I pA, 7) ^wammam 1 BLANK PAGE m \ Printed in the United Statts of America. Actable from National Technical Information Service U.S. Department of Commerce 5286 Port Royal Road. Springfield, Virginia 22161 Price: Printed Copy $7.75; Microfiche $2.25 0MK.4111 UC4-CH lili latfag NanalMr 1. OL. LMNrci.SKtN R. L- Hjfcn. SMXMM Ckirf FEMUAKY 1976 >«<h*«M«l L«*» OAK ftlOGt NATIONAL LABORATORY 0*ftidgt.T«WMWW 37180 oparaMty UNION CARMDE CORPORATION tor flit ENERGY RESEARCH AND DEVELOPMENT AOMNMTRATION wsra I. vrrn RcputU pwnwfr amei m dm «mr» WK M to* or* 0«M-2Ja» fltnurit: •**J«K20.I*5^ ORM.2504 IfciwJE •**JMK20. I*$* 0»Xl-27»2 KIIMI Em+m ftm*Xi.im OKM.2W3 RnwJE •**J«ar 20.1*40 0*M3I?* hmdE •*yJ«K20. I**l OKM.3320 ffcmriE 0**JMK2O.I*4>2 OKSL-34IS IfcriutfEa*agJ« r 20.1*4*3 0«M.J*7* reiw4 fcat e J«w 20.1*44 ORM-3032 fcr.i* t«*H *J» 20. !4»5 OKMKM reiwtf E***tti > 20.1** 0RXL-4IM tok*f: aawfIfa>20.W»? 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NOLffN«Aft.TS¥*TfMS 1 I Matlrsh&akXcxiofPlNinm I II I TwSrfmDt*aMm.wH*r4kKSSarfiKCs»»MSNl 1 II. t (w«c..<Mrtil>^^Siapln loTHbniVy» 2 113 t»4mpf» Bemxtw tyfifcn— «rfUF« Puiofced m Mortal rvpnfMf MlXlMn - - ^ 114 tifrvtsof Ox>ys> «m me ti|ii*fcniiii n<LTt-tT« Mofcea f-mnndc S>*ww f «amid m CramW 5 115 tin—up <£f iiiwn ftmm+on* 5 I I* ftt*mQ**MmK*<*C<*rammrta^tflmanit%mMcl*»Sditlnciot OiaUm ? i .1.- Cs*sraur> «f Fmurwstma mi fad KroaMWlw 9 1 I s rtvumtltclra* State* MJMmiSrits 9 \ 2 1tm*t-<n mi "n*Tma*yif»%m*>**•*&* II 1 AOlCOiS SYSTEMS ANPCCOrnCtMAlEl«aCY 2 I A^wStiKiH 12 211 1Vlftffih<n'>(t4<K«i A CrrtKal Review of Hydfutyus Spear* miTtKu%im*it\C.*»imt>mAmt**aS*+itKm 12 2 I 2 Tranputt M»M «»lf tmccMrasrd Aqanxn Urciroty tr SatetiotK 14 2 : * titrawm <it a 1%-^Stnetmt Model fa* EtoctruHle Sotnoons in Aq*e<a» Mure tkvtratytr Synrms 16 2 I 4 PreaVo.* •if Ot&xtc mi Activity CaefAdraf* f.»r EJrclrtdytr jdunwri si Ue«4*d Temperature* 17 2 I 5 l*m/*\*m fnMmi of Nunc Add at taa* Temperawre* from S»»mrlme% ••tTaknsmStdfa*? Activity Cuefficvuft sad lllerajindyaamK F«ntt»*H |7 2 16 E»penmemst sad Catenated Suamdttie* af Mamnmm Sattste Mxwdrydtag w Aqaroa* Xtiwc Aa< aid Related Sutabwtit* K 2 IT Tfcenattdyrumic f-uaci»«» at SatwratMi nf Several Metal Satiate* M Aaanwrt Satiate and DeuterosaManc Acids at Temperaiast* ap i» WOT 20 i: Ce.>tnermsl laerrv 21 2.2 I t\rcaajta(na> andSialaigm Dynamic GetHheriml Systran 2i J-2 2 *•><**) tTiemr»t»y ofufndJmawi Solutmn* 2.: 1 CMDISTItVfflSjmHirOf rtfflONtUACTQIlTKtINQlJOCV 31 bmdsbna m ttr&.«jr« Isttoar CTR^Iaakef Systems 26 3 2 ftmmiMm «»f M«?e» .A hv tfedroprn Isotopes 2d 3 3 Pusssbk Red.* Bun*** aw rilK Bankets 2» 3.4 Surface f:ffs\-u IT. OMMAK A Pwwnwwy Survey from a Chemical Pk»mt «'f W* 29 iii I* 4. OKMBniY0FnUmUUMUIfLBSN1S 4.1 Dmi—ama of d»IMf-Wj^< •<!••<• iFbWi^trfHjfcLi— (EhwN 1021 30 4 2 IVpmaoaaWlSaawsofSoavAcaaalrlfefal* 30 43 HeatofSaawoflriiiliaiilletal 32 4 • Sprxwacoa* mi X-fcay DrffracooaStates ofLatna— 253 iwwfa 32 4.5 SaaytaaCnaalrmaiaiActaafcEliaMats 33 4.6 Effect of SeoMdaiylaidsoa da Straw* of OKpO toads 34 4.7 Mi|i inJf-SttiesXIUys 37 4J9 EltCtfOA BaaawaffM EMCinCS Ml ActMMM. nuCAKMMBML. HMflBaWR. 4.9 Ainaaiiwi Sow Qrait Suaiia» of a* 4/Le»et a the Actaade Sewn 38 4.10 TarCaMfwaiaa 0»yaai Systrai 40 4.11 TrawlH i iia 0«»aanae» aal fjxyadftdts 40 4.12 Uaduaar Acaadt Hydrowda 41 4.13 Bccmmrmmi&tKWnMm&bmitivnm\<>tOmmmt:f,Es m*atwil*t 41 4.14 Effect of Ti ay* i lit oa a* SdfLaaarsccacc of SrCl, Doped «i* •**Cm<xliyts Okamooaof HurtDefect Eaaana 42 4.15 SttoKmUL-Maianmniy tjfltmmim^tkmtmimiCiimrimnii 42 4.16 Etectrocaaaal awl Spectroscopic Sfdas of Tianaiaa. Specas • 417 Searca for Palo aan Ftaoreeuau 44 5. fMVWtCNKESTM tHtMBHV 5.1 Traaams w Fata-Oxyarft-Oroar Sysanas fteacnoa of Of ID) AIOHB tri* CF,C1: 45 Water ObdWrprd from PowerPbatCniifcaj Syswaa 46 5J Claaariiy crfSatfaradaAiawadiMt . 46 *. si^ARATioi^cmxmntY 6 I SpectroplKwoaatnc Studai of SotoeowCowuaa»|ltwlin>*.ir«t •laternb 4* 6.1.1 Pfcotocamatry of Aiawnas Fwnuaaai Soatiow 4ft 6.1.2 Catawstry of Faaoa Prodacts a Carbon Dnudr «9 6.2 Macroporoas todies Fdkd ank Oxides and Salfafcs at Ad»rbeais 49 6.3 •raerktitio* of rVMograpluc Wastes 50 6.4 Aajnn tatfciaar Adatrptka of Inmatmm EJoaeati froa TMoadfrte Sototioas 51 65 Advanced Filtration Aapataticasof Energy Sajaifkatce S2 6.6 taaVltaotaioa Separaonm 55 6.7 New Separations Apmis 55 V 7. KUClEAftOKMSntY 7 1 OKMr^^emtt mi LX*MfUamRcMmm a( tiamtm2*9nS -- S? 7 2 XJta> Uemm6cj»mmm4 Deem ftapen^ of kmitofei of L»\ ILMTW 5* 7J SVK*CTB and Attnapttd X*ay Mrntjfcoition of Onmem 106 Uang *ehohjpeI%,Un> $9 74 AFjaT^tTn^panAwMUyfbrShon-liMrilieOTy-BaMMNwMcs r»o4u4j(Oiur to 75 Mr»»M—ioT*eBa:iwC^<wt»ra»dior*ePcia»otf2><Wo 61 7.6 AlttMp*4rta4Mctnaar:'*l04 62 7 7 Transfer R.^iom Thai Lead to nVN»Jei"'Cr and-'MTf 63 7H NeOTMMMn(LitnKsofSbiaMiDK.«TWIa4a,',Yt 63 79 InVtnnn of twnVSfni Rotation^ Staann^" ft *ynV PnpakiShaft Revnn^PistanCT Method .... 64 710 Ufeum*Hium*mim> m*Mit*tl Cimiim*txai*tmmm,*zD\ 66 711 Qe*wm**mrMmuuii»(4KCh»peDau*m*ammi4KOpuai fMrraal for SUNT Rjtr Lir* Nwlei 67 7 12 FiOiwiihc 162 MtV^'Nct •*•*<!•!of ?M 67 ~.l 3 Hra»>*ni-lndnccd Fan— and Fnsw of Mi n— Mam Smda 68 7 13.1 ,:C and :*Se Ions 6S 7.13.2 **Af««*4Kf km 69 7 |4 C»*>ponnd NncleitsReactions Mated b> **Ar «i* '**!>%. '*4D>. awl,,4Yl» 70 ".IS MnfcnuiLlron Transfer React»n»wnh4*Ar »amj 71 7 l* Hrjv>4»n MnftnNrieon-Transfcr Reactions io ACCOMMMI 72 7 |7 Vlnn MnllndKitv Conatrr w* Improved Efficiency .. 73 "M* Spontaneous Ftssson * Munwnc OKS . 73 7 |9 Nevtron Mntanht am • Natural Sampler 73 7 20 Vatroa MufeipHciaes m Fractions ham Lead mi Zmzmmm Ore rVvessmr. 74 7 21 How m Detect Hit Heanest Mai Made Isotopes 75 7 22 Measurement of me Ncucn* Fission CrossSection for " 'Cm LsnwTmr^f-FhnfciTechmanes 75 723 The Seutr.w Capture Cross Section of "StoS50keV 76 724 TheNevtronCapfnfeCrossSection of "Nito 13keV 7* 7.!5 Mrawemnii on *r22«Vl>«blrlMike1>}Th(it.Tr1,>Th Reaction 79 7.26 £T>f 2 Transition Strengths and Interpretations of 0*. 2*Slatesm,T,Hf SO 7.27 Low-Intensity tela Transition in the Decay of **Tc f I 728 "'NdDrcay and the °* Ft Ground SU!« Spin H2 729 Decay of "'Pb 82 7.30 Pnmordial Radinelemeni and Cosmoarnk Radioetetneni Distributions in Luna* Samples from Descartes and Tauras-litirow 63 a OaCANCOEMBTVYCATALYSS. AND COAL RESEAKll si Kfgiiii — M.if*c44tniM<MHytC»iw 85 8.2 AS^ofHtdndrSh^muW2-NuffcorayftaeMa »5 8.3 TWSv*il»otOiKjaK Conductors »7 8.4 AStuuWVuwiCaucaes *? 8.5 NKk« MafKtic Rnwau bkw*x> 88 86 Coal fTif— fui—iiii 89 8.7 fttwin of uteRguwalof HnnwHwatwC^ 89 8.8 nfeactsom of ffc^tofmnafCaiaKsttunut Wales Vapor . 40 89 MofMt-SaJtCatjMts . 90 8.10 Topodir—jt.> of durCataKsr* of uw? Hydropntatwu of Caefcon »> SicfcH 91 8 11 CoaajMer f»iyu lor Saaataaag a Mrdttaation » J«K and a Mr diuw-Steam Reformer 91 •. MOfYSKAL UutMaMKV 9 1 Sniflet EXCMIOB Traasfa few Poh f A fc> Bound Dvr * 77** 93 9.2 Tfceurt of Eidttd-Siaie iMeracHnns m hwkab Ayrpia 94 M. OKMKAtniVSCS 10.1 Structural Otessstrx 9« 10 I I Computer Simulation of lupwdSuduw 96 10 I 2 Amorphous S»M Water . 9s 10 13 Seutroa fttTrjcoon Stmhe* of Tfctf Hydratesof Fmijphntimtjtit Acid 97 10.1 4 Terror) Structural Mtereaccs benwm Mtcrohral Sermr Proteases and me Paacreatit Serme Eaiymes 98 10 1.5 Aa AtjEbrat/ Meamd for AaaK/mf Latae Rearrangement Seunxk* of Isomeric Mokvm>v 98 10.16 The Crystal and M-decufar Structure of aV Compiei of Plalmum Dbwfcdc mm the Puner of Pnaiii*.m laceume 99 10.1 7 A Neutron Diffraction Sv»t, ofuW I I Molecular Cnmpk* .if 7.7X8Jmacyanoi|uuiiwlunrfnav wr* p-Terpheavl 100 10.1 8 The Structure ofSaxitoxm A Test of Impcoiul Method* fat $-*mc me flttK ProMem 101 10.1 9 Strangr New Orfpmc Conductors The TetratlmifBlvaknc Halogen Complexes IOC 10.1.10 Xrufron Structural Sntdin RcbktJ to 0*m«w: Reactions 103 10.2 Atomic and Molecular C OJRMORS 105 10.2 1 Crossed Molrcular bam 5tua^ of the Reactinas of UF» wi* Alum Atoms 105 10.22 Surface Reac lints and tanpatmn of UF» I Oh 10.2.3 Hyper- and Pi*ar Cnamtdm* ofChargr-Sufe Selected 27.5-MrV Oxygen Ions iaSihvr 106 10.2.4 Electron Emission from Fast Oxygen and Copper lam Energjng from Tkin Gold Crystals m Channeled and Random Directions 107 •0.2.5 Crossed Molecular Beam Studies of Excited Atom Reactions 108 I© 3 mx*mmr mi tUmffmmmcy Smxtnmcam MUM Ckemmtn. mi UmmmmOmmutty . I0» 10.3.1 UtctnmSrmttnmmetSmixiailimiiiDvnm. Ffcr-*»vm **•** 109 10 3 2 SJecrai Spa ttemmmoe 5taak* oOJfctrrocydbc Kompamma m immto IMHMJ raoMnrss Ifc-fVfiBMi aiLMfcoKyhc Aai 110 !0.3 3 EkKtriwi Sf fcwaact Si fc n of ,V-HneracydK COHMNNJMH « bands Dana* K«4v* rVnaaKCa*wyi*eAaaNB Ill 10.3.4 T«Meafe»*rH,OCOCrl.-fl: Smew Ill 10.3 5 atoaaar FMMM • me RaawHas of Aaa* MI Iwaade kaStaM»*» 112 111 Uectf«iAea»^BcbsnnrofCo«r4eiAc«^#kiOTrMri^^lKti«Kw SnKw 114 112 Oe*t*m^*w0kmer»du4Bc4Sm*iUt£tHmr IIS 11.3 fchxUfdieaiial Hwrno at SwMwk Retmw 116 114 rm^lm)Kmftoatamd\mwi+rxke*+t4Bccuc4n 116 11 5 MeclrodKmcal Recover* a* RrdaL'.afc hmpM.