Band 44b Zeitschrift für Naturforschung 1989 Contents Contents of Number 1 New Transition Metal Complexes with the Ligand Me2S(0)=N PPh 2 = N — (In German) Original Communications H. W. R o e sk y , F. S c h r u m p f , and M. N olte- meyer 35 Synthesis and Structure of Tetrameric N,N'-Di- phenylformamidinatoGold(I), [Au(PhNCHNPh ) ] 4 Dibenzoylmethane Reaction with Dichlorophenyl- (In German) phosphine: Oxygen Transfer from Carbon to Phosphorus via a Defined C 2P 0 3 Phosphorane E. H a r t m a n n and J. S tr ä hl e 1 W. V. D a h l h o f f , K. M . T a b a , and R. M ynott 41 Synthesis and Crystal and Molecular Structure of /rans-Dichloro(ethanedial dioximato(l—)-N,N')- Borylation of Sulfamides, Sulfonimines and Sul- (ethanedial dioxime-N,N')rhodium(III) fonediimines (In German) M . M £g n a m is i-B e l o m b£ 5 W. E in h o l z , G. F r e y , and W. H a u b o l d 47 The Structure of [(terf-C4H 9)3PI][W(CO)4I3] — a Con­ 13C and 15N NMR Spectroscopic Study of Some Penta- tribution on the Acceptor Properties of Iodophos- carbonylchromium-Aminophosphane Complexes phonium Ions (In German) (In German) N. K u h n , R. Jü s c h k e , W.-W. d u M o n t , B. W r a c k m e y er , K . S c h a m e l , and M. H erber - M . B a t c h e r , D. B l ä s e r , and R. B o ese 9 HOLD 55 Phase Diagrams of Methyihalogenosilanes with Py­ Photoionization and Ion Fragmentation of SF 4 ridine and Lutidine (In German) (In German) K. H e n s e n and M. D räb ing 63 H.-W. Jo c h im s , E . R ü h l , a n d H. B aum g ä r t el 13 Reactions of Sodium Complexes of Aromatic Ethers Photoionization Mass Spectra of Methyl(tri- with Dichloro(diorganylamino)boranes fluoromethyl)sulfan CH3SCF3 (In German) (In German) G. H a g e n o w , H .-W . Jo c h im s , J. Sa w a t z k i, W. M ar in g g e l e and A. M eller 67 R . M in k w it z , a n d H . B a u m g ä r t e l 17 Vibrational Spectrum of the Cluster Compound Photoion Spectroscopy of Sulfurchloridepenta- Nb6F 15 (In German) fluoride SF5C1, the Ionization Potential of Sulfur- pentafluoride SF 5 (In German) G. K liche and H. G. v o n S c h n e r in g 74 H . B a u m g ä r t e l , H .-W . Jo c h im s , E. R ü h l , Synthesis of Water Soluble Tetrairidium Clusters O. L ö s k in g , and H . W il ln e r 21 Suitable for Heavy Atom Labelling of Proteins Dithiocarbimates from Sulfonamides, Part 1: Prep­ W. Ja h n 79 aration and X-Ray Crystal Structures of K2[S2C = N - S 0 2 -C 6H5] -2H20 and Chemistry on Rigid Interfaces, 9. Properties and Be­ K2[S2C = N - S 0 2 -C 6H 4 -C 1]-2H 20 haviour of Onium Group Modified Aerosils. Some Examples of Interparticular Reactions H .- U . H u m m e l an d U . K o rn 24 (In German) Dithiocarbimates from Sulfonamides, Part 2: Prep­ L. H o rn er and W. R oth 83 aration and X-Ray Crystal Structures of (PPh 4)2[Ni(S2C = N—S0 2 —Ph)2] and The Synthesis of Some Cyclopentadienyliron-Indium (PPh 4)2[Ni(S2C = N —S0 2 —C6H 4 —Cl)2] • 2 H20 Complexes H .- U . H u m m e l an d U . K orn 29 N . C. N o r m a n and P. M. W ebster 91 IV Contents Notes Chemistry of Polyfunctional Molecules, 104. Gold-, Palladium- and Platinumchlorocomplexes Syntheses of Dicyclopentadienyl-Titanium(IV) Sub­ of (±)-2-[N,N-Bis(2-diphenylphosphinoethyl)- stituted Carbodiimides (In German) amino]-tetrahydro-2//-l,3,2-oxazaphosphorine-2- oxide (In German) H. P lenio and H. W. R oesky 94 J. E ll e r m a n n and N . W ill 127 Synthesis and Structure of 2,4.6,8 -Tetrakis(diisopro- pylamino)2,4,6,8-tetrabora-tricyclo-[3.3.0.0' ]- Photochemical Splitting of a Polar Metal —Metal octane (In German) Bond by Metal to Metal Charge Transfer Excita­ tion of [Ph 3PAu—Co(CO)4] (In German) A. K r ä m e r , H. P r it z k o w , and W. S iebert 96 A. V ogler and H. K u n k e l y 132 Synthesis and Silica Gel Promoted Rearrangement of 5-Methylthio-3-carbo-/-butoxy-pent-3-en-2-one The Crystal Structure of [Ca(N3)2(H 20 ) 2] • C6H 14N4 at 100 K (In German) P. B a-lcz ew sk i and M . M ikolajczyk 99 F. A. M a u t n e r , H. KRiscHNER,andCH. K ratky 135 Phase Diagrams of Aluminium Halide-Pyridinium Halide Systems, III. Determination of the Phase Opening of Trinuclear Clusters by Diphosphino- Diagrams Aluminium Bromide-Pyridinium Iodide methane Ligands (In German) and Aluminium Chloride-Pyridinium Bromide R. P. P la n a l p and H. V a h r e n k a m p 139 (In German) G. S e e m a n n and K. H e n s e n 102 Photoredox Reactions of Hg(CN) 2/[Fe(CN)6]4~ and [HgCo 2(CN)10]6_ Induced by Inner-Sphere Metal to Metal Charge Transfer Excitation H. K u n k e l y , G. S t o c h e l , and A. V ogler 145 Tris(benzoyl-thiobenzoyl-methanato-0,S)indium, a Conformer of a Facial Isomer Contents of Number 2 V . D . G u p t a , A. K. M is h r a , H. N ö t h , and K . P olborn 149 Original Communications A Convenient Preparation of Bis(phosphorothioyl) Synthesis and Structure of Trimeric l,5-Bis(p-ethoxy- Sulfides phenyl)pentaazadienido-copper(I) — A Complex with Short Cu —Cu Contacts in a Linear Cu33+ Unit S. M i n , H. Is h ih a r a , T. M u r a i, and S. K ato 153 (In German) Ruthenium Complexes with Diazadienes, IX. A R. S c h m id and J. St r ä h l e 105 New Chromophore from Two Diazadiene Ruthenium Units — Structure and Properties of Synthesis and Structure of ^-Bromo-^-dioxo-bis- [(CO)2(DAD)CH 3R u -R u C H3(DAD)(CO)2] (phthalocyaninato-niobium(V))tribromide, (DAD = ipr—N= C H —CH = N —ipr) (In German) [(PcNb)20 2Br]+BrJ, a Dinuclear Phthalocya- ninato Complex (In German) H. tom D ieck, W. R o h d e , and U. B e h r e n s 158 F. G in gl and J. S t r ä h l e 110 Molecular and Crystal Structure of Two Cyclobuten- 3,4-dione Derivatives: The Dithallium Salt of 1,2- Synthesis and Crystal Structure of Dicyanimino- (T12CMCB) and the 1,2-Diiodocy- [Na-15-Crown-5][WF5(NCl)] (In German) clobuten-3,4-dione (I2CB) A. G o r g e , K. D e h n ic k e , and D . F e n s k e 117 B . L u n e l l i and M . M o nari 169 Detection of the Isotopomeric c/oso-Hydrohexa- Reactive E = C (p—p) 7r-Systems, XIX. F3CP=C(H)F borates 1IB„10B6_„H62_, n = 0-6. by Low Temper­ and F 3CP=C(D)F as Dienophiles (In German) ature Raman Spectroscopy (In German) U. A lt h o ff, J. G r o b e , D. L e V a n , and E.-U. W. P reetz and J. T h e s in g 121 W ÜRTH WEIN 175 Contents V On the Dynamic Structure Behaviour of the Di- The Space Group of (TTM-TTF) 2+(AuC14 ) 2 methylamine—Carbondioxide Complex (Dim- [TTM-TTF = Tetra(methylthio)tetrathiofulva- carb) (In German) lene] R . R a d e g l ia , J. A n d e r s c h , and W . S chroth 181 P. G. Jo n e s 243 Radical Ions, 81. ENDOR Spectroscopic Investiga­ High Catalytic Activity of Vanadium(V) Oxo-Poly- tions of Radical Cations of Aromatic Organosulfur mers for Oxidative Cleavage of Catechol Compounds (In German) Y. N ish id a and H. K ikuchi 245 H . B o c k . B. H ie r h o l z e r , and P. R ittmeyer 187 Synthesis and Crystal Structure of the Amidinato Complex Ph—C(NSiMe 3)2TeCl3 (In German) Contents of Number 3 E . H ey , C h . E rgf.z in g e r , and K. D e h n ic k e 205 a-Aminoalkylation of Enamines with Iminium- Original Communications tetrachloro-aluminates (In German) Seleno-antimonates(V): Preparation and Crystal N. R isch and A. E sser 208 Structure of Na3SbSe4, K3SbSe4 and [Ba(en)4]2[Ba(en)3](SbSe4) 2 (In German) Organometallic Compounds with o-Phenylene Substituents, Part XVI. 2 :1-Complexes of 2,3,7,8- B.