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Detection

 Example of n detection: Well logging Reservoir/Formation Evaluation  Brief introduction to neutron generation – Continuous sources – Large accelerators – Pulsed neutron generators  n interactions with matter  n detection  High/low energy n detectors Measurement Environment

Casing & BH Fluid

Cement Formation Region In most logging applications, pulsed neutron tools should be run decentralized in the wellbore.

The borehole region encompasses anything that’s before the formation. This includes tubulars, gravel packs, etc. Borehole Region High Energy Neutron Reactions

Inelastic γγγ γ of Capture

Inelastic Porosity Region - Compton Scattering effect Capture Porosity Region -. similar to Gamma-Gamma logging. Gamma transport is a function of Hydrogen Gamma transport is a Index. function of Density.

elastic High Energy Neutron Inelastic γ Neutron Energy Losses

Element Avg. # of Max. Atomic Atomic Collisions Energy Weight Number Loss per Collision Calcium 371 8% 40.1 20

Chlorine 316 10% 35.5 17

Silicon 261 12% 28.1 14

Oxygen 150 21% 16.0 8

Carbon 115 28% 12.0 6

Hydrogen 18 100% 1.0 1

Hydrogen – Avg. Loss due to Angular Collisions is 63% Gamma Rays From Neutron Decay

10 µµss Gamma Rays From Inelastic Collisions

1000 µµss Gamma Rays From Thermal

Seconds,Minutes, Hours, Days NN Gamma Rays From Products Detection Methods

Gates γγγ’s Sorted by Number γγγ γγγTime and of (gross counts) Detector grouped in Gates counts P Photomultiplier P P Tube

γγγ’s Sorted by energy Time γγγ levels (256) (Not Unlike the Colors of the Rain Bow)

Number of counts 256 channels

Gamma Ray Energy Typical Capture Cross Sections for Formation Minerals

Mineral ΣΣΣ @20 °°°C,c.u. Typically used ΣΣΣ values Sandstone 7 to 14 10 Limestone 7 to 15 12 Dolomite 8 to 12 9 Shales 20 to 50 Varies for Formation Oil 1616 to to 22 2020 ƒƒƒ(Temperature, Pressure & Gas 2 2to to 15 15 ƒƒƒ(Temperature,Specific Pressure Gravity) & Specific Gravity)

Fresh Water Water 22.20 22.20 25 20 Salt Water (100 Kppm) 59 59 Salt Water (240 Kppm) 119 119 Response for Reservoir Monitoring (soft rock formations) Neutron Sources

 Continuous (ex. AmBe) – DOE/DHS efforts to eliminate them  Large Accelerators (ex. SNS) – for large projects  Pulsed Neutron Generators – Compact, convenient replacement of chemical sources

n generator tube Pulsed Neutron Sources

• Pulsed Accelerator – deuterium ( 2H) and tritium ( 3H) collided at 100keV D + T →→→ n + 4He – produces bursts of with 14MeV energy – ~1 x 10 8 neutrons/sec. – no measurable radioactivity when off Neutron Detection

 n don’t interact directly with e in matter

 Indirect methods of detection needed

 Charged particles and gammas created during n interactions with matter are detected instead

 Elastic, inelastic and n capture: basic interactions – Scintillation detectors – Gas Proportional counters - ionization chambers – Semiconductor detectors Neutron Detection

Cross section of n interaction with He, B, Li

n+3 He → 3 H + 1 H + 0.764 MeV n+6 Li → 4 He + 3 H + 4.79 MeV n+→10 B 7*3 Li + He →+ 7 Li 4 He + 0.48 MeV γ →7Li + 4 He Neutron Detection Lithium scintillation detectors (thermal neutrons)

 Lithium capture a thermal n  Lithium transforms into He and tritium + ~4.8Mev  Kinetic energy of particles deposited into crystal  Crystal emit a gamma ray  Gamma ray strikes photocathode and creates an e -  e- charge multiplied in PMT  output pulse

n+6 Li → 4 He + 3 H + 4.79 MeV Neutron Detection Li exhibits low efficiency  add Eu, Zn, others

Density of Scintillation Material 6Li atoms efficiency wavelength per neutron (cm -3) (nm)

Li glass (Ce) 1.75 ×10 22 0.45 % 395 nm ~7,000

LiI (Eu) 1.83 ×10 22 2.8 % 470 ~51,000

ZnS (Ag) - LiF 1.18 ×10 22 9.2 % 450 ~160,000 Neutron Detection H scintillation detectors (fast neutrons)

 Scintillation with hydrogenous material  Elastic interaction of n with H  n loss energy  Thermal n is captured by H  H emits 2.1 MeV gamma  Gamma ray strikes photocathode and creates an e-  e- charge multiplied in PMT  output pulse Neutron Detection

Scintillation detectors Neutron Detection Gas filled (proportional) n detectors

 Based on n interaction with B, He  Low energy (thermal) neutrons interact with gas  Charge particles (alpha) and H recoil ionize gas  Avalanche dischrge between cathode and anode creates electrical pulse n+3 He → 3 H + 1 H + 0.764 MeV n+→10 B 7*3 Li + He →+ 7 Li 4 He + 0.48 MeV γ →7Li + 4 He Neutron Detection Semiconductors n detectors

 n reaction with B, LiF converts n  charged particles  T or create e- hole pairs  Electric pulse produced at contacts

n+6 Li → 4 He + 3 H + 4.79 MeV γ 0.48 Li He 7 4 4.79 0.764 → +

τ e e ⋅ j C = 6 4 3 3 3 1 10 7*3 7 4 P ++ →+→ → + + + + + →+ +

n Hen Lin H H B He H Li MeV He MeV Li He MeV