This is “Molecules, Ions, and Chemical Formulas”, chapter 2 from the book Principles of General Chemistry (index.html) (v. 1.0). This book is licensed under a Creative Commons by-nc-sa 3.0 (http://creativecommons.org/licenses/by-nc-sa/ 3.0/) license. See the license for more details, but that basically means you can share this book as long as you credit the author (but see below), don't make money from it, and do make it available to everyone else under the same terms. This content was accessible as of December 29, 2012, and it was downloaded then by Andy Schmitz (http://lardbucket.org) in an effort to preserve the availability of this book. Normally, the author and publisher would be credited here. However, the publisher has asked for the customary Creative Commons attribution to the original publisher, authors, title, and book URI to be removed. Additionally, per the publisher's request, their name has been removed in some passages. More information is available on this project's attribution page (http://2012books.lardbucket.org/attribution.html?utm_source=header). For more information on the source of this book, or why it is available for free, please see the project's home page (http://2012books.lardbucket.org/). You can browse or download additional books there. i Chapter 2 Molecules, Ions, and Chemical Formulas Chapter 1 "Introduction to Chemistry" introduced some of the fundamental concepts of chemistry, with particular attention to the basic properties of atoms and elements. These entities are the building blocks of all substances we encounter, yet most common substances do not consist of only pure elements or individual atoms. Instead, nearly all substances are chemical compounds or mixtures of chemical compounds. Although there are only about 115 elements (of which about 86 occur naturally), millions of chemical compounds are known, with a tremendous range of physical and chemical properties. Consequently, the emphasis of modern chemistry (and this text) is on understanding the relationship between the structures and properties of chemical compounds. Petroleum refining. Using chemicals, catalysts, heat, and pressure, a petroleum refinery will separate, combine, and rearrange the structure and bonding patterns of the basic carbon-hydrogen molecules found in crude oil. The final products include gasoline, paraffin, diesel fuel, lubricants, and bitumen. 123 Chapter 2 Molecules, Ions, and Chemical Formulas In this chapter, you will learn how to describe the composition of chemical compounds. We introduce you to chemical nomenclature—the language of chemistry—that will enable you to recognize and name the most common kinds of compounds. An understanding of chemical nomenclature not only is essential for your study of chemistry but also has other benefits—for example, it helps you understand the labels on products found in the supermarket and the pharmacy. You will also be better equipped to understand many of the important environmental and medical issues that face society. By the end of this chapter, you will be able to describe what happens chemically when a doctor prepares a cast to stabilize a broken bone, and you will know the composition of common substances such as laundry bleach, the active ingredient in baking powder, and the foul- smelling compound responsible for the odor of spoiled fish. Finally, you will be able to explain the chemical differences among different grades of gasoline. 124 Chapter 2 Molecules, Ions, and Chemical Formulas 2.1 Chemical Compounds LEARNING OBJECTIVE 1. To understand the differences between covalent and ionic bonding. The atoms in all substances that contain more than one atom are held together by electrostatic interactions1—interactions between electrically charged particles such as protons and electrons. Electrostatic attraction2 between oppositely 1. An interaction between charged species (positive and negative) results in a force that causes them to move electrically charged particles toward each other, like the attraction between opposite poles of two magnets. In such as protons and electrons. contrast, electrostatic repulsion3 between two species with the same charge 2. An electrostatic interaction (either both positive or both negative) results in a force that causes them to repel between oppositely charged each other, as do the same poles of two magnets. Atoms form chemical compounds species (positive and negative) when the attractive electrostatic interactions between them are stronger than the that results in a force that causes them to move toward repulsive interactions. Collectively, we refer to the attractive interactions between 4 each other. atoms as chemical bonds . 3. An electrostatic interaction between two species that have Chemical bonds are generally divided into two fundamentally different kinds: ionic the same charge (both positive or both negative) that results and covalent. In reality, however, the bonds in most substances are neither purely in a force that causes them to ionic nor purely covalent, but they are closer to one of these extremes. Although repel each other. purely ionic and purely covalent bonds represent extreme cases that are seldom 4. An attractive interaction encountered in anything but very simple substances, a brief discussion of these two between atoms that holds them extremes helps us understand why substances that have different kinds of chemical together in compounds. bonds have very different properties. Ionic compounds5 consist of positively and 5. A compound consisting of negatively charged ions held together by strong electrostatic forces, whereas 6 7 positively charged ions covalent compounds generally consist of molecules , which are groups of atoms (cations) and negatively in which one or more pairs of electrons are shared between bonded atoms. In a charged ions (anions) held covalent bond8, the atoms are held together by the electrostatic attraction between together by strong electrostatic forces. the positively charged nuclei of the bonded atoms and the negatively charged electrons they share. We begin our discussion of structures and formulas by 6. A compound that consists of describing covalent compounds. The energetic factors involved in bond formation discrete molecules. are described in more quantitative detail in Chapter 8 "Ionic versus Covalent 7. A group of atoms in which one Bonding". or more pairs of electrons are shared between bonded atoms. 8. The electrostatic attraction between the positively charged nuclei of the bonded atoms and the negatively charged electrons they share. 125 Chapter 2 Molecules, Ions, and Chemical Formulas Note the Pattern Ionic compounds consist of ions of opposite charges held together by strong electrostatic forces, whereas pairs of electrons are shared between bonded atoms in covalent compounds. Covalent Molecules and Compounds Just as an atom is the simplest unit that has the fundamental chemical properties of an element, a molecule is the simplest unit that has the fundamental chemical properties of a covalent compound. Some pure elements exist as covalent molecules. Hydrogen, nitrogen, oxygen, and the halogens occur naturally as the diatomic (“two atoms”) molecules H2, N2, O2, F2, Cl2, Br2, and I2 (part (a) in Figure 2.1 "Elements That Exist as Covalent Molecules"). Similarly, a few pure elements are polyatomic9 (“many atoms”) molecules, such as elemental phosphorus and sulfur, which occur as P4 and S8 (part (b) in Figure 2.1 "Elements That Exist as Covalent Molecules"). Each covalent compound is represented by a molecular formula10, which gives the atomic symbol for each component element, in a prescribed order, accompanied by a subscript indicating the number of atoms of that element in the molecule. The subscript is written only if the number of atoms is greater than 1. For example, water, with two hydrogen atoms and one oxygen atom per molecule, is written as H2O. Similarly, carbon dioxide, which contains one carbon atom and two oxygen atoms in each molecule, is written as CO2. Figure 2.1 Elements That Exist as Covalent Molecules 9. Molecules that contain more than two atoms. 10. A representation of a covalent compound that consists of the atomic symbol for each component element (in a prescribed order) accompanied by a subscript indicating the number of atoms of that element in the molecule. The subscript is written only if the number is greater than 1. 2.1 Chemical Compounds 126 Chapter 2 Molecules, Ions, and Chemical Formulas (a) Several elements naturally exist as diatomic molecules, in which two atoms (E) are joined by one or more covalent bonds to form a molecule with the general formula E2. (b) A few elements naturally exist as polyatomic molecules, which contain more than two atoms. For example, phosphorus exists as P4 tetrahedra—regular polyhedra with four triangular sides—with a phosphorus atom at each vertex. Elemental sulfur consists of a puckered ring of eight sulfur atoms connected by single bonds. Selenium is not shown due to the complexity of its structure. Covalent compounds that contain predominantly carbon and hydrogen are called organic compounds11. The convention for representing the formulas of organic compounds is to write carbon first, followed by hydrogen and then any other elements in alphabetical order (e.g., CH4O is methyl alcohol, a fuel). Compounds that consist primarily of elements other than carbon and hydrogen are called inorganic compounds12; they include both covalent and ionic compounds. In inorganic compounds, the component elements are listed beginning with the one farthest to the left in the periodic table (see Chapter 32 "Appendix H: Periodic Table of Elements"), such as we see in CO2 or SF6. Those in the same group are listed beginning with the lower element and working up, as in ClF. By convention, however, when an inorganic compound contains both hydrogen and an element from groups 13–15, the hydrogen is usually listed last in the formula. Examples are ammonia (NH3) and silane (SiH4). Compounds such as water, whose compositions were established long before this convention was adopted, are always written with hydrogen first: Water is always written as H2O, not OH2.