Heating with Wood: Principles of Combustion M i c h a e l Vo g e l , H o u s i n g a n d R e s i d e n t i a l E n e rg y S p e c i a l i s t

T h i s M o n t G u i d e e x p l a i n s h o w w o o d b u r n s . I t d i s c u s s e s t h e b a s i c re q u i re m e n t s f o r c o m b u s t i o n a n d f a c t o r s t h a t c a n i m p ro v e o r h i n d e r i t . I t o ff e r s a b a s i c u n d e r s t a n d i n g o f w o o d c o m b u s t i o n t h a t m a y b e h e l p f u l i n c o m p a r i n g w o o d s t o v e s o r o p e r a t i n g y o u r s m o re c l e a n l y, s a f e l y a n d e f fi c i e n t l y. Mo n tGu i d e

MT198405 HR Reviewed 10/05

K N O W I N G TH E P R I N C I P L E S O F c o m b u s t i o n , p a r t i c u l a r l y t h e c o m b u s- • Th e w o o d i s h e a t e d t o e v a p o r a t e a n d d r i v e t i o n o f w o o d , i s i m p o r t a n t t o a n y o n e o ff m o i s t u re . Th i s h e a td o e s n o t w a r m t h e w h o i s c o n s i d e r i n g p u r c h a s i n g a w o o d s t ov e o r r o o m . s t ov e a n d i s e v a l u a t i n g d e s i g n f e a t u re s o f s t ov e s . • Th e w o o d s t a r t s t o b re a k d ow n c h e m i c a l l y K n ow i n g c o m b u s t i o n p r i n c i p l e s a t 5 0 0 ° F a n d v o l a t i l e m a t t e r i s v a p o r i z e d . h e l p s p e o p l e d e c i d e i f t h e c l a i m s f o r a s t ov e a re v a l i d a n d w h i c h s t ov e b e s t fi t s • Th e s e v a p o r s c o n t a i n b e t w e e n 5 0 a n d 6 0 t h e i r n e e d s . In a d d i t i o n , u n d e r s t a n d i n g p e r c e n t o f t h e h e a t v a l u e o f t h e w o o d . h ow w o o d b u r n s h e l p t h e w o o d s t ov e o p e r a t o r b u r n w o o d m o re c l e a n l y, • A t 1 1 0 0 ° F t h e s e v a p o r s b u r n . Th i s h i g h s a f e l y a n d e f fi c i e n t l y. t e m p e r a t u re m u s t b e m a i n t a i n e d f o r m a x i m u m e ffi c i e n c y i n c o m b u s t i o n . C o m b u s t i o n b a s i c s A l l c o m b u s t i o n re q u i re s t h re e e l e m e n t s : • Fo l l ow i n g t h e re l e a s e o f v o l a t i l e g a s e s , t h e f u e l , a n o x i d i z e r a n d a s o u r c e o f re m a i n i n g m a t e r i a l i s c h a rc o a l , w h i c h b u r n s h e a t . W h e n t h e s e t h re e e l e m e n t s a t t e m p e r a t u re s e xc e e d i n g 1 1 0 0 ° F. a re c o m b i n e d i n t h e a p p r o p r i a t e e n v i r o n m e n t , c o m b u s t i o n w i l l o c c u r. I f a n y o f t h e e l e m e n t s i s re m ov e d , F i g u re 1 . S t a g e s o f Wo o d C o m b u s t i o n c o m b u s t i o n s t o p s . Wi t h a w o o d - b u r n i n g s t ov e , w o o d t h r o u g h p h o t o s y n t h e s i s . P h o t o s y n t h e t i c H e a t i s o b v i o u s l y t h e f u e l , a i r i s t h e o x i d i z e r e n e r g y s t o re d i n t h e w o o d i s re l e a s e d Th e h e a t re l e a s e d f r o m b u r n i n g o n e a n d t h e i n i t i a l s o u r c e o f h e a t i s u s u a l l y d u r i n g c o m b u s t i o n . Th u s , t h e e n e r g y p a r t o f w o o d o r c h a r c o a l b e d i g n i t e s t h e fl a m e f r o m a m a t c h . re l e a s e d f r o m b u r n i n g w o o d t o h e a t y o u r o t h e r p a r t s o f t h e w o o d . Sm a l l p i e c e s F u e l h o m e a c t u a l l y c a m e f r o m t h e s u n w h e n o f b u r n i n g w o o d a re n e e d e d t o i g n i t e Wo o d i s s i m i l a r i n s t r u c t u re t o t h e w o o d w a s f o r m i n g . A l s o c o n t a i n e d i n l a r g e r p i e c e s . w o o d i s a l a r g e a m o u n t o f w a t e r, a s w e l l fi b e r g l a s s . Th e fi b r o u s p a r t o f w o o d S t a g e s o f w o o d c o m b u s t i o n t h a t i s s i m i l a r t o g l a s s fi b e r s i s c a l l e d a s m i n e r a l s , o i l s a n d o t h e r c o m p o u n d s . Bu r n i n g w o o d i n v o l v e s s e v e r a l c e l l u l o s e . Th e c e l l u l o s e i s e m b e d d e d i n A i r p r o c e s s e s , a s Fi g u re 1 i l l u s t r a t e s . a m a t e r i a l c a l l e d l i g n i n , w h i c h a c t s l i k e A i r i s c o m p o s e d o f t w o m a i n g a s e s : t h e re s i n i n fi b e r g l a s s . B o t h c e l l u l o s e n i t r o g e n a n d o x y g e n . In c o m b u s t i o n , S t a g e o n e c o m b u s t i o n a n d l i g n i n a re m a d e b y t re e s f r o m o n l y o x y g e n i s c h e m i c a l l y a c t i v e . Th e fi r s t s t a g e o f c o m b u s t i o n i s t h e s i m p l e r m a t e r i a l s . Th e s u n s u p p l i e s Ni t r o g e n i s i n e r t , b u t s i n c e i t m a k e s u p h e a t i n g a n d e v a p o r a t i n g s t a g e . In i t i a l l y, t h e e n e r g y t o m a k e t h e s e s u b s t a n c e s a l m o s t 8 0 p e r c e n t o f t h e a i r, i t c o o l s h e a t i s b r o u g h t i n t o c o n t a c t w i t h a p i e c e d ow n a fi re b y t a k i n g a w a y h e a t .

F o r M o re O n l i n e M o n t G u i d e s , Vi s i t w w w. m o n t a n a . e d u / p u b l i c a t i o n s F-1 of wood in the presence of air. Heat called primary combustion. Primary but probably only during very hot fires causes several reactions. combustion begins at about 540° F, with just the right temperature and air First, it raises the temperature of an continues toward 900° F and results supply. Wood stove design features that area on the wood surface to some depth in the release of a large amount of can encourage secondary combustion into the wood. As the wood’s surface energy. Primary combustion also include a catalytic combustor, extended temperature approaches 212 degrees releases large amounts of unburned circulation of gases in the stove, baffles Fahrenheit, the water in the wood combustible gases, including methane and massive stove construction to hold begins to boil, then evaporates. As long and methanol as well as more acid, heat. water vapor and carbon dioxides. as the water remains in the wood, its Stage three combustion boiling and evaporation rob heat energy These gases, called secondary gases, from the source, thereby keeping the contain up to 60 percent of the During wood burning, after the gases are wood cells from gaining more heat. potential heat in the wood. Their driven from the wood, the carbon chains Moisture must be driven off before combustion is important to achieve of cellulose and lignin molecules remain. combustion can begin, so wood with a high overall combustion efficiency. The Carbon, or charcoal, burns a long time high moisture content is hard to ignite. secondary gases are not burned near with a low rate of heat output. Charcoal burning is important for two reasons. Unlike moisture, volatile gases are the wood because of lack of oxygen Additional energy is released, which combustible. They burn and release (oxygen is being consumed by primary is important to overall combustion heat. As the wood surface temperature combustion) or insufficient temperature. efficiency. rises beyond 212° F to about 450° The conditions needed to burn Also, charcoal burns at a low rate of F, major gases abundant in creosote secondary gases are sufficient oxygen combustion, which means that a good are produced: carbon dioxide, carbon and temperatures of at least 1100° F. charcoal bed will burn a long time, monoxide and acetic and formic acids. The air supply is critical. Too little air allowing a fire to last the night. The fire However, the gases generated in the will not support combustion and too can be rekindled by adding wood and first stage of combustion do not ignite much will cool the temperature to a opening the draft to supply new oxygen. until the moisture evaporates and the point where combustion cannot occur. kindling temperature is hot enough. Remember that air is about 80 percent inert gas and, when introduced Summary Stage two combustion into a wood stove, is below the Choosing the proper wood stove helps After moisture is driven from the wood 1100° F needed to sustain secondary wood burn more efficiently. However, and the heat raises the temperature of combustion. The more air that mixes proper operation of your stove is also the wood above 540° F, the second stage with the secondary gases, the greater critical. Understanding combustion of combustion takes place. This is the the quantity of heat absorbed by the principles and learning to manipulate heat-producing stage. It occurs at two nitrogen, and the lower the temperature the various conditions enables you different temperature levels: primary of the secondary gas-air mixture. to achieve maximum comfort and and secondary combustion. Secondary combustion can and efficiency from a wood heating system. The process by which gases are does occur in wood burning stoves released from wood and burned is

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Copyright © 2005 MSU Extension Service We encourage the use of this document for nonprofit educational purposes. This document may be reprinted for nonprofit educational purposes if no endorsement of a commercial product, service or company is stated or implied, and if appropriate credit is given to the author and the MSU Extension Service. To use these documents in electronic formats, permission must be sought from the Extension Communications Coordinator, Communications and Public Affairs, 416 Culbertson Hall, Montana State University–Bozeman, Bozeman MT 59717; E-mail: [email protected]. To order additional publications, please contact your county or reservation MSU Extension office, visit our online catalog at www.montana.edu/publications, or e-mail [email protected] The U.S. Department of Agriculture (USDA), Montana State University and the Montana State University Extension Service prohibit discrimination in all of File under: Housing & Residential Energy their programs and activities on the basis of race, color, national origin, gender, religion, age, disability, political beliefs, sexual orientation, and marital and family F-1 (Residential Heating Systems) status. Issued in furtherance of cooperative extension work in agriculture and home economics, acts of May 8 and June 30, 1914, in cooperation with the U.S. Reviewed Oct. 2005 Department of Agriculture, Douglas L. Steele, Vice Provost and Director, Exten- 2000 10.05GM sion Service, Montana State University, Bozeman, MT 59717.