SAFETY DATA SHEET Revision Date: 21/May/2015 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product Identifier Product Description: AROFLINT® 810 Other means of identification SAP ID(s): 194187 ; 194188; 195607 Material Code: 91859-00 Chemical Family Polyester Resin Recommended use of the chemical and restrictions on use Intended Use: Coatings Uses advised against No information available Details of the supplier of the safety data sheet Manufacturer/Supplier: Emergency Telephone (Chemtrec) 1-800-424-9300 Reichhold LLC 2 E-mail address [email protected] Corporate Headquarters P.O. Box 13582 Research Triangle Park, NC 27709 USA Tel +1-919-990-7500 Fax +1-919-767-8602 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Inhalation (Vapors) Category 4 Carcinogenicity Category 2 Reproductive toxicity Sub-category 1B Specific target organ toxicity (single exposure) Category 3 Chronic aquatic toxicity Category 3 Flammable liquids Category 3 Label elements Emergency Overview Danger Hazard Statements Harmful if inhaled Suspected of causing cancer May damage fertility or the unborn child May cause respiratory irritation Harmful to aquatic life with long lasting effects Flammable liquid and vapor __________________________________________________________________________________________ Page 1 / 11 194187 ; AROFLINT® 810 Revision Date: 21/May/2015 __________________________________________________________________________________________ Appearance Amber Physical State Liquid Odor Pungent Sweet Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing vapor or mist Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Avoid release to the environment Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing In case of fire: Use CO2, dry chemical, or alcohol resistant foam to extinguish Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to industrial incineration plant Dispose of in accordance with federal, state and local regulations Hazards not otherwise classified (HNOC) Other Information May be harmful if swallowed Causes mild skin irritation Unknown acute toxicity 66.8 % of the mixture consists of ingredient(s) of unknown toxicity Unknown aquatic toxicity 99.5 % of the mixture consists of components(s) of unknown hazards to the aquatic environment 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No Weight-% Trade Secret Polyester Resin Proprietary 66 - 69 Methyl Amyl Ketone 110-43-0 20.5 - 22.5 Isopropyl alcohol 67-63-0 4 - 6 Propylene glycol monomethyl ether 107-98-2 3 - 5 Chlorendic acid 115-28-6 < 1.5 Triphenyl Phosphite 101-02-0 0.2 - 0.4 If CAS number is "proprietary", the specific chemical identity has been withheld as a trade secret. __________________________________________________________________________________________ Page 2 / 11 194187 ; AROFLINT® 810 Revision Date: 21/May/2015 __________________________________________________________________________________________ 4. FIRST AID MEASURES First Aid Measures Eye Contact Move individual away from exposure. Immediately flush eyes with large quantities of clean water for at least 15 minutes. Get immediate medical attention. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops or persists. Wash contaminated clothing before reuse. Inhalation Remove victim to fresh air. Keep warm and quiet. If not breathing, give artificial respiration. If breathing is difficult, give oxygen by trained personnel. GET IMMEDIATE MEDICAL ATTENTION. Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. GET IMMEDIATE MEDICAL ATTENTION. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Inhalation of high vapor concentrations can cause CNS-depression and narcosis. Effects Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Carbon dioxide (CO2), Alcohol resistant foam, Dry chemical, Water spray Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Hazardous combustion products Carbon monoxide, Carbon dioxide (CO2) Combustion/Explosion Hazards Flammable. Vapors may form explosive mixture with air. Flash back possible over considerable distance. Empty containers may retain product residue (liquid and/or vapor). Do not pressurize, cut, weld, braze, solder, drill, grind, or expose these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may cause injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned to a drum reconditioner or properly disposed. Closed containers may rupture when exposed to extreme heat. Protective Equipment and Precautions for Firefighters Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly decontaminate all protective equipment after use. Evacuate all persons from the fire area to a safe location. Move non-burning material, as feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazard while extinguishing the blaze. DO NOT extinguish a fire resulting from the flow of this flammable liquid until the flow of liquid is effectively shut off. This precaution will help prevent the accumulation of an explosive vapor-air mixture after the initial fire is extinguished. Use water spray to cool fire-exposed containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures __________________________________________________________________________________________ Page 3 / 11 194187 ; AROFLINT® 810 Revision Date: 21/May/2015 __________________________________________________________________________________________ Personal Precautions Remove all sources of ignition. Use personal protective equipment as required. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Use non-sparking (non-metallic) tools to clean up spill. Environmental Precautions Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Methods and material for containment and cleaning up Methods for Containment Prevent spilled material from 1) contaminating soil, 2) entering sanitary sewers, storm sewers, and drainage systems, and 3) entering bodies of water or ditches that lead to waterways. Prevent spreading over a wide area (e.g. by containment or oil barriers). Methods for Clean-up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 7. HANDLING AND STORAGE Precautions for Safe Handling Handling Avoid breathing vapors or mists. Avoid contact with eyes, skin and clothing. Take off contaminated clothing and wash before reuse. Wash hands before breaks and immediately after handling the product. Ensure adequate ventilation. Remove all sources of ignition. Do not smoke. Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment. Empty containers may retain product residue (liquid and/or vapor). Do not pressurize, cut, weld, braze, solder, drill, grind, or expose these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may cause injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned to a drum reconditioner or properly disposed. Conditions for safe storage, including any incompatibilities Storage Keep away from heat, sparks and open flame. - No smoking. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits Methyl Amyl Ketone (CAS #: 110-43-0) ACGIH TLV 50 ppm TWA OSHA PEL 100 ppm TWA 465 mg/m3 TWA Canada - Alberta OELs 50 ppm TWA 233 mg/m3 TWA Canada - Ontario OELs 25 ppm TWA 115 mg/m3 TWA Canada - British Columbia OELs 50 ppm TWA NIOSH IDLH 800 ppm Immediately dangerous to life or health IDLH Mexico OEL 100 ppm STEL 465 mg/m3 STEL 50 ppm TWA 235 mg/m3 TWA Isopropyl alcohol (CAS #: 67-63-0) ACGIH TLV 200 ppm TWA 400 ppm STEL A4 Not Classifiable as a Human Carcinogen __________________________________________________________________________________________