Table of Contents 29 CHEMICAL STANDARDS Neats and Single-component Solutions 2 International Standards 123 Canada . .................................................. 123 Chemical Services & Products 19 European Mixes ............................................. 126 Custom Chemical Services ..................................... 19 Korean Drinking Water Regulations . ........................... 127 Reference Material Repackaging Services .......................... 19 Certification and Documentation ................................ 19 Food & Beverage Standards 127 Separate Source Products Meet US EPA Requirements ............... 19 Natural Products ............................................ 127 Certified Reference Materials .................................... 19 Antimicrobials/Preservatives ................................... 129 Antioxidants ................................................ 130 Air Monitoring Standards 21 Carbohydrates/Organic Acids/Sugar Alcohols ...................... 130 NIOSH and OSHA Methods for Workplace Atmospheres .............. 21 Flavenoids/Polyphenols . ...................................... 130 American Society for Testing and Materials (ASTM) Methods .......... 22 Food Dyes ................................................. 131 California Air Resources Board (CARB) Methods ..................... 23 Food Packaging Material Residues . ........................... 132 DNPH Carbonyl Derivatives ..................................... 24 Lipids/FAMEs ............................................... 132 DAIH Carbonyl Derivatives ..................................... 25 Mycotoxins ................................................. 140 Oxime Carbonyl Derivatives .................................... 25 Sweeteners ................................................. 142 Isocyanate monomer DBA derivatives ............................ 26 Vitamins . .................................................. 143 Multi-purpose Solutions . ....................................... 26 Japanese Indoor Air Methods ................................... 27 Petroleum Standards 143 U.S. EPA Indoor Air Pollutant Methods ............................ 28 ASTM Petroleum Standards .................................... 143 U.S. EPA Toxic Organic Air Monitoring Methods .................... 29 Biofuel Standards ............................................ 149 Gas Calibration Standards ...................................... 37 PNA/PONA/P-I-A-N-O Standards ................................ 150 Environmental Standards 40 Pharmaceutical Standards 152 Proficiency Testing ............................................ 40 Secondary Pharmaceutical Standards . ........................... 152 Drinking Water Methods ....................................... 47 USP Residual Solvent Standards ................................ 156 Wastewater Methods . ....................................... 60 Solid Waste, Groundwater Methods . ............................ 70 CLP Standards ............................................... 92 UST/GRO/DRO ............................................... 94 Flame Retardant Standards ..................................... 97 PCB Standards ............................................... 97 Pesticide Mixtures ............................................ 99 Pesticide Neats and Solutions ................................... 99 AUTHORIZED DISTRIBUTOR MZ-Analysentechnik GmbH, Barcelona-Allee 17• D-55129 Mainz Tel +49 6131 880 96-0, Fax +49 6131 880 96-20 e-mail: [email protected], www.mz-at.de For all of your analytical needs, visit us at sigma-aldrich.com/analytical To order, visit sigma-aldrich.com/order 2 Chemical Standards Neats and Single-component Solutions Neats and Single-component Solutions Sigma-Aldrich offers an extensive line of Fluka and Supelco brand neats and single-component solutions for a variety of applications that include, but are not limited to, environmental, food and beverage, forensics, petrochemical and pharmaceutical analyses. Most of these chemicals are 99% pure. Listed below is just a sampling of the many reference materials available. Please visit sigmaaldrich.com/standards to view our complete product line. Some of these products are classified as hazardous under European Union (EU) legislation. The Risk and Safety (R and S) phrases are listed in the Risk and Safety section at the front of the catalog. Note: Due to the growing importance of pesticide residue analyses, our neat and single-component solution pesticide standards have their own section within the Environmental standards chapter of this catalog. Description Concentration Cat. No. Qty cis-8,11,14-Eicosatrienoic acid methyl ~0.1 g/mL in ethanol - 00813-1ML-F 1mL ester solution Acenaphthene - - 48500-U 5000 mg Acenaphthene-d10 solution 2000 μg/mL in methanol - 48093 1mL Acenaphthene-d10 solution 2000 μg/mL in methylene chloride - 48417 1mL Acenaphthylene - - 48566 100 mg Acepromazine-d6 hydrochloride - - 32836-10MG 10 mg Acetaldehyde-2,4-DNPH solution 1000 μg/mL in acetonitrile (as aldehyde equivalent) - 47340-U 1mL Acetaldehyde-2,4-DNPH solution 1000 μg/mL in acetonitrile (aldehyde, equivalent) - 4M7340-U 5×1mL Acetoin - - 40127-U 1000 mg Acetone - - 90872-5ML-F 5mL 90872-10ML-F 10 mL Acetone solution 2000 μg/mL in methanol: water (9:1) - 48358 1mL Acetophenone - - 42163-1ML-F 1mL 42163-5ML-F 5mL N8-Acetylspermidine dihydrochloride - - A3658-100MG 100 mg Acrolein - Z 4S8501 100 mg 48501 5g Acrolein - - 5S06230 1g Acrylonitrile solution 5000 μg/mL in methanol - 40003 1mL Albendazole - - A4673-10G 10 g Ambroxol hydrochloride - - A9797-5G 5g 4-Aminoazobenzene - - 46130-250MG-R 250 mg o-Aminoazotoluene - - 31629-250MG 250 mg 1-Aminohydantoin hydrochloride - - 33655-100MG-R 100 mg 13 1-Amino-2,4-imidazolidinedione- C3 - - 34006-10MG-R 10 mg Amoxicillin trihydrate - - 31586-250MG 250 mg AMOZ - - 33349-50MG-R 50 mg AMOZ-d5 - - 33881-10MG-R 10 mg Ampicillin trihydrate - - 31591-250MG 250 mg tert-Amyl methyl ether solution 2000 μg/mL in methanol - 506737 1mL 5-α−Androstane solution 2000 μg/mL in methylene chloride - 48168 1mL 4-Androstene-3,17-dione - - 46033-250MG 250 mg N Androsterone - - 31579-250MG 250 mg Anhydrotetracycline hydrochloride - - 37919-100MG-R 100 mg Aniline - - 51788-1ML-F 1mL 51788-5ML-F 5mL Aniline solution 2000 μg/mL in methanol - 48030-U 1 kit p-Anisaldehyde - - 97063-1ML-F 1mL 97063-5ML-F 5mL Anisole - - 96109-5ML-F 5mL 96109-10ML-F 10 mL Anthracene - - 31581-250MG 250 mg Anthracene - - 48567 5000 mg Anthracene solution 200 μg/mL in methanol - 48647 1mL Anthracene-d10 - - 442456 100 mg Anthracene–d10 solution 2000 μg/mL in methylene chloride - 48863 1mL Antipyrine - - A5882-25G 25 g A5882-100G 100 g A5882-500G 500 g AOZ - - 33347-50MG-R 50 mg AOZ-d4 - - 33880-10MG-R 10 mg L-Arginine hydrochloride solution 100 mM amino acid in 0.1 M HCl - 08163-5ML-F 5mL sigma-aldrich.com/analytical View our current seminar and tradeshow schedule at sigma-aldrich.com/analytical-events Chemical Standards 3 Neats and Single-component Solutions Description Concentration Cat. No. Qty Atenolol-d7 - - 06613-2MG 2mg Azaperone - - 34223-100MG 100 mg Aztreonam - - A6848-50MG 50 mg BDE No 99 solution 50 μg/mL in isooctane - 33676-1ML 1mL Beclomethasone dipropionate - - B3022-250MG 250 mg B3022-1G 1g B3022-5G 5g Behenic acid - - 11909-100MG 100 mg 11909-5G 5g Benzaldehyde - - 09143-5ML-F 5mL 09143-25ML-F 25 mL Benzaldehyde-2,4-DNPH solution 100 μg/mL in acetonitrile (as aldehyde equivalent) - 47343 1mL Benz[a]anthracene - - 48563 100 mg Benz[a]anthracene-d12 - - 442468 10 mg Benz[a]anthracene-d12 solution 2000 μg/mL in methylene chloride - 48789 1mL Benzbromarone - - B5774-1G 1g Benzene - - 12540-5ML-F 5mL 12540-50ML-F 50 mL Benzene - - 48503 5000 mg Benzene solution 200 μg/mL in methanol - CRM48617 Benzene solution 5000 μg/mL in methanol - 40004 1mL Benzene-d6 solution 2000 μg/mL in methanol - 48940-U 1mL Benzidine solution 5000 μg/mL in methanol - 40005 1mL Benzo[b]fluoranthene - - 48490 50 mg Benzo[b]fluoranthene solution 200 μg/mL in methanol - 48637 1mL Benzo[j]fluoranthene solution 2000 μg/mL in methylene chloride - 502332 1mL Benzo[k]fluoranthene - - 48492 50 mg Benzo[k]fluoranthene solution 200 μg/mL in methylene chloride - 48668 1mL Benzo[k]fluoranthene solution 1000 μg/mL in acetone - 40073 1mL Benzoic acid solution 2000 μg/mL in methylene chloride - 47508-U 1mL Benzo[ghi]perylene - - 48491 25 mg Benzo[ghi]perylene solution 200 μg/mL in methylene chloride - 48667 1mL Benzophenone - - 442842 500 mg Benzo[a]pyrene - - 48564 100 mg Benzo[a]pyrene solution 200 μg/mL in methylene chloride - 48665 1mL Benzo[a]pyrene solution 1000 μg/mL in acetone - 40071 1mL Benzo[a]pyrene-d12 - - 442847 10 mg Benzo[e]pyrene - - 442475 25 mg Benzoylecgonine tetrahydrate - - B4147-10MG 10 mg B4147-25MG 25 mg B4147-100MG 100 mg YesN Benzyl alcohol - - 08421-5ML-F 5mL 08421-25ML-F 25 mL Benzyl alcohol - - 442481 1000 mg Benzyl butyl phthalate - - 36927-250MG 250 mg Benzyl butyl phthalate - - 442503 1000 mg Betamethasone - - 34166-100MG 100 mg Bis-(2-chloroisopropyl) ether - - 48498 100 mg Bis(2-ethylhexyl) phthalate solution 5000 μg/mL in methanol - 40064 1mL Bis(2-ethylhexyl) phthalate solution 2000 μg/mL in methanol - 47994 1mL Bisphenol A-d16 - - 442876 50 mg Boldine - - B3916-1G 1g B3916-5G 5g Brombuterol hydrochloride - - 94972-10MG 10 mg Bromochloromethane - - 442498 500 mg 2-Bromo-1-chloropropane solution 2000 μg/mL in methanol - 48088 1mL Bromodichloroacetic acid - - 442499 100 mg Bromodichloroacetic acid solution 1000 μg/mL in methyl tert-butyl ether - 47278 1mL Bromodichloromethane