK1/JMK! E#$D!F#!F4'!5JMK!-F#8=! ! A4'!fgA!?#8H0F-F(#$G!&#:!F4'!G(8HB(&('D!8#D'B!#&!(!!G4#S'D!F4-F!F4'! S'(%4F!#&!F4'!:'G#$-$?'!GF:0?F0:'!S(F4!-%#GF(?!UJMK1/JMK!F#!5JMK!-F#8!(G!I':;!B#S!JM=M^K)!S4(B'! F4'!GF:0?F0:'!(!!D(GHB-;'D!($!<(%0:'!P!4-G!F4'!B-:%'GF!S'(%4F!J\V^K=! ! '! ! ! ! ! <(%0:'! P=! >?4'8-F(?! :'H:'G'$F-F(#$G! #&! 4;H':?#$[0%-F(#$! ($! F4'! ?##:D($-F'D! M1H'$F;$'! ?#8H#0$D=! ! A4'!$08':(?-B!:'G0BFG!-:'!F4'!f5_!G'?#$D1#:D':!H':F0:E-F(#$!GF-E(B(L($%!'$':%('G! BJNK!($!C?-Bd8#B=! ! >($?'!F4'!UJMK1/JMK!E#$D!(G!B-:%'B;!-?F(I-F'D!($!-GG#?(-F(#$!S(F4!F4'!GF:#$%!W1&24&"F1(*! 4;H':?#$[0%-F(#$! '&&'?F)! F4'! /JMK! -F#8! ?#0BD! 8#I'! -?:#GG! F4'! UJMK1UJNK! E#$D! S(F4! -! G8-BB! '$':%;!E-::(':=! ! ZBF4#0%4!F4'!F#F-B!'$':%;!J"BK!#&!%&(!!(G!4(%4':!F4-$!(!$E;$N=V!C?-Bd8#B)!F4'! a(EEG!&:''!'$':%;!J"KK!&#:!F:-$G(F(#$!GF-F'!%&(!!(G!Q=N!C?-Bd8#B!B#S':!F4-$!F4-F!#&!(!=$ $ @$!F4'! G0EG'b0'$F!GF'HG)!F4'!($F':8'D(-F'!(")!S(F4!-!a(EEG!&:''!'$':%;!#&!MQ=R!C?-Bd8#B!-E#I'!!)!(G! %'$':-F'D)!-$D!F4'!f6Z!?4-:%'G!&#:!F4'!UJMK)!UJNK)!5JMK)!5JNK!-F#8G!-:'!oQ=NR)!1Q=PN)!1Q=Q`)! oQ=XN)!:'GH'?F(I'B;=! ! A4'!G0EG'b0'$F!F:-$G&':!#&!?-:E#$!-F#8!UJMK!E'FS''$!5JMK!-$D!5JNK!-F#8G! S(BB!B'-D!F#!F4'!?B'-I-%'!#&!F4'!5JMK15JNK!E#$D=! ! ZG!-!:'G0BF)!F4'!M)M1D(E#:-F(#$!H:#D0?F!"!(G! &#:8'D!S(F4!-!B-:%'!',':%#$(?!:'-?F(#$!'$':%;!#&!RN!C?-Bd8#B=! ! @$!E:('&)!F4'!&#:8-F(#$!#&!F4'!Q&1 ?##:D($-F(#$! ?#8HB',! (!! -BB#SG! F4'! UJGHK1/! ?B'-I-%'! -$D! &0:F4':! B'-DG! F#! F4'! 0$0G0-B! M)M1 D(E#:-F(#$!H:#D0?F=! ! (! ! ! ! <(%0:'!\=!a(EEG!&:''!'$':%;!H:#&(B'G!J($!C?-Bd8#BK!&#:!F4'!M)N1D(E#:-F(#$!H-F4S-;=! ! g!D'$#F'G! F4'!H'$F-G0EGF(F0F'D!H4'$;B!:($%=! ! ! @$!F4'!M)N1D(E#:-F(#$!H-F4S-;!J<(%0:'!\K)!M1H'$F;$'!?-$!8-F?4!F4'!H#?C'F!#&!D(E#:-$'!!)! %'$':-F($%! -! G0H:-8#B'?0B-:! ($F':8'D(-F'! *! F4:#0%4! -! $#$1?#$I-B'$F! ($F':-?F(#$! S(F4! -! &:''! '$':%;! #&! O=`! C?-Bd8#B)! -$D! F4'! F4:''1D(8'$G(#$! &(%0:'! #&! *! (G! :'H#:F'D! ($! <(%0:'! R=!!A4'! E#0$D'D!M1H'$F;$'!?-$!&0:F4':!-HH:#-?4!F4'!5JMK!-F#8!($!-$#F4':!Q&1?##:D($-F(#$!8#F(&!F4:#0%4! F4'!F:-$G(F(#$!GF-F'!%&!'+!=! ! U#8H-:'D!S(F4!(FG!(G#8':!(!$J&#:!F4'!M)M1D(E#:-F(#$!($!<(%0:'!MK)! +!!4-G!B'GG!GF':(?!4($D:-$?')!-$D!(F!?#0BD!B('!($!B#S':!'$':%;=! ! @$!&-?F)!F4'!&:''!'$':%;!#&!+!!(G! MR=R!C?-Bd8#B!-E#I'!!)!S4(?4!(G!P!C?-Bd8#B!B#S':!F4-$!(!=! ! f'I':F4'B'GG)!F4'!?##:D($-F'D!M1 H'$F;$'!($!+!!E'-:G!F4'!G-8'!'B'?F:#$(?!GF:0?F0:'!-G!($!(!!-??#:D($%!F#!F4'!-$-B;G(G!($!<(%0:'!>M! ($!>@=! ! A4'!G4(&F!#&!?-:E#$!-F#8!UJMK!&:#8!F4'!5JMK!-F#8!F#!5JNK!S(BB!B'-D!F#!-!?B'-I-%'!#&!F4'! )! ! ! 515!E#$D)!-$D!F4(G!:'b0(:'G!F4'!G;GF'8!F#!#I':?#8'!-$!'$':%;!E-::(':!#&!N!C?-Bd8#B=!

View Full Text

Details

  • File Type
    pdf
  • Upload Time
    -
  • Content Languages
    English
  • Upload User
    Anonymous/Not logged-in
  • File Pages
    16 Page
  • File Size
    -

Download

Channel Download Status
Express Download Enable

Copyright

We respect the copyrights and intellectual property rights of all users. All uploaded documents are either original works of the uploader or authorized works of the rightful owners.

  • Not to be reproduced or distributed without explicit permission.
  • Not used for commercial purposes outside of approved use cases.
  • Not used to infringe on the rights of the original creators.
  • If you believe any content infringes your copyright, please contact us immediately.

Support

For help with questions, suggestions, or problems, please contact us