Page 1/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 05/31/2011 Reviewed on 08/10/2004 1 Identification of the substance/mixture and of the company/undertaking Product identifier Product name: Potassium hexafluorosilicate Stock number: 89023 CAS Number: 16871-90-2 EINECS Number: 240-896-2 Index number: 009-012-00-0 Relevant identified uses of the substance or mixture and uses advised against. Sector of Use SU24 Scientific research and development Details of the supplier of the safety data sheet Manufacturer/Supplier: Alfa Aesar, A Johnson Matthey Company Johnson Matthey Catalog Company, Inc. 30 Bond Street Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: [email protected] www.alfa.com Information Department: Health, Safety and Environmental Department Emergency telephone number: During normal hours the Health, Safety and Environmental Department at (800) 343-0660. After normal hours call Carechem 24 at (866) 928-0789. 2 Hazards identification Classification of the substance or mixture GHS06 Skull and crossbones H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. Classification according to Directive 67/548/EEC or Directive 1999/45/EC T; Toxic R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. Label elements Labelling according to EU guidelines: Code letter and hazard designation of product: T Toxic Risk phrases: 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Safety phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 45 In case of accident or if you feel unwell, seek medical advice immediately. Hazard description: WHMIS classification Classification system HMIS ratings (scale 0-4) (Hazardous Materials Identification System) HEALTH 2 Health (acute effects) = 2 FIRE 0 Flammability = 0 Reactivity = 0 REACTIVITY 0 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. (Contd. on page 2) USA DR Page 2/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 05/31/2011 Reviewed on 08/10/2004 Product name: Potassium hexafluorosilicate (Contd. of page 1) vPvB: Not applicable. 3 Composition/information on ingredients Chemical characterization: Substances (CAS#) Description: Potassium hexafluorosilicate (CAS# 16871-90-2), 100% Identification number(s): EINECS Number: 240-896-2 Index number: 009-012-00-0 4 First aid measures Description of first aid measures General information Immediately remove any clothing soiled by the product. Remove breathing apparatus only after contaminated clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. After inhalation Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice. After skin contact Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice. After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing Do not induce vomiting; immediately call for medical help. Seek immediate medical advice. 5 Firefighting measures Extinguishing media Suitable extinguishing agents Extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents Water Special hazards arising from the substance or mixture In case of fire, the following can be released: Hydrogen fluoride (HF) Silicon oxide Metal oxide fume Advice for firefighters Protective equipment: Wear self-contained respirator. Wear fully protective impervious suit. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions: Do not allow material to be released to the environment without proper governmental permits. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling Precautions for safe handling Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace. Open and handle container with care. Information about protection against explosions and fires: No special measures required. (Contd. on page 3) USA DR Page 3/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 05/31/2011 Reviewed on 08/10/2004 Product name: Potassium hexafluorosilicate (Contd. of page 2) Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Store away from oxidizing agents. Store away from water/moisture. Further information about storage conditions: Protect from humidity and water. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. 8 Exposure controls/personal protection Additional information about design of technical systems: Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Control parameters Components with limit values that require monitoring at the workplace: Fluorides (as F) mg/m3 ACGIH TLV 2.5 Austria MAK 2.5 Belgium TWA 2.5 Finland TWA 2.5 France TWA 2.5 Germany MAK 2.5 Hungary TWA 1; 2-STEL Netherlands MAC-K 3.5 Norway TWA 0.6 Poland TWA 1; 3-STEL Sweden NGV 2 Switzerland MAK-W 1.5; 3-KZG-W United Kingdom TWA 2.5 Russia TWA 2 Denmark TWA 2.5 USA PEL 2.5 Additional information: No data Exposure controls Personal protective equipment General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: Use suitable respirator when high concentrations are present. Protection of hands: Impervious gloves Eye protection: Safety glasses Body protection: Protective work clothing. 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Powder Color: White Odor: Not determined Odour threshold: Not determined. pH-value (10 g/l) at 20°C (68 °F): 3.4 Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined Sublimation temperature / start: Not determined Flash point: Not applicable (Contd. on page 4) USA DR Page 4/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 05/31/2011 Reviewed on 08/10/2004 Product name: Potassium hexafluorosilicate (Contd. of page 3) Flammability (solid, gaseous) Not determined. Ignition temperature: Not determined Decomposition temperature: Not determined Auto igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined Upper: Not determined Vapor pressure: Not applicable. Density at 20°C (68 °F): 2.27 g/cm³ (18.943 lbs/gal) Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: Slightly soluble in cold water Decomposes in hot water Segregation coefficient (n-octonol/water): Not determined. Viscosity: dynamic: Not applicable. kinematic: Not applicable. Other information No further relevant information available. 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications. Stable until: Melting point Possibility of hazardous reactions Reacts with strong mineral acids forming hydrogen fluoride Yields hydrofluoric acid (HF) when dissolved in water. Incompatible materials: Oxidizing agents Water/moisture Hazardous decomposition products: Hydrogen fluoride Silicon oxide Metal oxide fume 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 500 mg/kg (guinea pig) 70 mg/kg (mouse) 156 mg/kg (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: No sensitizing effects known. Subacute to chronic toxicity: Fluorides may cause salivation, nausea, vomiting, diarrhea and abdominal pain, followed by weakness, tremors, shallow respiration, convulsions and coma. May cause brain and kidney damage. Chronic fluoride poisoning can cause severe bone changes, loss of weight, anorexia, anemia and dental defects. Inorganic silicon compounds may be acute inhalation irritants. Prolonged inhalation may cause pulmonary fibrosis known as silicosis. Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) reports the following effects in laboratory animals: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia. Behavioral - ataxia. (Contd. on page 5) USA DR Page 5/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 05/31/2011 Reviewed on 08/10/2004 Product name: Potassium hexafluorosilicate (Contd. of page 4) Behavioral - muscle contraction