Page 1/15 Material Safety Data Sheet ISO 11014:2009 and GHS 2007 Printing date 10/03/2017 Review date 10/03/2017 * 1 Identification · Product identifier · Trade name: STANDARD-3ICPMS MULTIELEM CAL · Article number N9300233 · Application of the substance / the mixture Laboratory chemicals · Details of the supplier of the safety data sheet · Manufacturer/Supplier: PerkinElmer, Inc. 710 Bridgeport Avenue Shelton, Connecticut 06484 USA [email protected] · Emergency telephone number: CHEMTREC (within US) 800-424-9300 CHEMTREC (from outside US) +1 703-527-3887 (call collect) CHEMTREC (within AU) +(61)-290372994 * 2 Hazard(s) identification · Classification of the substance or mixture Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS05 · Signal word Danger · Hazard-determining components of labeling: Nitric Acid · Hazard statements H314 Causes severe skin burns and eye damage. · Precautionary statements P260 Do not breathe dusts or mists. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Classification system: · NFPA ratings (scale 0 - 4) Health = 3 0 Fire = 0 3 0 Reactivity = 0 (Contd. on page 2) USA 45.2.29 Page 2/15 Material Safety Data Sheet ISO 11014:2009 and GHS 2007 Printing date 10/03/2017 Review date 10/03/2017 Trade name: STANDARD-3ICPMS MULTIELEM CAL (Contd. of page 1) · HMIS-ratings (scale 0 - 4) HEALTH 3 Health = 3 FIRE 0 Fire = 0 REACTIVITY 0 Reactivity = 0 · Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Hazardous components: 7697-37-2 Nitric Acid Ox. Liq. 2, H272 5.0% Skin Corr. 1A, H314 · Additional Components 7440-38-2 Arsenic 0.001% Acute Tox. 3, H301; Acute Tox. 3, H331 Carc. 1A, H350 513-77-9 barium carbonate 0.001% Acute Tox. 4, H302 7440-41-7 beryllium 0.001% Acute Tox. 3, H301; Acute Tox. 2, H330 Carc. 1B, H350; STOT RE 1, H372 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317; STOT SE 3, H335 7440-69-9 bismuth 0.001% 7440-43-9 cadmium (non-pyrophoric) 0.001% Acute Tox. 2, H330 Muta. 2, H341; Carc. 1B, H350; Repr. 2, H361; STOT RE 1, H372 7440-48-4 cobalt 0.001% Resp. Sens. 1, H334; Carc. 2, H351 Skin Sens. 1, H317 7789-02-8 Chromium Nitrate Nonahydrate 0.001% Ox. Sol. 2, H272 Acute Tox. 3, H301; Acute Tox. 3, H311 Skin Corr. 1C, H314 Acute Tox. 4, H332; Eye Irrit. 2A, H319; STOT SE 3, H335 7789-18-6 caesium nitrate 0.001% Ox. Sol. 3, H272 7440-50-8 copper 0.001% 7439-89-6 iron 0.001% 7440-55-3 gallium 0.001% Skin Corr. 1C, H314 (Contd. on page 3) USA 45.2.29 Page 3/15 Material Safety Data Sheet ISO 11014:2009 and GHS 2007 Printing date 10/03/2017 Review date 10/03/2017 Trade name: STANDARD-3ICPMS MULTIELEM CAL (Contd. of page 2) 7439-97-6 mercury 0.001% Acute Tox. 2, H330 Repr. 1B, H360; STOT RE 1, H372 7440-74-6 Indium 0.001% 7757-79-1 potassium nitrate 0.001% Ox. Sol. 2, H272 554-13-2 lithium carbonate 0.001% Acute Tox. 3, H301 Eye Irrit. 2A, H319 7439-95-4 magnesium 0.001% Pyr. Sol. 1, H250; Water-react. 1, H260 7439-96-5 manganese 0.001% 497-19-8 sodium carbonate 0.001% Eye Irrit. 2A, H319 1317-36-8 lead monoxide 0.001% Repr. 1A, H360; STOT RE 2, H373 Acute Tox. 4, H302; Acute Tox. 4, H332 13126-12-0 rubidium nitrate 0.001% Ox. Sol. 1, H271 7782-49-2 selenium 0.001% Acute Tox. 3, H301; Acute Tox. 3, H331 STOT RE 2, H373 1633-05-2 strontium carbonate 0.001% 10102-45-1 thallium nitrate 0.001% Acute Tox. 2, H300; Acute Tox. 2, H330 STOT RE 2, H373 7803-55-6 ammonium trioxovanadate 0.001% Acute Tox. 2, H300 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335 7440-66-6 zinc 0.001% Water-react. 2, H261 7429-90-5 aluminium 0.001% 7440-22-4 silver 0.001% 7440-61-1 uranium 0.001% Acute Tox. 2, H300; Acute Tox. 2, H330 STOT RE 2, H373 7440-70-2 calcium 0.001% Water-react. 2, H261 7440-02-0 nickel 0.001% Carc. 2, H351; STOT RE 1, H372 Skin Sens. 1, H317 7732-18-5 Water 94.97% * 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: In case of unconsciousness place patient stably in side position for transportation. (Contd. on page 4) USA 45.2.29 Page 4/15 Material Safety Data Sheet ISO 11014:2009 and GHS 2007 Printing date 10/03/2017 Review date 10/03/2017 Trade name: STANDARD-3ICPMS MULTIELEM CAL (Contd. of page 3) · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required. * 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. · Protective Action Criteria for Chemicals · PAC-1: 7697-37-2 Nitric Acid 0.16 ppm 7440-38-2 Arsenic 1.5 mg/m3 513-77-9 barium carbonate 2.2 mg/m3 7440-41-7 beryllium 0.0023 mg/m3 7440-69-9 bismuth 15 mg/m3 7440-43-9 cadmium (non-pyrophoric) 0.10 mg/m3 7440-48-4 cobalt 0.18 mg/m3 7789-18-6 caesium nitrate 7.2 mg/m3 7440-50-8 copper 3 mg/m3 7439-89-6 iron 3.2 mg/m3 7440-55-3 gallium 30 mg/m3 7439-97-6 mercury 0.15 mg/m3 7440-74-6 Indium 0.3 mg/m3 7757-79-1 potassium nitrate 9 mg/m3 554-13-2 lithium carbonate 3.1 mg/m3 (Contd. on page 5) USA 45.2.29 Page 5/15 Material Safety Data Sheet ISO 11014:2009 and GHS 2007 Printing date 10/03/2017 Review date 10/03/2017 Trade name: STANDARD-3ICPMS MULTIELEM CAL (Contd. of page 4) 7439-95-4 magnesium 18 mg/m3 7439-96-5 manganese 3 mg/m3 497-19-8 sodium carbonate 7.6 mg/m3 1317-36-8 lead monoxide 0.16 mg/m3 13126-12-0 rubidium nitrate 14 mg/m3 7782-49-2 selenium 0.6 mg/m3 1633-05-2 strontium carbonate 71 mg/m3 10102-45-1 thallium nitrate 0.078 mg/m3 7803-55-6 ammonium trioxovanadate 0.01 mg/m3 7440-66-6 zinc 6 mg/m3 7440-22-4 silver 0.3 mg/m3 7440-61-1 uranium 0.6 mg/m3 7440-02-0 nickel 4.5 mg/m3 · PAC-2: 7697-37-2 Nitric Acid 24 ppm 7440-38-2 Arsenic 17 mg/m3 513-77-9 barium carbonate 270 mg/m3 7440-41-7 beryllium 0.025 mg/m3 7440-69-9 bismuth 170 mg/m3 7440-43-9 cadmium (non-pyrophoric) 0.76 mg/m3 7440-48-4 cobalt 2 mg/m3 7789-18-6 caesium nitrate 79 mg/m3 7440-50-8 copper 33 mg/m3 7439-89-6 iron 35 mg/m3 7440-55-3 gallium 330 mg/m3 7439-97-6 mercury 1.7 mg/m3 7440-74-6 Indium 3.3 mg/m3 7757-79-1 potassium nitrate 100 mg/m3 554-13-2 lithium carbonate 34 mg/m3 7439-95-4 magnesium 200 mg/m3 7439-96-5 manganese 5 mg/m3 497-19-8 sodium carbonate 83 mg/m3 1317-36-8 lead monoxide 130 mg/m3 13126-12-0 rubidium nitrate 150 mg/m3 7782-49-2 selenium 6.6 mg/m3 1633-05-2 strontium carbonate 780 mg/m3 10102-45-1 thallium nitrate 4.3 mg/m3 7803-55-6 ammonium trioxovanadate 0.11 mg/m3 7440-66-6 zinc 21 mg/m3 7440-22-4 silver 170 mg/m3 7440-61-1 uranium 5 mg/m3 7440-02-0 nickel 50 mg/m3 (Contd.