MINERALOGIA – SPECIAL PAPERS Volume 39, 2012 nd The 2 Conference organized by the Geochemical Group of the Mineralogical Society of Poland Kielce, Sept. 24–26, 2012 The 11th Geochronological Conference ”Dating of Minerals and Rocks XI” Kielce, Sept. 26–27, 2012 Abstracts, excursion and field session guide KIELCE, SEPTEMBER 24-27, 2012 Mineralogia – Special Papers formerly Mineralogia Polonica – Special Papers Editor of the series – Marek MICHALIK Institute of Geological Sciences, Jagiellonian University 30-063 Kraków, Oleandry 2a, Poland [email protected] Editors of Volume 39: Zdzisław M. MIGASZEWSKI and Agnieszka GAŁUSZKA Geochemistry and the Environment Div., Institute of Chemistry, Jan Kochanowski University in Kielce [email protected], [email protected] Stanisław HAŁAS Mass Spectrometry Laboratory, Institute of Physics, Maria Curie-Skłodowska University in Lublin [email protected] Technical Editors: Agnieszka GAŁUSZKA, Zdzisław M. MIGASZEWSKI and Stanisław HAŁAS Jan Kochanowski University in Kielce & Maria Curie-Skłodowska University in Lublin The 2nd International Conference “Contemporary Problems of Geochemistry” and the Conference “Dating of Minerals and Rocks XI” were organized by the Geochemical Group of the Mineralogical Society of Poland and this issue of “Mineralogia – Special Papers” was financially supported by sponsors: Bruker Polska, Hydrogeotechnika Sp. z o.o. Kielce, Precoptic Co. – Nikon Mikroskopy Polska, Perkin Elmer Polska Sp. z o.o. ISSN: 1899-8518 Printed: Wydawnictwo Naukowe „Akapit”, Kraków tel./fax (012) 280-71-51; kom. 608 024 572 e-mail: [email protected]; www.akapit.krakow.pl The 2nd International Conference “Contemporary Problems of Geochemistry” & The Conference “Dating of Minerals and Rocks XI” organized by Mineralogical Society of Poland together with Jan Kochanowski University in Kielce Mass Spectrometry Laboratory of Maria Curie-Skłodowska University in Lublin KIELCE, SEPTEMBER 24-27, 2012 Contemporary Problems of Geochemistry – Organizing committee: Chairman: Zdzisław MIGASZEWSKI - Jan Kochanowski University in Kielce Vice-chairman: Agnieszka GAŁUSZKA - Jan Kochanowski University in Kielce Members: Ryszard KRYZA - University of Wrocław Marek MICHALIK - Jagiellonian University in Kraków Beata STOŻEK - Jagiellonian University in Kraków Secretary: Sabina DOŁĘGOWSKA - Jan Kochanowski University in Kielce Artur MICHALIK - Jan Kochanowski University in Kielce Anna RADZIMOWSKA - Jan Kochanowski University in Kielce Dating of Minerals and Rocks XI – Organizing committee: Chairman: Stanisław HAŁAS - Maria Curie-Skłodowska University in Lublin Vice-chairmen: Zdzisław MIGASZEWSKI - Jan Kochanowski University in Kielce Agnieszka GAŁUSZKA - Jan Kochanowski University in Kielce Members: Maciej CZARNACKI - Maria Curie-Skłodowska University in Lublin Ryszard KRYZA - University of Wrocław Marek MICHALIK - Jagiellonian University in Kraków Tomasz PIEŃKOS - Maria Curie-Skłodowska University in Lublin Beata STOŻEK - Jagiellonian University in Kraków Artur WÓJTOWICZ - Maria Curie-Skłodowska University in Lublin Secretary: Sabina DOŁĘGOWSKA - Jan Kochanowski University in Kielce Artur MICHALIK - Jan Kochanowski University in Kielce Anna RADZIMOWSKA - Jan Kochanowski University in Kielce SPONSORSHIP ul. Budziszyńska 69 60-179 Poznań tel. +48-61-8689008, fax +48-61-8689096 25-116 Kielce ul. Ściegiennego 262A tel.: +4841 348 06 60 fax: +4841 348 96 00 e-mail: info@hydrogeotechnika Perkin Elmer Polska Sp. z o.o. ul. Wołoska 9, Warszawa tel. 22 310 88 00, fax 22 310 88 01 PRECOPTIC Co. The Eyes of Science NIKON MIKROSKOPY POLSKA 01-934 Warszawa, ul. Arkuszowa 60 Tel/fax (22) 835 54 73,CONTENTS 834 12 25 adres e-mail: [email protected] www.precoptic.pl TABLE OF CONTENTS Ryszard KRYZA Preface ............................................................................................................................ 13 Contemporary Problems of Geochemistry INVITED LECTURES Khageshwar S. PATEL, Yogita NAYAK, Raj K. PATEL, Harald SAATHOFF, Jutta LINTELMANN, Georg MATUSCHEK Black carbon and polycyclic aromatic hydrocarbon pollution in India .......................... 17 Ruth E. WOLF, Andrew S. TODD, Suzette A. MORMAN, Todd M. HOEFEN, Philip L. HAGEMAN, Geoffrey S. PLUMLEE Using ICP-MS to decipher biogeochemical processes: speciation and isotope doping case studies ..................................................................................................................... 19 ORAL AND POSTER CONTRIBUTIONS Anna BARAN, Andrzej PELC, Stanisław CHMIEL, Stanisław HAŁAS Origin of saline waters in the vicinity of Rzeszów in the light of isotope (δ18O, δD, δ13C, δ37Cl) and hydrochemical studies ........................................................ 25 Piotr BOŻĘCKI, Grzegorz RZEPA, Przemysław RZEPKA Preliminary results of neutralization of AMD waters from selected reservoirs in the Muskau Arch near Łęknica, W Poland ........................................................................... 26 Jakub CIĄŻELA, Torsten BOLTE, Francois HOLTZ, Andrzej MUSZYŃSKI, Katarzyna MACHOWIAK The effect of water activity on the eutectic point in natural granitic system .................. 28 Kamil CZECH, Magdalena GARNUSZEK, Dariusz WIDEŁ Application of selected modified halloysite adsorbents for ammonia adsorption determined by capillary electrophoresis method ............................................................ 30 Zbigniew CZUPYT, Stanisław CHMIEL, Stanisław HAŁAS Cavity Ring Down Spectrometry: an alternative to Isotope Ratio Mass Spectrometry .. 33 Sabina DOŁĘGOWSKA, Artur MICHALIK Anomalous concentrations of rare earth elements in mosses and soils from the Kielce region (south-central Poland) ......................................................................................... 35 Agata DUCZMAL-CZERNIKIEWICZ, Stanisław HAŁAS, Beata GEBUS, Zbigniew CZUPYT Stable isotope record of carbonates from the Poznań Formation ................................... 38 Agnieszka GAŁUSZKA, Zdzisław M. MIGASZEWSKI Arsenic in waters of the Podwiśniówka area: geochemical and environmental considerations ................................................................................................................. 41 Beata GEBUS, Zbigniew CZUPYT, Stanisław HAŁAS Simultaneous preparation of N2 and CO2 for stable isotope analysis from nitrate samples ........................................................................................................................... 44 Beata GEBUS, Stanisław HAŁAS Micro ion selective electrodes – an alternative for nitrate/nitrite precision concentration measurements .......................................................................................... 46 Maciej GÓRKA, Dominika LEWICKA-SZCZEBAK, Roland FUß, Mariusz-Orion JĘDRYSEK One-year spatial and temporal monitoring of concentration and carbon isotopic composition of atmospheric CO2 and CH4 in urban area (Wrocław, SW Poland) ......... 47 Stanisław HAŁAS, Józef DĄBEK, Adrian PACEK Lithium isotope analysis in waters and sediments .......................................................... 49 Miłosz HUBER, Stanisław HAŁAS Ore minerals characterization and stable sulfur isotopes from Broken Hammer, Sudbury .......................................................................................................................... 50 Jakub KIERCZAK, Artur PĘDZIWIATR, Jarosław WAROSZEWSKI Distribution and bioavailability of Ni and Cr in serpentine soils from Lower Silesia – preliminary results .......................................................................................................... 52 Dorota KOWALIK-KOCISZEWSKA, Ryszard KRYZA, Jacek ĆWIĄKALSKI Historical sandstone epitaphs from Lower Silesia (SW Poland): preliminary results of petrographic investigations ........................................................................................ 53 Jakub MATUSIK, Tomasz BAJDA Kaolinite-based sorbent of hexavalent chromium: sorption mechanism, pH effect and desorption behaviour ............................................................................................... 55 Artur MICHALIK, Sabina DOŁĘGOWSKA Rare earth elements distribution in spring waters of Świętokrzyski National Park, Poland ............................................................................................................................. 57 Zdzisław M. MIGASZEWSKI, Agnieszka GAŁUSZKA, Andrzej MIGASZEWSKI REE concentrations in well and pond waters of the Podwiśniówka area (Holy Cross Mountains, south-central Poland) ................................................................................... 59 Zdzisław M. MIGASZEWSKI, Agnieszka GAŁUSZKA, Karina KRZCIUK LA-ICP-MS study of selected trace element distributions in pyrite from the Podwiśniówka quarry, Holy Cross Mts (south-central Poland) ..................................... 61 Khageshwar S. PATEL, Yogita NAYAK, Nitin K. JAISWAL, Raj K. PATEL, Matini LAUTENT, Laura BORGESE, Alessandra GIANONCELLI, Elza BONTEMPI Heavy metal pollution of Indian sediment ..................................................................... 63 Katarzyna PIETRZYKOWSKA, Marta PRELL, Ryszard KRYZA Świny Castle (Sudetes, SW Poland): a natural laboratory to study lichenological- lithological interrelationships ......................................................................................... 65 Marta PRELL, Katarzyna PIETRZYKOWSKA, Ryszard KRYZA Petrography, deterioration and lichenology of sandstones from the Pomorski bridge in Wrocław and old Płakowice quarry (a comparative study) .......................................