The Kondo Effect and Conformal Field Theory

The Kondo Effect and Conformal Field Theory

The Kondo Effect and Conformal Field Theory Alexander B. Atanasov∗ and Andrew K. Saydjari Harvard University Dept. of Physics 1 The Kondo Effect and RG It is an experimentally known fact that classes of metals with magnetic impurities exhibit a minimum resistivity at a certain temperature TK , below which the resistivity begins to rise. The existence of this minimum is, on its face, paradoxical, as standard phonon theory in metals predicts that the resistivity should be a monotonically increasing function of temperature. Moreover, this minimum temperature does not depend on the concentration of the impurities, so it is not due to electronic correlation between neighboring impurities, but must rather be due to the scattering effect between the electrons and the magnetic impurity. Kondo proposed a model in 1964 that reproduced this effect, and so it has since been known as the Kondo effect. It can be described be the following Hamiltonian: β X α X α ~σα H = y (k) (k)(k) + λS~ · y (k) (k) (1) α 2 β k,α k;k0 The simple Drude model of conductance gives a resistivity in the presence of a single impurity as: m m ρ(T ) = 2 = 2 Γ(F ): ne τDrude ne Here τDrude is the single-particle transport life-time. It is related to the inverse of the scattering rate Γ for an electron at the fermi energy F . Since the scattering rate is proportional to angular integrate matrix element of the T matrix, we see that the scattering matrix determines the resistivity. The Kondo effect comes from the renormalization of the propagator. The contributing diagrams involve spin flips, as is explained in detail in [1]. The contributing Feynman diagrams are below. Here, τ is the opposite spin from σ. From integrating out the high-energy modes, we obtain a beta function of β(λ) = −νλ2 where ν is the density of states. This gives us that λ runs as λ0 λeff = (2) log(T=TK ) −1/νλ Here D is the UV cutoff for the bandwidth: jk − kF j < D. This gives TK to be on the order of De 0 . This calculation was done by Kondo, giving the correct temperature at which perturbation theory breaks down. To be able to describe the full non-interacting picture, we need the full mechanics of Wilson's numerical renormalization scheme. However, from the more modern perspective of understanding field theories as flows from UV to IR fixed points, we can develop our understanding of the Kondo problem (and even calculate relvant low-temperature quantities) in terms of the 2D conformal field theory at T = 0. 1 2 Reduction to 1+1 Dimensions The following 4 sections will summarize the analysis and results of [2]. Note that near the Fermi energy (k) ≈ vF (k−kF ). Since we are looking at only s-wave scattering, consider the equivalent one dimensional problem. 1 (k) ! p 0(k) 4πk Z y H0 = vF dk(k − kF ) 0(k) 0(k) Z y = vF dkk 0(k + kF ) 0(k + kF ) Z ~σ H = λv ν dkdk0 y(k) (k) int F 0 2 0 R ikr R −ikr We can then write L = dke 0(k + kF ) for an incoming wave and R = dke 0(k + kF ) for an outgoing wave. These sum together to give the full position space Fourier transform of . We then get: v Z 1 @ @ H = F dr y (r)i (r) − y (r)i (r) 0 2π L @r L R @r R 0 (3) Z ~σ ~σ H = λv ν dkdk0 y(k) (k) = v νλ S~ · y(0) (0) int F 0 2 0 F 2 Since L;R(r; t) are defined only for r positive, we can define L(z = τ + ix) = L(x; τ) ∗ (4) R(z = τ − ix) = R(x; τ): for τ imaginary time. Further, because these must agree at x = 0, we can write everything in terms of L with L(−x; τ) := R(x; τ). Then we can write v d H = f y i : (5) 0 2π L dx L This 1+1D free fermion theory is in fact conformally-invariant (i.e. a CFT). The two-point functions can easily be computed as: y 1 1 ∗ y 1 1 h L(z) L(0)i = ; h R(z ) R(0)i = ∗ vF z vF z We will set vF = 1 and rescale νλ ! λ for future discussion. We can also now write the full 1+1D Hamiltonian as a lattice model as: X ~σ H = t ( y + y ) + λ S~ · y (6) i i+1 i+1 i 0 2 0 i At λ = 0, this free fermion model has even and odd parity wave functions going as cos kx and sin kx, respectively. On the other hand, if we make the interaction term large λ t, the electron at the origin will want to do everything possible to ensure that the state at the origin is a singlet. Thus, the ground state will be a singlet at 0, and fluctuations away from 0 are allowed, so long as particles and holes do not interfere with the singlet state at the origin. 2 3 The role of CFT The CFT side of the picture emerges from the free electron model by defining the current density operator in terms of the normal order of the field. y y J(x − t) = : L : ≡ lim L(x) L(x + ) − h0j (x) L(x + ) j0i : (7) L !0 L This in turn satisfies an OPE: d : J(x)J(x + ) := 2i : y(x)i (x): (8) dx But this is just the free theory Hamiltonian, so (up to an infinite constant), we get: 1 H = J 2: (9) 4π It is here, in this surprisingly trivial setting, that we begin to see an affine algebra structure begin to emerge. If we add spin indices to , we get two current densities, corresponding to charge and spin: β yα yα ~σα J =: α :; J~ =: : β α β α d :J 2 : =: y y : +2i y (10) α β dx α 3 α β 3i α d :J~2 : = − : y y : + y 4 α β 2 dx α These can be directly seen to satisfy commutation relations: d [J(x);J(y)] = 4πi δ(x − y) dx d [J a(x);J b(y)] = 2πiabcJ c(x)δ(x − y) + πiδab δ(x − y) dx (11) [J(x); J~(y)] = 0 1 1 )H = J 2 + J~2 : 8π 6π | {z } | {z } Hc Hs We thus can express the Hamiltonian in terms of two commuting conserved charges. This is the important point, as it allows us to decouple the \charge" from the \spin" degrees of freedom. We write H = Hc +Hs. a 1 R l inπx=l a In terms of Fourier modes Jn ≡ 2π −l e J (x), this gives: 1 [J a;J b ] = iabcJ c + nδ : (12) n m n+m 2 n;−m 1 This is the affine SU(2) Kac-Moody algebra of level k = 1, denoted SU\(2)1. Note that this gives 1 π X H = :J~ J~ : : (13) s 3l −n n n=−∞ 1For some reason some literature calls k the central charge, which is not consistent with other more usual definitions of the true Virasoro central charge c. 3 4 Boundary Conditions and Strong-Weak Fixed Points In the last section, we expressed the free fermion theory in terms of a SU(2) Kac-Moody algebra at k = 1. The boundary conditions on the free theory at x = ±l are that (l) = − (−l). This gives a spectrum π 1 1 k = (n + ) + (n + ) (14) l " 2 # 2 For a charge Q = Q" + Q# state we get an energy of: 1 πV 1 1 X E = [ Q2 + Q + m(n" + n# )]; (15) l 2 " 2 # m m m=−∞ where the last term corresponds to excitations gained from raising nm electrons up m levels, and is zero for the ground state. The boundary conditions determine the spectrum and couple the Q and Sz quantum numbers so that Q = 2Sz mod 2: (16) This means that, in terms of representations of the KM algebra, the states must be obtained by applying a appropriate raising operators (J−n) to the ground states that are either even charge integer spin or odd charge half-integer spin. The total Hilbert space is the sum of two irreducible representations of SU\(2)1 (known as \conformal towers" in the literature): (even; integer) ⊕ (odd; half-integer): It is quick to see that if we have the opposite boundary conditions, (l) = (−l), corresponding to the phase-shifted case at the interacting fixed point, we'd get the reverse boundary conditions: (even; half-integer) ⊕ (odd; integer): The fact that the interacting fixed point can be written as a free fermion theory with different boundary conditions leads one to consider whether we can obtain another Kac-Moody algebra in the perturbed hamiltonian: β α d α ~σ 1 1 H = y i + λψy α · S~ δ(x) = J 2 + J~2 + λJ~ · S~ δ(x) (17) dx α 2 β 8π 6π This is just a perturbation of the spin Hamiltonian, which can be written in Fourier space as: 1 ! πV X 1 H = J~ · J~ + λJ~ · S~ s l 3 −n n n n=−∞ It looks like at λ = 2=3, this factors into (up to an irrelevant constant): 1 πV X H = (J~ + S~) · (J~ + S~) 3l −n n n=−∞ Defining J~n = J~n + S~, we get an algebra satisfying the exact same commutation relations, but with J~ instead of J~.

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