University of Alberta a Stratigraphie and Geochemical Investigation Of
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University of Alberta A stratigraphie and geochemical investigation of Upper Devonian shale and marl aquitards, west-central Alberta, Canada. Catherine Cheryl SkiIliter O A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirernents for the degree of Master of Science. Department of Earth and Atrnospheric Sciences Edmonton, Alberta SpRng. 2000 National Ubrary Bibliothèque nationale 191 du Canada Acquisitions and Acquisitions et Biûliographic Secvices seMces bbliographiques The author has granted a non- L'auteur a accordé une licence non exchisve licence allowing the excbve pexmettant à la National Liiof Canada to Bibliothèque nationale du Canada de reproduce, loan, distrite or sell reproduire, prêter, distriiuer ou copies of this thesis in microform, vendre des copies de cette thése sous paper or electronic formats. la forme de microfiche/film, de reproduction sur papier ou sur format électronique. The author retains ownership of the L'auteur conserve la propriété du copyright in this thesis. Neither the droit d'auteur qui protège cette thèse. thesis nor substantial extracts fkom it Ni la thèse ni des exIn& substantiels may be pimted or otherwise de celle-ci ne doivent être imprimés reproduced without the author's ou autrement reproduits sans son permission. autorisation. Abstract A regional investigation of Devonian aquitards in west-central Alberta has identified the aquitards as effective barrien to (paleo-)fluids since the Late DevonianIEariy Carboniferous. Aquitards thin progressively towards the disturbed beH, and in areas such as the Obed and Simonette fields, aquitards are absent, permitting interconnection between the four major Devonian carbonate aquifers (i.e., D-1 through D-4). Aquitard lithofacies Vary in depositional environments from basin, via dope (or ramp), to near-reef. Paragenetic sequences have been established for both near-reef and near-basinal lithofacies. Stable isotopic analyses (6"0 and 613c) reveal that aquitards have been relatively impene:ible to aqueous formation fluids since the Late DevoniadEarly Carboniferous. Mercury injection data show that the aquitards are relatively effective seals to hydrocarbons. The nearmarine ''~rhr ratios of the carbonate fractions within the aquitards differ significantiy from highly radiogenic (87~renriched), late-stage, carbonate cements within adjacent carbonate aquifers. This finding suggests the lafier were precipitated from fluids containing an extrabasinal fluid component. Extrabasinal fluids likely entered the Devonian system through tectonic expulsion during the Laramide orogeny. These fluids are confined to Devonian carbonate aquifers and have probably moved in a predorninantly northeast direction. in the vicinity of the disturbed belt region, cross formational fluid flow is likely, due to the absence of aquitards or in areas where the D-1 to the D-4 is hydrologically connected. Acknowledgements I would first like to acknowledge and thank Hans for his guidance and support throughout supervision of this thesis. Several othen at UofA made this project possible, including: Don Resultay and Mark Labbe for thin section preparation; Diane Caird for XRD analyses; Ted Evans for help with magnetic susceptibility; Olga Levner, Stacey Hagan, Kariis Muehlenbachs, and Rob Creaser for help with stable and radiogenic isotope analyses; Arndt Buhlmann for computer software support; and Ben Rostron for discussions on fluid flow mechanisms. In Calgary, thanks is extended to: Adam Hedinger, Jack Wendte, Mark Mallamo, Ken Watson, and Ross McLean for discussions regarding Devonian stratigraphy and structure; to the crew at the EUB, especially Lori, for assistance in core logging and sampling; to the AGS in Edmonton for use of the microfiche and copying services; to Regina Shedd and Jon Greggs at UofC for assistance in rounding up some valuable cross sections; to Soumini Reddy, Jeny Shaw, and Bemie Schulmeister at the Petroleum Recovery lnstitute (PR!) for their in- kind support in completing mercury injection tests. Accommodation in Calgary was most kindly provided by Kim Manzano, Chez Elizabeth and Marianne. A special mention to Mare, Betsy, Astrid, Rajeev, Karen, Andrea, Nancy, Steph, Leslie, Devon, Darlene, George, and Ted for their friendship, guidance, and plenty of helpful discussions along the way. 1 am indebted to present and past 'Gang" members including Maja, Matt, Karsten, Kim, Marianne, Lisa, and Jeff; it's been a pleasure working with you and I wish you success in al1 of your future endeavors! 1 offer a warm thank-you to my farnily for their support and to Simon for his constant love, cornmitment, and guidance. An extra special thanks is extended to: Pat Cavell for her endeanng support, never-ending discussions, and guidance throughout the entire project; and to Caroline Nixon, who was a great help in the initial stages of th8 project cieaning, cnishing, and drilling sarnples, and cornpleting magnetic susceptibility tests, and also near the end during some serious editing of the rough drafts of chapters. Your perseverance, persuasiveness, and encouragement moved me. Table of Contents 1. 1. Introduction and Previous Studies ....................... ........ .............. 1 1.2. Objectives of the Research Project .............................................. 5 1.3. Study Area and Core Control.............................. ............................. 6 2. Chapter 2 O Regional Geological Setting and Depositional History m....m....m 8 2.1 . Western Canada Sedimentary Basin ............................... ... ........... 8 2.2. Devonian Stratigraphy ................................................................ 8 2.3. The Alberta Basin .............................. ..............................................10 2.3.1. West Shale Basin ....................... ............................... 10 2.4. WCSB Structures lnfluencing Devonian Stratigraphy ....................... 10 2.5. Woodbend Group ............................ ................................................ 13 2.5.1 . Stratigraphy and Depositional history ................................. 13 2.6. Winterbum Group ................. ........ ......................................16 2.6.1. Stratigraphy and Depositional History ..................... .......... 16 Lower Winterbum Group ........................ ................... 17 Upper Winterburn Group ............................ ............ 17 2.7. Basin Fill Units ....................... ............. .. ................................ 19 2.8. Hydrostratigraphic Units of the WCSB ...................................... 21 2.9. Identification of Aquitards .. ............................. ........................... 23 2.1 0 . Shale and Marl Aquitards ....................... ... ........ ................... 23 2.1 0.1 . Wnterbum Group Aquitards ........................................... 23 2.1 0.2. WoodbendMlinterbum Aquitard ................... ....... ..... 23 2.1 0.3. Woodbend Group Aquitard ...................... ...... ............ 24 2.10.4. Majeau Lake Formation Aquitard ......................................24 2.1 0.5. Beavehill Lake Group Aquitards ..................................... 24 2.1 0.6. Watt Mountain Formation Aquitard ................... ... ...... 24 2.1 1. Carbonate Aquifers ....................................................................... 24 3. Chapter 3 .Stratigraphie and Structural Investigation of Middle to Upper Devonian Aquitardsmmmmmmmm........................................................ 25 3.1 . Introduction and Objectives ................... .... ............................... 25 3.2. Cross Section Methods .................... ........ ........................................ 27 3.3. Hydrocarbon Production in Wells .....................................................28 3.4. Stratigraphic Cross Section Methods .................. ... ...*..**......**..... 28 3.5. Structural Cross Section Methods .................................. ............. 29 3.6. Synopsis of Stratigraphic and Structural Investigations.................. 29 3.6.1 . Sumrnary of Cross Sections A-A' ........................................ 29 3.6.2. Summary of Cross Sections B-8' .................................. ... 32 3.6.3. Summaiy of Cross Sections C-C' ................... .... .... .... 32 3.6.4. Sumrnary of Cross Sections D-D' ......................... .. .......... 37 3.6.5. Summary of Cross Sections E-E' ............................... ...37 3.6.6. Summary of Cross Section F-Ç' ....................................... 42 4. Chapter 4 .Lithofacies and Mineralogical Facies of Regional Aquitards .................................................................................... 45 4.1. Introduction ......................... ....~........................................................45 4.2. Lithological Facies ....................... ... ........................................ 46 4.2.1. Introduction ..................... ......**.**.*.......*...*..*........*..........46 4.2.2. Lithofacies A .................................... ...................................49 4.2.3. Lithofacies B ....................... ................................................ 53 4.2.4. Lithofacies AD........... ......,.. ................. .. 53 4.2.5. lithofacies AE ............... ...... ........ .......... ....*..........*........58 4.2.6. Lithofacies C ......................... ........*..........*..........................61 4.2.7. Lithofacies G ................................. .....................................